The impact of Grey Heron (Ardea cinerea L.) colony on soil biogeochemistry and vegetation: a natural long-term in situ experiment in a planted pine forest

Increased anthropogenic pressure including intensification of agricultural activities leads to long-term decline of natural biotopes, with planted forests often considered as promising compensatory response, although reduced biodiversity and ecosystem stability represent their common drawbacks. Here we present a complex investigation of the impact of a large Grey Heron (Ardea cinerea L.) colony on soil biogeochemistry and vegetation in a planted Scots pine forest representing a natural in situ experiment on an engineered ecosystem. After settling around 2006, the colony expanded for 15 years, leading to the intensive deposition of nutrients with feces, food remains and feather thereby considerably altering the local soil biogeochemistry. Thus, lower pH levels around 4.5, 10- and 2-fold higher concentrations of phosphorous and nitrogen, as well as 1.2-fold discrepancies in K, Li, Mn, Zn and Co., respectively, compared to the surrounding control forest area could be observed. Unaltered total organic carbon (Corg) suggests repressed vegetation, as also reflected in the vegetation indices obtained by remote sensing. Moreover, reduced soil microbial diversity with considerable alternations in the relative abundance of Proteobacteria, Firmicutes, Acidobacteriota, Actinobacteriota, Verrucomicrobiota, Gemmatimonadota, Chujaibacter, Rhodanobacter, and Bacillus has been detected. The above alterations to the ecosystem also affected climate stress resilience of the trees indicated by their limited recovery from the major 2010 drought stress, in marked contrast to the surrounding forest (p = 3∙10−5). The complex interplay between geographical, geochemical, microbiological and dendrological characteristics, as well as their manifestation in the vegetation indices is explicitly reflected in the Bayesian network model. Using the Bayesian inference approach, we have confirmed the predictability of biodiversity patterns and trees growth dynamics given the concentrations of keynote soil biogeochemical alternations with correlations R > 0.8 between observations and predictions, indicating the capability of risk assessment that could be further employed for an informed forest management

DIATOMITES AND OPOKA FROM WESTERN KAZAKHSTAN DEPOSITS: LITHOGEOCHEMISTRY, STRUCTURAL AND TEXTURAL PARAMETERS, POTENTIAL OF USE

Link for citation: Smirnov P.V., Zhakipbayev B.E., Staroselets D.A., Deryagina O.I., Batalin G.A., Gareev B.I., Vergunov A.V. Diatomites and opoka from Western Kazakhstan deposits: lithogeochemistry, structural and textural parameters, potential of use. Bulletin of the Tomsk Polytechnic University. Geo Аssets Engineering, 2023, vol. 334, no. 7, рр. 187-201. In Rus. The relevance. In recent decades, individual studies in the Republic of Kazakhstan have been aimed at expanding the potential of using rocks of large and industrial exploitation of silicite deposits for revising their physicochemical, mineralogical parameters, and assessing the prospects for expanding their use in new industries and technologies in the construction and technical industries, materials science based on deep chemical processing of mineral raw materials. The article presents new data on the chemical-mineralogical and structural parameters of diatomites from the Utesai deposit and opoka from the Taskala deposit of the Republic of Kazakhstan. The main aim: comprehensive analysis of the chemical-mineral composition and structural and textural features of rocks from two largest deposits of silicon raw materials in the Western part of Kazakhstan – the Utesai diatomite deposit and the Taskala opoka deposit. Objects: diatomites of the Utesai deposit and opoka of the Taskala deposits in the western part of the Republic of Kazakhstan. Methods: field research, lithological and petrographic analysis of thin sections, X-ray diffraction analysis, differential thermal analysis, scanning electron microscopy, X-ray fluorescence analysis. Results. The studied diatomites and opoka are characterized by a high degree of homogeneity; they are represented by typical phases for silicic rocks of the region – opal-CT, clay minerals with an admixture of quartz and feldspars. From the mineralogical point of view, the most obvious difference between the studied diatomites and the Trans-Urals is the significant content of kaolinite – over 10 %, while in the diatomites of the Trans-Urals, the main clay component is smectite and mixed-layer illite-smectite formations. The rocks under consideration are clayey diatomites and clayey flasks, the total content of basic oxides allows us to characterize raw materials as medium quality, most suitable for the production of foam glass materials, and, in particular, glass fiber, in the production of which alumina is an important functional component. At the same time, the significant content of clay and other impurities does not allow us to recommend such raw materials for the production of filter and sorbing materials

Application of Sonotriboluminescence to Determine Arene Molecules in Hydrocarbons

The sonotriboluminescence of suspensions of terbium(III) and europium(III) sulfates in decane without and in the presence of benzene, toluene and p-xylene was studied. The choice of crystals of these lanthanides is due to the fact that they have intense luminescence during mechanical action, and also do not dissolve in hydrocarbon solvents. During ultrasonic exposure to suspensions in pure alkanes, bands of Ln3+ ions and N2 in the UV region are recorded in the luminescence spectrum. When aromatic hydrocarbon molecules are added, bands of benzene, toluene and p-xylene molecules, coinciding with their photoluminescence spectra, are recorded in the sonotriboluminescence spectra in the UV region. The high sensitivity of the luminescence of suspensions to arene additives made it possible to obtain the dependence of the characteristic fluorescence of arene molecules in the sonotriboluminescence spectra on their concentration in suspensions. The limits of detection of benzene, toluene and p-xylene in the composition of this suspension were established. The lower limits of detection from the sonotriboluminescence spectra for xylene, toluene and benzene are 0.1, 3 and 50 ppmv, respectively. Fluorescence bands of these molecules were also recorded in the sonotriboluminescence spectra of suspensions in commercial dodecane and heptane with additives of commercial gasoline (up to 1%). The results obtained can be used for luminescent detection of aromatic compounds in saturated hydrocarbons

Dithiophosphate-Induced Redox Conversions of Reduced and Oxidized Glutathione

Phosphorus species are potent modulators of physicochemical and bioactive properties of peptide compounds. O,O-diorganyl dithiophoshoric acids (DTP) form bioactive salts with nitrogen-containing biomolecules; however, their potential as a peptide modifier is poorly known. We synthesized amphiphilic ammonium salts of O,O-dimenthyl DTP with glutathione, a vital tripeptide with antioxidant, protective and regulatory functions. DTP moiety imparted radical scavenging activity to oxidized glutathione (GSSG), modulated the activity of reduced glutathione (GSH) and profoundly improved adsorption and electrooxidation of both glutathione salts on graphene oxide modified electrode. According to NMR spectroscopy and GC–MS, the dithiophosphates persisted against immediate dissociation in an aqueous solution accompanied by hydrolysis of DTP moiety into phosphoric acid, menthol and hydrogen sulfide as well as in situ thiol-disulfide conversions in peptide moieties due to the oxidation of GSH and reduction of GSSG. The thiol content available in dissolved GSH dithiophosphate was more stable during air oxidation compared with free GSH. GSH and the dithiophosphates, unlike DTP, caused a thiol-dependent reduction of MTS tetrazolium salt. The results for the first time suggest O,O-dimenthyl DTP as a redox modifier for glutathione, which releases hydrogen sulfide and induces biorelevant redox conversions of thiol/disulfide groups

Early Triassic Monzonite–Granite Series in Eastern Kazakhstan as a Reflection of Siberian Large Igneous Province Activity

We provide the results of studying the internal structure and composition of the rocks of the Semeitau and Delbegetei massifs located in Eastern Kazakhstan. It was previously believed that these massifs have different ages and were formed in different geodynamic settings. The U-Pb zircon age from the monzonites and quartz monzonites was determined to be 249 ± 2 Ma, which showed the same Early Triassic age of the massifs. Both massifs are composed of rocks of the same monzonite–granite series of rocks with a significant proportion of high-silica rocks (leucocratic granites). Intermediate rocks are formed due to the differentiation of subalkaline mafic magmas, and the felsic rocks (rhyolites and granites) are the result of partial melting of crustal substrates. The massif formation model assumes the intrusion of mafic magmas into the crust, their differentiation and mixing with crustal melts, and then the intrusion of various rocks into the upper crustal levels. Analysis of the geological position, age and composition of the rocks allows us to conclude that the Semeitau and Delbegetei massifs were formed in an intraplate geodynamic setting. The activity of the mantle plume is the most probable reason for their formation. The Semeitau and Delbegetei massifs can be included in the southern part of the range of the Early Triassic Siberian Large Igneous Province

Early Triassic Monzonite–Granite Series in Eastern Kazakhstan as a Reflection of Siberian Large Igneous Province Activity

We provide the results of studying the internal structure and composition of the rocks of the Semeitau and Delbegetei massifs located in Eastern Kazakhstan. It was previously believed that these massifs have different ages and were formed in different geodynamic settings. The U-Pb zircon age from the monzonites and quartz monzonites was determined to be 249 ± 2 Ma, which showed the same Early Triassic age of the massifs. Both massifs are composed of rocks of the same monzonite–granite series of rocks with a significant proportion of high-silica rocks (leucocratic granites). Intermediate rocks are formed due to the differentiation of subalkaline mafic magmas, and the felsic rocks (rhyolites and granites) are the result of partial melting of crustal substrates. The massif formation model assumes the intrusion of mafic magmas into the crust, their differentiation and mixing with crustal melts, and then the intrusion of various rocks into the upper crustal levels. Analysis of the geological position, age and composition of the rocks allows us to conclude that the Semeitau and Delbegetei massifs were formed in an intraplate geodynamic setting. The activity of the mantle plume is the most probable reason for their formation. The Semeitau and Delbegetei massifs can be included in the southern part of the range of the Early Triassic Siberian Large Igneous Province

Diet and life history reduce interspecific and intraspecific competition among three sympatric Arctic cephalopods.

Trophic niche and diet comparisons among closely sympatric marine species are important to understand complex food webs, particularly in regions most affected by climate change. Using stable isotope analyses, all ontogenetic stages of three sympatric species of Arctic cephalopods (genus Rossia) were studied to assess inter- and intraspecific competition with niche and diet overlap and partitioning in West Greenland and the Barents Sea. Seven traits related to resource and habitat utilization were identified in Rossia: no trait was shared by all three species. High boreal R. megaptera and Arctic endemic R. moelleri shared three traits with each other, while both R. megaptera and R. moelleri shared only two unique traits each with widespread boreal-Arctic R. palpebrosa. Thus all traits formed fully uncrossing pattern with each species having unique strategy of resource and habitat utilization. Predicted climate changes in the Arctic would have an impact on competition among Rossia with one potential ‘winner’ (R. megaptera in the Barents Sea) but no potential ‘losers’