19,306 research outputs found
Jahn-Teller Spectral Fingerprint in Molecular Photoemission: C60
The h_u hole spectral intensity for C60 -> C60+ molecular photoemission is
calculated at finite temperature by a parameter-free Lanczos diagonalization of
the electron-vibration Hamiltonian, including the full 8 H_g, 6 G_g, and 2 A_g
mode couplings. The computed spectrum at 800 K is in striking agreement with
gas-phase data. The energy separation of the first main shoulder from the main
photoemission peak, 230 meV in C60, is shown to measure directly and rather
generally the strength of the final-state Jahn-Teller coupling.Comment: 5 pages, 3 figure
Monitoring long-term evolution of engineered barrier systems using magnets:Magnetic response
International audienc
Low-energy excitations of a linearly Jahn-Teller coupled orbital quintet
The low-energy spectra of the single-mode h x (G+H) linear Jahn-Teller model
is studied by means of exact diagonalization. Both eigenenergies and
photoemission spectral intensities are computed. These spectra are useful to
understand the vibronic dynamics of icosahedral clusters with partly filled
orbital quintet molecular shells, for example C60 positive ions.Comment: 14 pages revte
Radial Velocities as an Exoplanet Discovery Method
The precise radial velocity technique is a cornerstone of exoplanetary
astronomy. Astronomers measure Doppler shifts in the star's spectral features,
which track the line-of/sight gravitational accelerations of a star caused by
the planets orbiting it. The method has its roots in binary star astronomy, and
exoplanet detection represents the low-companion-mass limit of that
application. This limit requires control of several effects of much greater
magnitude than the signal sought: the motion of the telescope must be
subtracted, the instrument must be calibrated, and spurious Doppler shifts
"jitter" must be mitigated or corrected. Two primary forms of instrumental
calibration are the stable spectrograph and absorption cell methods, the former
being the path taken for the next generation of spectrographs. Spurious,
apparent Doppler shifts due to non-center-of-mass motion (jitter) can be the
result of stellar magnetic activity or photospheric motions and granulation.
Several avoidance, mitigation, and correction strategies exist, including
careful analysis of line shapes and radial velocity wavelength dependence.Comment: Invited review chapter. 13pp. v2 includes corrections to Eqs 3-6,
updated references, and minor edit
The role of the Berry Phase in Dynamical Jahn-Teller Systems
The presence/absence of a Berry phase depends on the topology of the manifold
of dynamical Jahn-Teller potential minima. We describe in detail the relation
between these topological properties and the way the lowest two adiabatic
potential surfaces get locally degenerate. We illustrate our arguments through
spherical generalizations of the linear T x h and H x h cases, relevant for the
physics of fullerene ions. Our analysis allows us to classify all the spherical
Jahn-Teller systems with respect to the Berry phase. Its absence can, but does
not necessarily, lead to a nondegenerate ground state.Comment: revtex 7 pages, 2 eps figures include
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