A Detailed Study of Giants and Horizontal Branch Stars in M68: Atmospheric Parameters and Chemical Abundances

In this paper, we present a detailed high-resolution spectroscopic study of post main sequence stars in the Globular Cluster M68. Our sample, which covers a range of 4000 K in $T_{eff}$, and 3.5 dex in $log(g)$, is comprised of members from the red giant, red horizontal, and blue horizontal branch, making this the first high-resolution globular cluster study covering such a large evolutionary and parameter space. Initially, atmospheric parameters were determined using photometric as well as spectroscopic methods, both of which resulted in unphysical and unexpected $T_{eff}$, $log(g)$, $\xi_{t}$, and [Fe/H] combinations. We therefore developed a hybrid approach that addresses most of these problems, and yields atmospheric parameters that agree well with other measurements in the literature. Furthermore, our derived stellar metallicities are consistent across all evolutionary stages, with $\langle$[Fe/H]$\rangle$ = $-$2.42 ($\sigma$ = 0.14) from 25 stars. Chemical abundances obtained using our methodology also agree with previous studies and bear all the hallmarks of globular clusters, such as a Na-O anti-correlation, constant Ca abundances, and mild $r$-process enrichment.Comment: Accepted to the Astronomical Journa

First results from the UBC etch-alignment mosaic CCD

First imaging results are obtained with a new CCD mosaic prototype (3K x 3k, 15 \mu m pixels). The CCDs are aligned using an etched socket alignment technique. Three different measurements of the alignment are made using star images, test p attern images, and microscope analysis. The CCDs have an angular misalignement o f less than 30 ppm. The composite device is flat to within \pm 3 \mu m, with rows/columns oriented to within 20 ppm. The use of an existing technology with built in precision reduces many of the difficulties and expenses typically encountered with mosaic detector construction. A new camera being built for the UBC liquid mirror telescope is al so described.Comment: 11 pages, 6 figs, 3 tables To appear in SPIE Photonics West97 - Electronic Imagin

Organic semiconductor laser platform for the detection of DNA by AgNP plasmonic enhancement

Organic semiconductor lasers are a sensitive biosensing platform that respond to specific biomolecule binding events. So far, such biosensors have utilized protein-based interactions for surface functionalization but a nucleic acid–based strategy would considerably widen their utility as a general biodiagnostic platform. This manuscript reports two important advances for DNA-based sensing using an organic semiconductor (OS) distributed feedback (DFB) laser. First, the immobilization of alkyne-tagged 12/18-mer oligodeoxyribonucleotide (ODN) probes by Cu-catalyzed azide alkyne cycloaddition (CuAAC) or “click-chemistry” onto an 80 nm thick OS laser film modified with an azide-presenting polyelectrolyte monolayer is presented. Second, sequence-selective binding to these immobilized probes with complementary ODN-functionalized silver nanoparticles, is detected. As binding occurs, the nanoparticles increase the optical losses of the laser mode through plasmonic scattering and absorption, and this causes a rise in the threshold pump energy required for laser action that is proportional to the analyte concentration. By monitoring this threshold, detection of the complementary ODN target down to 11.5 pM is achieved. This complementary binding on the laser surface is independently confirmed through surface-enhanced Raman spectroscopy (SERS)

Influence of extended dynamics on phase transitions in a driven lattice gas

Monte Carlo simulations and dynamical mean-field approximations are performed to study the phase transition in a driven lattice gas with nearest-neighbor exclusion on a square lattice. A slight extension of the microscopic dynamics with allowing the next-nearest-neighbor hops results in dramatic changes. Instead of the phase separation into high- and low-density regions in the stationary state the system exhibits a continuous transition belonging to the Ising universality class for any driving. The relevant features of phase diagram are reproduced by an improved mean-field analysis.Comment: 3 pages, 3 figure

SERS enhancement of silver nanoparticles prepared by a template-directed triazole ligand strategy

Two advances in the development of a one-pot method to prepare silver nanoparticles (AgNPs) using the Tollens’ reagent are described. First, a template-directed process of AgNP synthesis using resorcinol triazole ligands bearing two pendent galactose sugars is shown. Second, the conversion of these AgNPs into SERS nanotags is demonstrated using malachite green isothiocyanate as the Raman reporter molecule

SERS enhancement of silver nanoparticles prepared by a template-directed triazole ligand strategy

Two advances in the development of a one-pot method to prepare silver nanoparticles (AgNPs) using the Tollens' reagent are described. First, a template-directed process of AgNP synthesis using resorcinol triazole ligands bearing two pendent galactose sugars is shown. Second, the conversion of these AgNPs into SERS nanotags is demonstrated using malachite green isothiocyanate as the Raman reporter molecule