206 research outputs found
Cloning and Joint Measurements of Incompatible Components of Spin
A joint measurement of two observables is a {\it simultaneous} measurement of
both quantities upon the {\it same} quantum system. When two quantum-mechanical
observables do not commute, then a joint measurement of these observables
cannot be accomplished by projective measurements alone. In this paper we shall
discuss the use of quantum cloning to perform a joint measurement of two
components of spin associated with a qubit system. We introduce a cloning
scheme which is optimal with respect to this task. This cloning scheme may be
thought to work by cloning two components of spin onto its outputs. We compare
the proposed cloning machine to existing cloners.Comment: 7 pages, 2 figures, submitted to PR
Pb and Bi L-Subshell Ionization Cross-Section Ratios Versus Proton Bombarding Energy from 0.5 to 4 MeV
Experimental ratios of L-subshell cross sections are given for ionization of lead and bismuth by 0.5-4-MeV-proton bombardment. The ratio of the LII to LI cross sections exhibits a maximum near 1.75 MeV. Individual subshell cross sections are obtained from the experimental ratios and previous total-cross-section data. These subshell ratios and cross sections are compared with the theoretical predictions of the plane-wave Born approximation using nonrelativistic hydrogenic wave functions, of the binary-encounter approximation scaled from Mg K-shell cross sections, and of the binary-encounter approximation scaled from cross sections obtained using L-shell velocity distributions. It was found that both approximations predict the trend of the data for the LII and LIII subshells, but that only the plane-wave Born approximation gave the proper behavior for the LI subshell
Joint measurements of spin, operational locality and uncertainty
Joint, or simultaneous, measurements of non-commuting observables are
possible within quantum mechanics, if one accepts an increase in the variances
of the jointly measured observables. In this paper, we discuss joint
measurements of a spin 1/2 particle along any two directions. Starting from an
operational locality principle, it is shown how to obtain a bound on how sharp
the joint measurement can be. We give a direct interpretation of this bound in
terms of an uncertainty relation.Comment: Accepted for publication in Phys. Rev.
Joint measurements and Bell inequalities
Joint quantum measurements of non-commuting observables are possible, if one
accepts an increase in the measured variances. A necessary condition for a
joint measurement to be possible is that a joint probability distribution
exists for the measurement. This fact suggests that there may be a link with
Bell inequalities, as these will be satisfied if and only if a joint
probability distribution for all involved observables exists. We investigate
the connections between Bell inequalities and conditions for joint quantum
measurements to be possible. Mermin's inequality for the three-particle
Greenberger-Horne-Zeilinger state turns out to be equivalent to the condition
for a joint measurement on two out of the three quantum systems to exist.
Gisin's Bell inequality for three co-planar measurement directions, meanwhile,
is shown to be less strict than the condition for the corresponding joint
measurement
Frictional quantum decoherence
The dynamics associated with a measurement-based master equation for quantum
Brownian motion are investigated. A scheme for obtaining time evolution from
general initial conditions is derived. This is applied to analyze dissipation
and decoherence in the evolution of both a Gaussian and a Schr\"{o}dinger cat
initial state. Dependence on the diffusive terms present in the master equation
is discussed with reference to both the coordinate and momentum
representations.Comment: 18 pages, 7 figure
The Magnetically-Tuned Transition-Edge Sensor
We present the first measurements on the proposed magnetically-tuned superconducting transition-edge sensor (MTES) and compare the modified resistive transition with the theoretical prediction. A TES's resistive transition is customarily characterized in terms of the unit less device parameters alpha and beta corresponding to the resistive response to changes in temperature and current respectively. We present a new relationship between measured IV quantities and the parameters alpha and beta and use these relations to confirm we have stably biased a TES with negative beta parameter with magnetic tuning. Motivated by access to this new unexplored parameter space, we investigate the conditions for bias stability of a TES taking into account both self and externally applied magnetic fields
Identification of Class I HLA T Cell Control Epitopes for West Nile Virus
The recent West Nile virus (WNV) outbreak in the United States underscores the importance of understanding human immune responses to this pathogen. Via the presentation of viral peptide ligands at the cell surface, class I HLA mediate the T cell recognition and killing of WNV infected cells. At this time, there are two key unknowns in regards to understanding protective T cell immunity: 1) the number of viral ligands presented by the HLA of infected cells, and 2) the distribution of T cell responses to these available HLA/viral complexes. Here, comparative mass spectroscopy was applied to determine the number of WNV peptides presented by the HLA-A*11:01 of infected cells after which T cell responses to these HLA/WNV complexes were assessed. Six viral peptides derived from capsid, NS3, NS4b, and NS5 were presented. When T cells from infected individuals were tested for reactivity to these six viral ligands, polyfunctional T cells were focused on the GTL9 WNV capsid peptide, ligands from NS3, NS4b, and NS5 were less immunogenic, and two ligands were largely inert, demonstrating that class I HLA reduce the WNV polyprotein to a handful of immune targets and that polyfunctional T cells recognize infections by zeroing in on particular HLA/WNV epitopes. Such dominant HLA/peptide epitopes are poised to drive the development of WNV vaccines that elicit protective T cells as well as providing key antigens for immunoassays that establish correlates of viral immunity. © 2013 Kaabinejadian et al
Increase of Direct C-C Coupling Reaction Yield by Identifying Structural and Electronic Properties of High-Spin Iron Tetra-azamacrocyclic Complexes
Macrocyclic ligands have been explored extensively as scaffolds for transition metal catalysts for oxygen and hydrogen atom transfer reactions. C–C reactions facilitated using earth abundant metals bound to macrocyclic ligands have not been well-understood but could be a green alternative to replacing the current expensive and toxic precious metal systems most commonly used for these processes. Therefore, the yields from direct Suzuki–Miyaura C–C coupling of phenylboronic acid and pyrrole to produce 2-phenylpyrrole facilitated by eight high-spin iron complexes ([Fe3+L1(Cl)2]+, [Fe3+L4(Cl)2]+, [Fe2+L5(Cl)]+, [Fe2+L6(Cl)2], [Fe3+L7(Cl)2]+, [Fe3+L8(Cl)2]+, [Fe2+L9(Cl)]+, and [Fe2+L10(Cl)]+) were compared to identify the effect of structural and electronic properties on catalytic efficiency. Specifically, catalyst complexes were compared to evaluate the effect of five properties on catalyst reaction yields: (1) the coordination requirements of the catalyst, (2) redox half-potential of each complex, (3) topological constraint/rigidity, (4) N atom modification(s) increasing oxidative stability of the complex, and (5) geometric parameters. The need for two labile cis-coordination sites was confirmed based on a 42% decrease in catalytic reaction yield observed when complexes containing pentadentate ligands were used in place of complexes with tetradentate ligands. A strong correlation between iron(III/II) redox potential and catalytic reaction yields was also observed, with [Fe2+L6(Cl)2] providing the highest yield (81%, −405 mV). A Lorentzian fitting of redox potential versus yields predicts that these catalysts can undergo more fine-tuning to further increase yields. Interestingly, the remaining properties explored did not show a direct, strong relationship to catalytic reaction yields. Altogether, these results show that modifications to the ligand scaffold using fundamental concepts of inorganic coordination chemistry can be used to control the catalytic activity of macrocyclic iron complexes by controlling redox chemistry of the iron center. Furthermore, the data provide direction for the design of improved catalysts for this reaction and strategies to understand the impact of a ligand scaffold on catalytic activity of other reactions
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