421 research outputs found
Molecular Hydrogen Formation on Low Temperature Surfaces in Temperature Programmed Desorption Experiments
The study of the formation of molecular hydrogen on low temperature surfaces
is of interest both because it allows to explore elementary steps in the
heterogeneous catalysis of a simple molecule and because of the applications in
astrochemistry. Here we report results of experiments of molecular hydrogen
formation on amorphous silicate surfaces using temperature-programmed
desorption (TPD). In these experiments beams of H and D atoms are irradiated on
the surface of an amorphous silicate sample. The desorption rate of HD
molecules is monitored using a mass spectrometer during a subsequent TPD run.
The results are analyzed using rate equations and the activation energies of
the processes leading to molecular hydrogen formation are obtained from the TPD
data. We show that a model based on a single isotope provides the correct
results for the activation energies for diffusion and desorption of H atoms.
These results can thus be used to evaluate the formation rate of H_2 on dust
grains under the actual conditions present in interstellar clouds.Comment: 30 pages, 1 table, 6 figures. Published versio
Current strategies for tracheal replacement: A review
Airway cancers have been increasing in recent years. Tracheal resection is commonly performed during surgery and is burdened from post-operative complications severely affecting quality of life. Tracheal resection is usually carried out in primary tracheal tumors or other neoplasms of the neck region. Regenerative medicine for tracheal replacement using bio-prosthesis is under current research. In recent years, attempts were made to replace and transplant human cadaver trachea. An effective vascular supply is fundamental for a successful tracheal transplantation. The use of biological scaffolds derived from decellularized tissues has the advantage of a three-dimensional structure based on the native extracellular matrix promoting the perfusion, vascularization, and differentiation of the seeded cell typologies. By appropriately modulating some experimental parameters, it is possible to change the characteristics of the surface. The obtained membranes could theoretically be affixed to a decellularized tissue, but, in practice, it needs to ensure adhesion to the biological substrate and/or glue adhesion with biocompatible glues. It is also known that many of the biocompatible glues can be toxic or poorly tolerated and induce inflammatory phenomena or rejection. In tissue and organ transplants, decellularized tissues must not produce adverse immunological reactions and lead to rejection phenomena; at the same time, the transplant tissue must retain the mechanical properties of the original tissue. This review describes the attempts so far developed and the current lines of research in the field of tracheal replacement
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Infrared, UV/VIS and Raman Spectroscopy of Comet Wild-2 Samples Returned by the Stardust Mission
Results from the preliminary examination of Stardust samples obtained using various spectroscopic methods will be presented
The mass of the neutron star in Vela X-1 and tidally induced non-radial oscillations in GP Vel
We report new radial velocity observations of GP Vel/HD77581, the optical
companion to the eclipsing X-ray pulsar Vela X-1. Using data spanning more than
two complete orbits of the system, we detect evidence for tidally induced
non-radial oscillations on the surface of GP Vel, apparent as peaks in the
power spectrum of the residuals to the radial velocity curve fit. By removing
the effect of these oscillations (to first order) and binning the radial
velocities, we have determined the semi-amplitude of the radial velocity curve
of GP Vel to be K_o=22.6+/-1.5 km/s. Given the accurately measured
semi-amplitude of the pulsar's orbit, the mass ratio of the system is
0.081+/-0.005. We are able to set upper and lower limits on the masses of the
component stars as follows. Assuming GP Vel fills its Roche lobe then the
inclination angle of the system, i=70.1+/-2.6 deg. In this case we obtain the
masses of the two stars as M_x=2.27 +/-0.17 M_sun for the neutron star and
M_o=27.9+/-1.3 M_sun for GP Vel. Conversely, assuming the inclination angle is
i=90 deg, the ratio of the radius of GP Vel to the radius of its Roche lobe is
beta=0.89+/-0.03 and the masses of the two stars are M_x=1.88+/-0.13 M_sun and
M_o=23.1+/-0.2 M_sun. A range of solutions between these two sets of limits is
also possible, corresponding to other combinations of i and beta. In addition,
we note that if the zero phase of the radial velocity curve is allowed as a
free parameter, rather than constrained by the X-ray ephemeris, a significantly
improved fit is obtained with an amplitude of 21.2+/-0.7 km/s and a phase shift
of 0.033+/-0.007 in true anomaly. The apparent shift in the zero phase of the
radial velocity curve may indicate the presence of an additional radial
velocity component at the orbital period.Comment: Accepted for publication in Astronomy & Astrophysic
The Early Psychosis Screener (EPS): Quantitative validation against the SIPS using machine learning
Machine learning techniques were used to identify highly informative early psychosis self-report items and to validate an early psychosis screener (EPS) against the Structured Interview for Psychosis-risk Syndromes (SIPS). The Prodromal Questionnaire–Brief Version (PQ-B) and 148 additional items were administered to 229 individuals being screened with the SIPS at 7 North American Prodrome Longitudinal Study sites and at Columbia University. Fifty individuals were found to have SIPS scores of 0, 1, or 2, making them clinically low risk (CLR) controls; 144 were classified as clinically high risk (CHR) (SIPS 3–5) and 35 were found to have first episode psychosis (FEP) (SIPS 6). Spectral clustering analysis, performed on 124 of the items, yielded two cohesive item groups, the first mostly related to psychosis and mania, the second mostly related to depression, anxiety, and social and general work/school functioning. Items within each group were sorted according to their usefulness in distinguishing between CLR and CHR individuals using the Minimum Redundancy Maximum Relevance procedure. A receiver operating characteristic area under the curve (AUC) analysis indicated that maximal differentiation of CLR and CHR participants was achieved with a 26-item solution (AUC = 0.899 ± 0.001). The EPS-26 outperformed the PQ-B (AUC = 0.834 ± 0.001). For screening purposes, the self-report EPS-26 appeared to differentiate individuals who are either CLR or CHR approximately as well as the clinician-administered SIPS. The EPS-26 may prove useful as a self-report screener and may lead to a decrease in the duration of untreated psychosis. A validation of the EPS-26 against actual conversion is underway
The USNO-B Catalog
USNO-B is an all-sky catalog that presents positions, proper motions,
magnitudes in various optical passbands, and star/galaxy estimators for
1,042,618,261 objects derived from 3,643,201,733 separate observations. The
data were obtained from scans of 7,435 Schmidt plates taken for the various sky
surveys during the last 50 years. USNO-B1.0 is believed to provide all-sky
coverage, completeness down to V = 21, 0.2 arcsecond astrometric accuracy at
J2000, 0.3 magnitude photometric accuracy in up to five colors, and 85%
accuracy for distinguishing stars from non-stellar objects. A brief discussion
of various issues is given here, but the actual data are available from
http://www.nofs.navy.mil and other sites.Comment: Accepted by Astronomical Journa
Molecular Hydrogen Formation on Amorphous Silicates Under Interstellar Conditions
Experimental results on the formation of molecular hydrogen on amorphous
silicate surfaces are presented for the first time and analyzed using a rate
equation model. The energy barriers for the relevant diffusion and desorption
processes are obtained. They turn out to be significantly higher than those
obtained earlier for polycrystalline silicates, demonstrating the importance of
grain morphology. Using these barriers we evaluate the efficiency of molecular
hydrogen formation on amorphous silicate grains under interstellar conditions.
It is found that unlike polycrystalline silicates, amorphous silicate grains
are efficient catalysts of H formation within a temperature range which
is relevant to diffuse interstellar clouds. The results also indicate that the
hydrogen molecules are thermalized with the surface and desorb with low kinetic
energy. Thus, they are unlikely to occupy highly excited states.Comment: 5 pages, 3 figures, 1 table. Accepted to ApJL. Shortened a bi
Complex organic molecules in protostellar environments in the SKA era
Molecular complexity builds up at each step of the Sun-like star formation
process, starting from simple molecules and ending up in large polyatomic
species. Complex organic molecules (COMs; such as methyl formate, HCOOCH,
dymethyl ether, CHOCH, formamide, NHCHO, or glycoaldehyde,
HCOCHOH) are formed in all the components of the star formation recipe
(e.g. pre-stellar cores, hot-corinos, circumstellar disks, shocks induced by
fast jets), due to ice grain mantle sublimation or sputtering as well as
gas-phase reactions. Understanding in great detail the involved processes is
likely the only way to predict the ultimate molecular complexity reached in the
ISM, as the detection of large molecules is increasingly more difficult with
the increase of the number of atoms constituting them.
Thanks to the recent spectacular progress of astronomical observations, due
to the Herschel (sub-mm and IR), IRAM and SMA (mm and sub-mm), and NRAO (cm)
telescopes, an enormous activity is being developed in the field of
Astrochemistry, extending from astronomical observatories to chemical
laboratories. We are involved in several observational projects providing
unbiased spectral surveys (in the 80-300 and 500-2000 GHz ranges) with
unprecedented sensitivity of templates of dense cores and protostars. Forests
of COM lines have been detected. In this chapter we will focus on the chemistry
of both cold prestellar cores and hot shocked regions, (i) reviewing results
and open questions provided by mm-FIR observations, and (ii) showing the need
of carrying on the observations of COMs at lower frequencies, where SKA will
operate. We will also emphasize the importance of analysing the spectra by the
light of the experimental studies performed by our team, who is investigating
the chemical effects induced by ionising radiation bombarding astrophysically
relevant ices.Comment: 18 pages, 8 figure
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