294 research outputs found
Recent advances in the design and photocatalytic enhanced performance of gold plasmonic nanostructures decorated with non-titania based semiconductor hetero-nanoarchitectures
Plasmonic photocatalysts combining metallic nanoparticles and semiconductors have been aimed as versatile alternatives to drive light-assisted catalytic chemical reactions beyond the ultraviolet (UV) regions, and overcome one of the major drawbacks of the most exploited photocatalysts (TiO2 or ZnO). The strong size and morphology dependence of metallic nanostructures to tune their visible to near-infrared (vis-NIR) light harvesting capabilities has been combined with the design of a wide variety of architectures for the semiconductor supports to promote the selective activity of specific crystallographic facets. The search for efficient heterojunctions has been subjected to numerous studies, especially those involving gold nanostructures and titania semiconductors. In the present review, we paid special attention to the most recent advances in the design of gold-semiconductor hetero-nanostructures including emerging metal oxides such as cerium oxide or copper oxide (CeO2 or Cu2O) or metal chalcogenides such as copper sulfide or cadmium sulfides (CuS or CdS). These alternative hybrid materials were thoroughly built in past years to target research fields of strong impact, such as solar energy conversion, water splitting, environmental chemistry, or nanomedicine. Herein, we evaluate the influence of tuning the morphologies of the plasmonic gold nanostructures or the semiconductor interacting structures, and how these variations in geometry, either individual or combined, have a significant influence on the final photocatalytic performance
High-radiance LED-driven fluidized bed photoreactor for the complete oxidation of n-hexane in air
This work presents a highly efficient photo-reactor configuration for VOC abatement. It consists of a fluidized bed made of commercial, easy to fluidize, transparent borosilicate glass beads coated with commercial TiO2 nanoparticles (0.15–2.3 wt% loadings). Herein, we demonstrate that the use of high-radiance/low consumption UV-LEDs as irradiation sources with a deeper light penetration under fluidizing conditions facilitates the photocatalytic response to achieve the complete oxidation of VOCs. The role of different parameters such as catalyst loading and irradiation power have been thoroughly studied and evaluated to maximize the full combustion of n-hexane. Under the high radiance (up to 2200 mW/cm2) conditions used the bed heats significantly (up to 190 °C), although this did not have an effect on the conversions reached, which depended solely on the wavelength and power used. The productivity of the photoreactor tested and the space velocity used were around 5.25 × 10-2 mol/g·h and 12000 h-1 respectively
Magnetic field diagnostics and spatio-temporal variability of the solar transition region
Magnetic field diagnostics of the transition region from the chromosphere to
the corona faces us with the problem that one has to apply extreme UV
spectro-polarimetry. While for coronal diagnostic techniques already exist
through infrared coronagraphy above the limb and radio observations on the
disk, for the transition region one has to investigate extreme UV observations.
However, so far the success of such observations has been limited, but there
are various projects to get spectro-polarimetric data in the extreme UV in the
near future. Therefore it is timely to study the polarimetric signals we can
expect for such observations through realistic forward modeling.
We employ a 3D MHD forward model of the solar corona and synthesize the
Stokes I and Stokes V profiles of C IV 1548 A. A signal well above 0.001 in
Stokes V can be expected, even when integrating for several minutes in order to
reach the required signal-to-noise ratio, despite the fact that the intensity
in the model is rapidly changing (just as in observations). Often this
variability of the intensity is used as an argument against transition region
magnetic diagnostics which requires exposure times of minutes. However, the
magnetic field is evolving much slower than the intensity, and thus when
integrating in time the degree of (circular) polarization remains rather
constant. Our study shows the feasibility to measure the transition region
magnetic field, if a polarimetric accuracy on the order of 0.001 can be
reached, which we can expect from planned instrumentation.Comment: Accepted for publication in Solar Physics (4.Mar.2013), 19 pages, 9
figure
The Structure and Dynamics of the Upper Chromosphere and Lower Transition Region as Revealed by the Subarcsecond VAULT Observations
The Very high Angular resolution ULtraviolet Telescope (VAULT) is a sounding
rocket payload built to study the crucial interface between the solar
chromosphere and the corona by observing the strongest line in the solar
spectrum, the Ly-a line at 1216 {\AA}. In two flights, VAULT succeeded in
obtaining the first ever sub-arcsecond (0.5") images of this region with high
sensitivity and cadence. Detailed analyses of those observations have
contributed significantly to new ideas about the nature of the transition
region. Here, we present a broad overview of the Ly-a atmosphere as revealed by
the VAULT observations, and bring together past results and new analyses from
the second VAULT flight to create a synthesis of our current knowledge of the
high-resolution Ly-a Sun. We hope that this work will serve as a good reference
for the design of upcoming Ly-a telescopes and observing plans.Comment: 28 pages, 11 figure
Produção e valor nutritivo da forragem de capim-elefante em dois sistemas de produção.
Esta pesquisa foi realizada com o objetivo de avaliar a produção e o valor nutritivo da forragem de capimelefante cultivado em sistemas convencional e agroecológico. No sistema convencional, o capim-elefante foi estabelecido em cultivo exclusivo, em linhas com espaçamento de 1,4 m e, no sistema agroecológico, em linhas afastadas 3 m. Nas entrelinhas, estabeleceu-se azevém no período hibernal para desenvolvimento de espécies de crescimento espontâneo no período estival. Avaliaram-se a massa, a produção e a composição botânica e estrutural da forragem e a carga animal. Amostras de simulação de pastejo foram coletadas para determinação dos teores de proteína bruta e fibra em detergente neutro e da digestibilidade in vitro da matéria seca e matéria orgânica. O delineamento experimental foi o inteiramente casualizado com dois tratamentos (sistemas convencional e agroecológico) e duas repetições (piquetes). Valores mais elevados para massa de forragem, produção de forragem, taxa de acúmulo diário e carga animal foram observados no sistema convencional. A relação folha:colmo foi similar entre os sistemas. Valor mais elevado de proteína bruta foi observado no sistema agroecológico. O capim-elefante sob manejo convencional apresenta maior produção de forragem, com menores teores de proteína bruta. O sistema agroecológico apresenta melhor distribuição da produção de forragem no decorrer do ano
Measurement of the scintillation time spectra and pulse-shape discrimination of low-energy beta and nuclear recoils in liquid argon with DEAP-1
The DEAP-1 low-background liquid argon detector was used to measure
scintillation pulse shapes of electron and nuclear recoil events and to
demonstrate the feasibility of pulse-shape discrimination (PSD) down to an
electron-equivalent energy of 20 keV.
In the surface dataset using a triple-coincidence tag we found the fraction
of beta events that are misidentified as nuclear recoils to be (90% C.L.) for energies between 43-86 keVee and for a nuclear recoil
acceptance of at least 90%, with 4% systematic uncertainty on the absolute
energy scale. The discrimination measurement on surface was limited by nuclear
recoils induced by cosmic-ray generated neutrons. This was improved by moving
the detector to the SNOLAB underground laboratory, where the reduced background
rate allowed the same measurement with only a double-coincidence tag.
The combined data set contains events. One of those, in the
underground data set, is in the nuclear-recoil region of interest. Taking into
account the expected background of 0.48 events coming from random pileup, the
resulting upper limit on the electronic recoil contamination is
(90% C.L.) between 44-89 keVee and for a nuclear recoil
acceptance of at least 90%, with 6% systematic uncertainty on the absolute
energy scale.
We developed a general mathematical framework to describe PSD parameter
distributions and used it to build an analytical model of the distributions
observed in DEAP-1. Using this model, we project a misidentification fraction
of approx. for an electron-equivalent energy threshold of 15 keV for
a detector with 8 PE/keVee light yield. This reduction enables a search for
spin-independent scattering of WIMPs from 1000 kg of liquid argon with a
WIMP-nucleon cross-section sensitivity of cm, assuming
negligible contribution from nuclear recoil backgrounds.Comment: Accepted for publication in Astroparticle Physic
Solar Intranetwork Magnetic Elements: bipolar flux appearance
The current study aims to quantify characteristic features of bipolar flux
appearance of solar intranetwork (IN) magnetic elements. To attack such a
problem, we use the Narrow-band Filter Imager (NFI) magnetograms from the Solar
Optical Telescope (SOT) on board \emph{Hinode}; these data are from quiet and
an enhanced network areas. Cluster emergence of mixed polarities and IN
ephemeral regions (ERs) are the most conspicuous forms of bipolar flux
appearance within the network. Each of the clusters is characterized by a few
well-developed ERs that are partially or fully co-aligned in magnetic axis
orientation. On average, the sampled IN ERs have total maximum unsigned flux of
several 10^{17} Mx, separation of 3-4 arcsec, and a lifetime of 10-15 minutes.
The smallest IN ERs have a maximum unsigned flux of several 10^{16} Mx,
separations less than 1 arcsec, and lifetimes as short as 5 minutes. Most IN
ERs exhibit a rotation of their magnetic axis of more than 10 degrees during
flux emergence. Peculiar flux appearance, e.g., bipole shrinkage followed by
growth or the reverse, is not unusual. A few examples show repeated
shrinkage-growth or growth-shrinkage, like magnetic floats in the dynamic
photosphere. The observed bipolar behavior seems to carry rich information on
magneto-convection in the sub-photospheric layer.Comment: 26 pages, 14 figure
Balanços energéticos agropecuários: uma importante ferramenta como indicativo de sustentabilidade de agroecossistemas.
No Brasil, pouca atenção se tem dado às formas e caminhos com que os fluxos energéticos se distribuem nos sistemas produtivos. Na agropecuária, a atenção tem sido voltada a novas fontes de energia (biomassa) ou em tecnologia alternativa, visando a racionalização do uso de energia fóssil ou elétrica. Entretanto, a agricultura tem se desenvolvido baseada fortemente na utilização intensiva de máquinas agrícolas, com conseqüente uso de combustíveis fósseis. Um fator de estrangulamento muito forte no consumo energético geral tem sido a utilização massiva de fertilizantes derivados do petróleo nos agroecossistemas. Estudos de Balanços Energéticos visam determinar os pontos de estrangulamento energético fundamentando a busca por tecnologias poupadoras de energia, especialmente aquelas de origem fóssil (combustível, fertilizante, agrotóxicos, energia despendida na fabricação das máquinas e implementos, etc.). No Brasil, a Região Sul, é onde se encontram vários trabalhos buscando uma agricultura mais auto-sustentável, do ponto de vista da utilização da energia. Em vista da possibilidade de eventuais futuras crises energéticas, o presente trabalho procura analisar o estado-da-arte dos estudos em Balanço Energético, no Brasil e no Mundo, como uma ferramenta de indicação da sustentabilidade dos sistemas agropecuários
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