6,180 research outputs found
Void-mediated formation of Sn quantum dots in a Si matrix
Atomic scale analysis of Sn quantum dots (QDs) formed during the molecular beam-epitaxy (MBE) growth of Sn_xSi_(1āx) (0.05 ā©½ x ā©½ 0.1) multilayers in a Si matrix revealed a void-mediated formation mechanism. Voids below the Si surface are induced by the lattice mismatch strain between Sn_xSi_(1āx) layers and Si, taking on their equilibrium tetrakaidecahedron shape. The diffusion of Sn atoms into these voids leads to an initial rapid coarsening of quantum dots during annealing. Since this formation process is not restricted to Sn, a method to grow QDs may be developed by controlling the formation of voids and the diffusion of materials into these voids during MBE growth
Characterization of transport and magnetic properties in thin film La(0.67)(Ca(x)Sr(1-x))(0.33)MnO(3) mixtures
We have grown thin films of (100) oriented
La_{0.67}(Ca_{x}Sr_{1-x})_{0.33}MnO_{3} on (100) NdGaO_{3} substrates by
off-axis sputtering. We have looked at the changes in the resistivity and
magnetoresistance of the samples as the Ca/Sr ratio was varied. We find that as
the calcium fraction is decreased, the lattice match to the substrate
decreases, and the films become more disordered, as observed in transport
measurements and the variation in Curie and peak resistance temperatures. We
find a correlation between the temperature independent and T^2 terms to the low
temperature resistivity. The room temperature magnetoresistance exhibits a
maximum as the peak temperature is increased by the substitution of Sr for Ca,
and a change in the field dependence to the resistivity at room temperature is
observed.Comment: 5 pages, 6 eps figures, to be published in Journal of Applied Physic
High Temperature Ferromagnetism with Giant Magnetic Moment in Transparent Co-doped SnO2-d
Occurrence of room temperature ferromagnetism is demonstrated in pulsed laser
deposited thin films of Sn1-xCoxO2-d (x<0.3). Interestingly, films of
Sn0.95Co0.05O2-d grown on R-plane sapphire not only exhibit ferromagnetism with
a Curie temperature close to 650 K, but also a giant magnetic moment of about 7
Bohr-Magneton/Co, not yet reported in any diluted magnetic semiconductor
system. The films are semiconducting and optically highly transparent.Comment: 12 pages, 4 figure
Transcriptional Activation of Antioxidants May Compensate for Selenoprotein Deficiences in \u3ci\u3eAmblyomma maculatum\u3c/i\u3e (Acari: Ixodidae) Injected With \u3ci\u3eselK\u3c/i\u3e- or \u3ci\u3eselM\u3c/i\u3e- dsRNA
The GulfāCoast tick, Amblyomma maculatum, possesses an elaborate set of selenoproteins, which prevent the deleterious effects from oxidative stress that would otherwise occur during feeding. In the current work, we examined the role of selenoprotein K (SelK) and selenoprotein M (SelM) in feeding A.āmaculatum by bioinformatics, transcriptional gene expression, RNA interference and antioxidant assays. The transcriptional expression of SelK did not vary significantly in salivary glands or midguts throughout the bloodmeal. However, there was a 58āfold increase in transcript levels of SelM in tick midguts. Ticks injected with selKādsRNA or selMādsRNA did not reveal any observable differences in egg viability but oviposition was reduced. Surprisingly, salivary antioxidant activity was higher in selenoprotein knockouts compared with controls, which is probably the result of compensatory transcriptional expression of genes involved in combating reactive oxygen species. In fact, quantitative realātime PCR data suggest that the transcriptional expression of catalase increased in ticks injected with selMādoubleāstranded RNA. Additionally, the transcriptional expression of selN decreased ā¼90% in both SelK/SelM knockdowns. These data indicate that SelK and SelM are salivary antioxidants but are not essential for tick survival or reproduction and are compensated by other antioxidant systems
Evaluation of selected chemical processes for production of low-cost silicon phase 2. silicon material task, low-cost silicon solar array project
Progress from October 1, 1977, through December 31, 1977, is reported in the design of the 50 MT/year experimental facility for the preparation of high purity silicon by the zinc vapor reduction of silicon tetrachloride in a fluidized bed of seed particles to form a free flowing granular product
A Molecular Dynamics Study of Monomer Melt Properties of Cyanate Ester Monomer Melt Properties
The objective of this work was to computationally predict the melting temperature and melt properties of thermosetting monomers used in aerospace applications. In this study, we applied an existing voids method by Solca. to examine four cyanate ester monomers with a wide range of melting temperatures. Voids were introduced into some simulations by removal of molecules from lattice positions to lower the free-energy barrier to melting to directly simulate the transition from a stable crystal to amorphous solid and capture the melting temperature. We validated model predictions by comparing melting temperature against previously reported literature values. Additionally, the torsion and orientational order parameters were used to examine the monomersā freedom of motion to investigate structureāproperty relationships. Ultimately, the voids method provided reasonable estimates of melting temperature while the torsion and order parameter analysis provided insight into sources of the differing melt properties between the thermosetting monomers. As a whole, the results shed light on how freedom of molecular motions in the monomer melt state may affect melting temperature and can be utilized to inspire the development of thermosetting monomers with optimal monomer melt properties for demanding applications
The atomic structure of large-angle grain boundaries and in and their transport properties
We present the results of a computer simulation of the atomic structures of
large-angle symmetrical tilt grain boundaries (GBs) (misorientation
angles \q{36.87}{^{\circ}} and \q{53.13}{^{\circ}}),
(misorientation angles \q{22.62}{^{\circ}} and \q{67.38}{^{\circ}}). The
critical strain level criterion (phenomenological criterion)
of Chisholm and Pennycook is applied to the computer simulation data to
estimate the thickness of the nonsuperconducting layer enveloping
the grain boundaries. The is estimated also by a bond-valence-sum
analysis. We propose that the phenomenological criterion is caused by the
change of the bond lengths and valence of atoms in the GB structure on the
atomic level. The macro- and micro- approaches become consistent if the
is greater than in earlier papers. It is predicted that the
symmetrical tilt GB \theta = \q{53.13}{^{\circ}} should demonstrate
a largest critical current across the boundary.Comment: 10 pages, 2 figure
Doctors and nurses subjective predictions of 6-month outcome compared to actual 6-month outcome for adult patients with spontaneous intracerebral haemorrhage (ICH) in neurocritical care: An observational study.
Acute spontaneous intracerebral haemorrhage is a devastating form of stroke. Prognostication after ICH may be influenced by clinicians' subjective opinions. To evaluate subjective predictions of 6-month outcome by clinicians' for ICH patients in a neurocritical care using the modified Rankin Scale (mRS) and compare these to actual 6-month outcome. We included clinicians' predictions of 6-month outcome in the first 48Ā h for 52 adults with ICH and compared to actual 6-month outcome using descriptive statistics and multilevel binomial logistic regression. 35/52 patients (66%) had a poor 6-month outcome (mRS 4-6); 19/52 (36%) had died. 324 predictions were included. For good (mRS 0-3) versus poor (mRS 4-6), outcome, accuracy of predictions was 68% and exact agreement 29%. mRS 6 and mRS 4 received the most correct predictions. Comparing job roles, predictions of death were underestimated, by doctors (12%) and nurses (13%) compared with actual mortality (36%). Predictions of vital status showed no significant difference between doctors and nurses: ORĀ =Ā 1.24 {CI; 0.50-3.05}; ( Ā =Ā 0.64) or good versus poor outcome: ORĀ =Ā 1.65 {CI; 0.98-2.79}; ( Ā =Ā 0.06). When predicted and actual 6-month outcome were compared, job role did not significantly relate to correct predictions of good versus poor outcome: ORĀ =Ā 1.13 {CI;0.67-1.90}; ( Ā =Ā 0.65) or for vital status: ORĀ =Ā 1.11 {CI; 0.47-2.61}; Ā =Ā 0.81). Early prognostication is challenging. Doctors and nurses were most likely to correctly predict poor outcome but tended to err on the side of optimism for mortality, suggesting an absence of clinical nihilism in relation to ICH. [Abstract copyright: Ā© 2024 The Authors. Published by Elsevier B.V.
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