Quantum Spin Holography with Surface State Electrons

In a recent paper Moon and coworkers [C.R. Moon et al., Nature Nanotechnology 4, 167 (2009)] have shown that the single-atom limit for information storage density can be overcome by using the coherence of electrons in a two-dimensional electron gas to produce quantum holograms comprised of individually manipulated molecules projecting an electronic pattern onto a portion of a surface. We propose to further extend the concept by introducing quantum spin holography - a version of quantum holographic encoding allowing to store the information in two spin channels independently.Comment: 5 pages, 3 figure

Confined bulk states as a long-range sensor for impurities and a transfer channel for quantum information

We show that confinement of bulk electrons can be observed at low-dimensional surface structures and can serve as a long-range sensor for the magnetism and electronic properties of single impurities or as a quantum information transfer channel with large coherence lengths. Our ab initio calculations reveal oscillations of electron density in magnetic chains on metallic surfaces and help to unambiguously identify the electrons involved as bulk electrons. We furthermore discuss the possibility of utilizing bulk state confinement to transfer quantum information, encoded in an atom's species or spin, across distances of several nanometers with high efficiency.Comment: 5 pages, 2 figure

Особливості адміністративно-територіальної реформи Польщі

Розглянуто адміністративно – територіальний устрій Польщі до проведення реформи 1998р. Проаналізовано адміністративно-територіальні перетворення, що відбулися в Польщі в результаті проведення реформи 1998р. Автор розглядає можливість використання польського досвіду, щодо зміни адміністративно – територіального устрою в Україні. The article deals with the administrative - territorial division of Poland to the reform of 1998. Analyzed administrative - territorial changes that took place in Poland as a result of the reform of 1998. The author examines the possibility of using the Polish experience to change the administrative - territorial structure of Ukraine

Relativistic peculiarities at stepped surfaces: surprising energetics and unexpected diffusion patterns

We revive intriguing, yet still unexplained, experimental results of Ehrlich and co-workers [ Phys. Rev. Lett. 77 1334 (1996); Phys. Rev. Lett. 67 2509 (1991)] who have observed, that 5d adatoms distributed on (111) surface islands of 5d metals favor the adsorption at the cluster's edge rather than at the cluster's interior, which lies in contrast with the behavior of 4d and 3d elements. Our state of the art ab initio calculations demonstrate that such behavior is a direct consequence of the relativity of 5d metals.Comment: 5 pages, 5 figure

Tailoring exchange interactions in engineered nanostructures: Ab initio study

We present a novel approach to spin manipulation in atomic-scale nanostructures. Our ab initio calculations clearly demonstrate that it is possible to tune magnetic properties of sub-nanometer structures by adjusting the geometry of the system. By the example of two surface-based systems we demonstrate that (i) the magnetic moment of a single adatom coupled to a buried magnetic Co layer can be stabilized in either a ferromagnetic or an antiferromagnetic configuration depending on the spacer thickness. It is found that a buried Co layer has a profound effect on the exchange interaction between two magnetic impurities on the surface. (ii) The exchange interaction between magnetic adatoms can be manipulated by introducing artificial nonmagnetic Cu chains to link them.Comment: 4 pages, submitted to PR

Potential Energy Driven Spin Manipulation via a Controllable Hydrogen Ligand

Spin-bearing molecules can be stabilized on surfaces and in junctions with desirable properties such as a net spin that can be adjusted by external stimuli. Using scanning probes, initial and final spin states can be deduced from topographic or spectroscopic data, but how the system transitioned between these states is largely unknown. Here we address this question by manipulating the total spin of magnetic cobalt hydride complexes on a corrugated boron nitride surface with a hydrogen- functionalized scanning probe tip by simultaneously tracking force and conductance. When the additional hydrogen ligand is brought close to the cobalt monohydride, switching between a corre- lated S = 1 /2 Kondo state, where host electrons screen the magnetic moment, and a S = 1 state with magnetocrystalline anisotropy is observed. We show that the total spin changes when the system is transferred onto a new potential energy surface defined by the position of the hydrogen in the junction. These results show how and why chemically functionalized tips are an effective tool to manipulate adatoms and molecules, and a promising new method to selectively tune spin systems

Catalytic molecularly imprinted polymer membranes: Development of the biomimetic sensor for phenols detection

Portable biomimetic sensor devices for the express control of phenols content in water were developed. The synthetic binding sites mimicking active site of the enzyme tyrosinase were formed in the structure of free-standing molecularly imprinted polymer membranes. Molecularly imprinted polymer membranes with the catalytic activity were obtained by co-polymerization of the complex Cu (II)–catechol–urocanic acid ethyl ester with (tri)ethyleneglycoldimethacrylate, and oligourethaneacrylate. Addition of the elastic component oligourethaneacrylate provided formation of the highly cross-linked polymer with the catalytic activity in a form of thin, flexible, and mechanically stable membrane. High accessibility of the artificial catalytic sites for the interaction with the analyzed phenol molecules was achieved due to addition of linear polymer (polyethyleneglycol Mw 20,000) to the initial monomer mixture before the polymerization. As a result, typical semi-interpenetrating polymer networks (semi-IPNs) were formed. The cross-linked component of the semi-IPN was represented by the highly cross-linked catalytic molecularly imprinted polymer, while the linear one was represented by polyethyleneglycol Mw 20,000. Extraction of the linear polymer from the fully formed semi-IPN resulted in formation of large pores in the membranes’ structure. Concentration of phenols in the analyzed samples was detected using universal portable device oxymeter with the oxygen electrode in a close contact with the catalytic molecularly imprinted polymer membrane as a transducer. The detection limit of phenols detection using the developed sensor system based on polymers–biomimics with the optimized composition comprised 0.063 mM, while the linear range of the sensor comprised 0.063–1 mM. The working characteristics of the portable sensor devices were investigated. Storage stability of sensor systems at room temperature comprised 12 months (87%). As compared to traditional methods of phenols detection the developed sensor system is characterized by simplicity of operation, compactness, an

Tailoring exchange interactions in engineered nanostructures: Ab initio study

We present a novel approach to spin manipulation in atomic-scale nanostructures. Our ab initio calculations clearly demonstrate that it is possible to tune magnetic properties of sub-nanometer structures by adjusting the geometry of the system. By the example of two surface-based systems we demonstrate that (i) the magnetic moment of a single adatom coupled to a buried magnetic Co layer can be stabilized in either a ferromagnetic or an antiferromagnetic configuration depending on the spacer thickness. It is found that a buried Co layer has a profound effect on the exchange interaction between two magnetic impurities on the surface. (ii) The exchange interaction between magnetic adatoms can be manipulated by introducing artificial nonmagnetic Cu chains to link them.Comment: 4 pages, submitted to PR