1,624 research outputs found
Adhesion, Stiffness and Instability in Atomically Thin MoS2 Bubbles
We measured the work of separation of single and few-layer MoS2 membranes
from a SiOx substrate using a mechanical blister test, and found a value of 220
+- 35 mJ/m^2. Our measurements were also used to determine the 2D Young's
modulus of a single MoS2 layer to be 160 +- 40 N/m. We then studied the
delamination mechanics of pressurized MoS2 bubles, demonstrating both stable
and unstable transitions between the bubbles' laminated and delaminated states
as the bubbles were inflated. When they were deflated, we observed edge pinning
and a snap-in transition which are not accounted for by the previously reported
models. We attribute this result to adhesion hysteresis and use our results to
estimate the work of adhesion of our membranes to be 42 +- 20 mJ/m^2
Energy-Momentum Tensor of Particles Created in an Expanding Universe
We present a general formulation of the time-dependent initial value problem
for a quantum scalar field of arbitrary mass and curvature coupling in a FRW
cosmological model. We introduce an adiabatic number basis which has the virtue
that the divergent parts of the quantum expectation value of the
energy-momentum tensor are isolated in the vacuum piece of , and
may be removed using adiabatic subtraction. The resulting renormalized
is conserved, independent of the cutoff, and has a physically transparent,
quasiclassical form in terms of the average number of created adiabatic
`particles'. By analyzing the evolution of the adiabatic particle number in de
Sitter spacetime we exhibit the time structure of the particle creation
process, which can be understood in terms of the time at which different
momentum scales enter the horizon. A numerical scheme to compute as a
function of time with arbitrary adiabatic initial states (not necessarily de
Sitter invariant) is described. For minimally coupled, massless fields, at late
times the renormalized goes asymptotically to the de Sitter invariant
state previously found by Allen and Folacci, and not to the zero mass limit of
the Bunch-Davies vacuum. If the mass m and the curvature coupling xi differ
from zero, but satisfy m^2+xi R=0, the energy density and pressure of the
scalar field grow linearly in cosmic time demonstrating that, at least in this
case, backreaction effects become significant and cannot be neglected in de
Sitter spacetime.Comment: 28 pages, Revtex, 11 embedded .ps figure
Voltage gated inter-cation selective ion channels from graphene nanopores
With the ability to selectively control ionic flux, biological protein ion
channels perform a fundamental role in many physiological processes. For
practical applications that require the functionality of a biological ion
channel, graphene provides a promising solid-state alternative, due to its
atomic thinness and mechanical strength. Here, we demonstrate that nanopores
introduced into graphene membranes, as large as 50 nm in diameter, exhibit
inter-cation selectivity with a ~20x preference for K+ over divalent cations
and can be modulated by an applied gate voltage. Liquid atomic force microscopy
of the graphene devices reveals surface nanobubbles near the pore to be
responsible for the observed selective behavior. Molecular dynamics simulations
indicate that translocation of ions across the pore likely occurs via a thin
water layer at the edge of the pore and the nanobubble. Our results demonstrate
a significant improvement in the inter-cation selectivity displayed by a
solid-state nanopore device and by utilizing the pores in a de-wetted state,
offers an approach to fabricating selective graphene membranes that does not
rely on the fabrication of sub-nm pores
Band Gap Engineering with Ultralarge Biaxial Strains in Suspended Monolayer MoS2
We demonstrate the continuous and reversible tuning of the optical band gap
of suspended monolayer MoS2 membranes by as much as 500 meV by applying very
large biaxial strains. By using chemical vapor deposition (CVD) to grow
crystals that are highly impermeable to gas, we are able to apply a pressure
difference across suspended membranes to induce biaxial strains. We observe the
effect of strain on the energy and intensity of the peaks in the
photoluminescence (PL) spectrum, and find a linear tuning rate of the optical
band gap of 99 meV/%. This method is then used to study the PL spectra of
bilayer and trilayer devices under strain, and to find the shift rates and
Gr\"uneisen parameters of two Raman modes in monolayer MoS2. Finally, we use
this result to show that we can apply biaxial strains as large as 5.6% across
micron sized areas, and report evidence for the strain tuning of higher level
optical transitions.Comment: Nano Lett., Article ASA
Ultra-strong Adhesion of Graphene Membranes
As mechanical structures enter the nanoscale regime, the influence of van der
Waals forces increases. Graphene is attractive for nanomechanical systems
because its Young's modulus and strength are both intrinsically high, but the
mechanical behavior of graphene is also strongly influenced by the van der
Waals force. For example, this force clamps graphene samples to substrates, and
also holds together the individual graphene sheets in multilayer samples. Here
we use a pressurized blister test to directly measure the adhesion energy of
graphene sheets with a silicon oxide substrate. We find an adhesion energy of
0.45 \pm 0.02 J/m2 for monolayer graphene and 0.31 \pm 0.03 J/m2 for samples
containing 2-5 graphene sheets. These values are larger than the adhesion
energies measured in typical micromechanical structures and are comparable to
solid/liquid adhesion energies. We attribute this to the extreme flexibility of
graphene, which allows it to conform to the topography of even the smoothest
substrates, thus making its interaction with the substrate more liquid-like
than solid-like.Comment: to appear in Nature Nanotechnolog
Classical and quantum radiation from a moving charge in an expanding universe
We investigate photon emission from a moving particle in an expanding
universe. This process is analogous to the radiation from an accelerated charge
in the classical electromagnetic theory. Using the framework of quantum field
theory in curved spacetime, we demonstrate that the Wentzel-Kramers-Brillouin
(WKB) approximation leads to the Larmor formula for the rate of the radiation
energy from a moving charge in an expanding universe. Using exactly solvable
models in a radiation-dominated universe and in a Milne universe, we examine
the validity of the WKB formula. It is shown that the quantum effect suppresses
the radiation energy in comparison with the WKB formula.Comment: 16 pages, JCAP in pres
Determination of the Bending Rigidity of Graphene via Electrostatic Actuation of Buckled Membranes
The small mass and atomic-scale thickness of graphene membranes make them
highly suitable for nanoelectromechanical devices such as e.g. mass sensors,
high frequency resonators or memory elements. Although only atomically thick,
many of the mechanical properties of graphene membranes can be described by
classical continuum mechanics. An important parameter for predicting the
performance and linearity of graphene nanoelectromechanical devices as well as
for describing ripple formation and other properties such as electron
scattering mechanisms, is the bending rigidity, {\kappa}. In spite of the
importance of this parameter it has so far only been estimated indirectly for
monolayer graphene from the phonon spectrum of graphite, estimated from AFM
measurements or predicted from ab initio calculations or bond-order potential
models. Here, we employ a new approach to the experimental determination of
{\kappa} by exploiting the snap-through instability in pre-buckled graphene
membranes. We demonstrate the reproducible fabrication of convex buckled
graphene membranes by controlling the thermal stress during the fabrication
procedure and show the abrupt switching from convex to concave geometry that
occurs when electrostatic pressure is applied via an underlying gate electrode.
The bending rigidity of bilayer graphene membranes under ambient conditions was
determined to be eV. Monolayers have significantly lower
{\kappa} than bilayers
Temporal invariance of social-ecological catchments
Natural resources such as waterbodies, public parks, and wildlife refuges attract people from varying distances on the landscape, creating âsocial-ecological catchments.â Catchments have provided great utility for understanding physical and social relationships within specific disciplines. Yet, catchments are rarely used across disciplines, such as its application to understand complex spatiotemporal dynamics between mobile human users and patchily distributed natural resources. We collected residence ZIP codes from 19,983 angler parties during 2014â2017 to construct seven anglerâwaterbody catchments in Nebraska, USA. We predicted that sizes of dense (10% utilization distribution) and dispersed (95% utilization distribution) anglerâwaterbody catchments would change across seasons and years as a function of diverse resource selection among mobile anglers. Contrary to expectations, we revealed that catchment size was invariant. We discuss how social (conservation actions) and ecological (low water quality, reduction in species diversity) conditions are expected to impact landscape patterns in resource use. We highlight how this simple concept and user-friendly technique can inform timely landscape-level conservation decisions within coupled social-ecological systems that are currently difficult to study and understand
Leveraging Skype in the Classroom for Science Communication: A Streaming Science â Scientist Online Approach
A growing need exists to identify, implement, and research alternative methods to communicate with, educate, and engage youth about science, in order to increase science literacy and knowledge of future societal decision-makers. Electronic field trips (EFTs) are one channel of non-formal communication and education that have been introduced in agricultural and natural resources to reach youth audiences with science-based information in real-time. EFTs can be conducted in several different ways due to the proliferation of video production and web-streaming technologies. The following professional development article offers science communication professionals and scientists a detailed model and specific steps to develop and host an EFT via the Skype in the Classroom platform. The outlined model builds off of prior application and research from the Streaming Science online science communication platform and offers a secondary model for effective EFT implementation and research. The authors describe the establishment of an online science communication network, the development of the Streaming Science: Scientist Online format, content creation, the production team structure, and mobile production hardware and software. Scientist Online EFT program outcomes in terms of participation are noted, as well as student outcomes in the form of excerpts to demonstrate student engagement are shared
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