Ferropericlase inclusions in ultradeep diamonds from Sao Luiz (Brazil): High Li abundances and diverse Li-isotope and trace element compositions suggest an origin from a subduction mélange

The most remarkable feature of the inclusion suite in ultradeep alluvial and kimberlitic diamonds from Sao Luiz (Juina area in Brazil) is the enormous range in Mg# [100xMg/(Mg + Fe)] of the ferropericlases (fper). The Mg-richer ferropericlases are from the boundary to the lower mantle or from the lower mantle itself when they coexist with ringwoodite or Mg- perovskite (bridgmanite). This, however, is not an explanation for the more Fe-rich members and a lowermost mantle or a “D” layer origin has been proposed for them. Such a suggested ultra-deep origin separates the Fe-rich fper-bearing diamonds from the rest of the Sao Luiz ultradeep diamond inclusion suite, which also contains Ca-rich phases. These are now thought to have an origin in the uppermost lower mantle and in the transition zone and to belong either to a peridotitic or mafic (subducted oceanic crust) protolith lithology. We analysed a new set of more Fe-rich ferropericlase inclusions from 10 Sao Luiz ultradeep alluvial diamonds for their Li isotope composition by solution MC-ICP-MS (multi collector inductively coupled plasma mass spectrometry), their major and minor elements by EPMA (electron probe micro-analyser) and their Li-contents by SIMS (secondary ion mass spectrometry), with the aim to understand the origin of the ferropericlase protoliths. Our new data confirm the wide range of ferropericlase Mg# that were reported before and augment the known lack of correlation between major and minor elements. Four pooled ferropericlase inclusions from four diamonds provided sufficient material to determine for the first time their Li isotope composition, which ranges from δ7Li + 9.6 ‰ to −3.9 ‰. This wide Li isotopic range encompasses that of serpentinized ocean floor peridotites including rodingites and ophicarbonates, fresh and altered MORB (mid ocean ridge basalt), seafloor sediments and of eclogites. This large range in Li isotopic composition, up to 5 times higher than ‘primitive upper mantle’ Li-abundances, and an extremely large and incoherent range in Mg# and Cr, Ni, Mn, Na contents in the ferropericlase inclusions suggests that their protoliths were members of the above lithologies. This mélange of altered rocks originally contained a variety of carbonates (calcite, magnesite, dolomite, siderite) and brucite as the secondary products in veins and as patches and Ca-rich members like rodingites and ophicarbonates. Dehydration and redox reactions during or after deep subduction into the transition zone and the upper parts of the lower mantle led to the formation of diamond and ferropericlase inclusions with variable compositions and a predominance of the Ca-rich, high-pressure silicate inclusions. We suggest that the latter originated from peridotites, mafic rocks and sedimentary rocks as redox products between calcite and SiO2

Rapid eclogitisation of the Dabie–Sulu UHP terrane: Constraints from Lu–Hf garnet geochronology

AbstractThe Qinling–Dabie–Sulu orogenic belt in eastern China is one of the largest ultrahigh-pressure (UHP) terranes worldwide. Mineral Sm–Nd- and zircon U–Pb dating has been widely used to reveal the metamorphic history of this collisional orogen. However, the exact timing of the UHP metamorphic event(s) remains controversial and ages ranging from 245 Ma to 220 Ma have been suggested. We present high precision garnet–cpx Lu–Hf ages for six eclogites from the Dabie and Sulu areas. All ages fall in a narrow range between 219.6 and 224.4 Ma. Five samples define a mean age of 223.0±0.9 Ma and one sample yields a slightly younger age of 219.6±1.4 Ma. This very tight age range is particularly remarkable considering the large regional distribution of sample localities (on the order of 100 km at the time of UHP metamorphism) and the wide variety of garnet and eclogite chemical compositions represented. Two samples yield Sm–Nd ages that are indistinguishable from their Lu–Hf ages, albeit with larger uncertainties.The identical ages of eclogites from both the Dabie and the Sulu region emphasize their close genetic relationship and similar metamorphic histories. The Lu–Hf results appear to date a punctuated event of garnet growth. Alternatively, the Lu–Hf garnet ages may represent the onset of rapid, contemporaneous uplift and subsequent cooling. However, trace element zoning of Lu and Hf is still preserved in garnet porphyroblasts, even in those with a homogeneous major element distribution. Thus, complete re-equilibration of the Lu–Hf system during peak-temperature conditions probably did not occur. The garnet forming event can be placed toward the final stage of the UHP metamorphism, in agreement with some published U–Pb zircon ages. A possible trigger for this short-lived and widespread mineral growth episode may have been a fluid that became available at that stage of the metamorphic history. Although HREE-depleted patterns of older zircon grains may indicate the presence of an older generation of garnet, complete eclogitisation may have been inhibited during the major part of the prograde P–T path due to dry conditions during most of the UHP metamorphism. The uniform Lu–Hf (and Sm–Nd) ages of all investigated Dabie and Sulu eclogites suggest that garnet growth and thus possibly fluid availability were limited to a short time interval over a remarkably large regional scale

Implementation of Internet-based preventive interventions for depression and anxiety: role of support? The design of a randomized controlled trial

<p>Abstract</p> <p>Background</p> <p>Internet-based self-help is an effective preventive intervention for highly prevalent disorders, such as depression and anxiety. It is not clear, however, whether it is necessary to offer these interventions with professional support or if they work without any guidance. In case support is necessary, it is not clear which level of support is needed. This study examines whether an internet-based self-help intervention with a coach is more effective than the same intervention without a coach in terms of clinical outcomes, drop-out and economic costs. Moreover, we will investigate which level of support by a coach is more effective compared to other levels of support.</p> <p>Methods</p> <p>In this randomized controlled trial, a total of 500 subjects (18 year and older) from the general population with mild to moderate depression and/or anxiety will be assigned to one of five conditions: (1) web-based problem solving through the internet (self-examination therapy) without a coach; (2) the same as 1, but with the possibility to ask help from a coach on the initiative of the respondent (on demand, by email); (3) the same as 1, but with weekly scheduled contacts initiated by a coach (once per week, by email); (4) weekly scheduled contacts initiated by a coach, but no web-based intervention; (5) information only (through the internet). The interventions will consist of five weekly lessons. Primary outcome measures are symptoms of depression and anxiety. Secondary outcome measures are drop-out from the intervention, quality of life, and economic costs. Other secondary outcome measures that may predict outcome are also studied, e.g. client satisfaction and problem-solving skills. Measures are taken at baseline (pre-test), directly after the intervention (post-test, five weeks after baseline), 3 months later, and 12 months later. Analysis will be conducted on the intention-to-treat sample.</p> <p>Discussion</p> <p>This study aims to provide more insight into the clinical effectiveness, differences in drop-out rate and costs between interventions with and without support, and in particular different levels of support. This is important to know in relation to the dissemination of internet-based self-help interventions.</p> <p>Trial Registration</p> <p>Nederlands Trial Register (NTR): TC1355</p

Steady state geotherm, thermal disturbances, and tectonic development of the lower lithosphere underneath the Gibeon Kimberlite Province, Namibia

The Gibeon Kimberlite Province of southern Namibia comprises more than 75 group I kimberlite pipes and dykes. From the Gibeon Townsland 1 pipe, 38 upper mantle xenoliths (23 garnet lherzolites and 15 garnet harzburgites) were collected and minerals were analysed by electron microprobe for major elements. Pressures and temperatures of crystallisation for xenoliths with either coarse equant, porphyroclastic and mosaic-porphyroclastic textures were estimated by a number of combinations of geothermometers and geobarometers judged to be reliable and accurate for peridotites by Prey and Kohler (1990): The P-T estimates for equilibrated xenoliths agree within the errors of the methods and plot within the stability field of graphite. The P-T values for coarse equant xenoliths fall close to a geothermal gradient of about 44 mW/m(2) within a very restricted pressure range. The porphyroclastic xenoliths yield similar and higher temperatures at similar depths. In these xenoliths Ca in orthopyroxene and Ca in olivine increase towards the rims and are high in the neoblasts indicating a stage of transient heating at depth. The mosaic-porphyroclastic xenolith minerals yield the highest temperatures, are unzoned and indicate internal mineral equilibrium. The depth of origin for the xenoliths from Gibeon Townsland 1 ranges from 100 to 140 km. The ``cold``, coarse equant peridotites are relatively enriched garnet lherzolites with comparatively (to the ``hot`` peridotites) low modal orthopyroxene contents, whereas the ``hot``, mosaic-porphyroclastic peridotites are depleted garnet harzburgites with high modal amounts of orthopyroxene. This is opposite to the findings for peridotites from the Kaapvaal craton where the cold peridotites are depleted harzburgites with high modal orthopyroxene and many of the hot peridotites are fertile lherzolites with low modal abundance of orthopyroxene. We present a model in which the high temperature, depleted garnet harzburgites are equated to the cold, coarse equant peridotites from the Kaapvaal craton. It is envisaged that this material was detached and transported laterally by an upwelling, deflected plume

Accessories in Kaiserstuhl carbonatites and related rocks as accurate and faithful recorders of whole rock age and isotopic composition

The accessories perovskite, pyrochlore, zirconolite, calzirtite and melanite from carbonatites and carbonate-rich foidites from the Kaiserstuhl are variously suited for the in situ determination of their U–Pb ages and Sr, Nd- and Hf-isotope ratios by LA-ICP-MS. The 143Nd/144Nd ratios may be determined precisely in all five phases, the 176Hf/177Hf ratios only in calzirtite and the 87Sr/86Sr ratios in perovskites and pyrochlores. The carbonatites and carbonate-rich foidites belong to one of the three magmatic groups that Schleicher et al. (1990) distinguished in the Kaiserstuhl on the basis of their Sr, Nd and Pb isotope ratios. Tephrites, phonolites and essexites (nepheline monzogabbros) form the second and limburgites (nepheline basanites) and olivine nephelinites the third. Our 87Sr/86Sr isotope data from the accessories overlap with the carbonatite and olivine nephelinite fields defined by Schleicher et al. (1990) but exhibit a much narrower range. These and the εNd and εHf values plot along the mantle array in the field of oceanic island basalts relatively close to mid-ocean ridge basalts. Previously reported K–Ar, Ar–Ar and fission track ages for the Kaiserstuhl lie between 16.2 and 17.8 Ma. They stem entirely from the geologically older tephrites, phonolites and essexites. No ages existed so far for the geologically younger carbonatites and carbonate-rich foidites except for one apatite fission track age (15.8 Ma). We obtained precise U–Pb ages for zirconolites and calzirtites of 15.66, respectively 15.5 Ma (± 0.1 2σ) and for pyrochlores of 15.35 ± 0.24 Ma. Only the perovskites from the Badberg soevite yielded a U–P concordia age of 14.56 ± 0.86 Ma while the perovskites from bergalites (haüyne melilitites) only gave 206Pb/238U and 208Pb/232Th ages of 15.26 ± 0.21, respectively, 15.28 ± 0.48 Ma. The main Kaiserstuhl rock types were emplaced over a time span of 1.6 Ma almost 1 million years before the carbonatites and carbonate-rich foidites. These were emplaced within only 0.32 Ma.Frankfurt Institute for Advanced Studies (FIAS) (4401

The origin of the diamonds from the Panda Kimberlite pipe, NWT

http://easweb.eas.ualberta.ca/index.php?page=5&id=376

Mineral inclusions in diamonds from the Panda kimberlite, Slave Province, Canada.

The composition of the lithospheric and sublithospheric mantle beneath the Slave craton was investigated, using 88 diamonds and their mineral inclusion. The inclusions were analyzed using electron (major elements) and ion micro probes (trace and ultra-trace elements. Major element data show that the majority of inclusions belongs to the peridotitic suite and suggests formation in a moderately depleted environment, without indications for low Ca-harzburgitic and dunitic sources. Garnet-olivine, garnet-opx and Zn in spinel geothermobarometry indicate diamond formation under P-T conditions and along a geothermal gradient (40-42 mW/m2) similar to other cratons worldwide. Touching inclusion pairs appear to have equilibrated at lower temperatures corresponding to a geothermal gradient of around 37 mW/m2 (surface heat flow). A similar Cretaceous to Tertiary palaeo-geotherm was found for garnet peridotite xenoliths from the Lac de Gras area. This apparent discrepancy possibly relates to partly low aggregation levels of nitrogen impurities within Panda diamonds which suggest a drop in temperature by at least 100°C soon after diamond formation. Eclogitic mineral inclusions are rare in Panda diamonds, similar other kimberlites within the Ekati property and Snap Lake but in contrast to DO27. Beside the lithospheric inclusions three diamonds contain phases that indicate a possible origin from the lower mantle. The characteristic inclusion phase in these diamonds is ferropericlase. In one case ferropericlase is associated with CaSi-perovskite, in a second sample with a SiO2-phase. Another diamond contained a touching inclusion pair of ferropericlase and MgAl-spinel (with minor amounts of Fe and Cr). This spinel probably originated as epsilon-spinel, a lower mantle phase experimentally predicted for corundum saturated bulk compositions. A characteristic feature of all assumed lower mantle diamonds is an irregular crystal shape in combination with nitrogen concentrations below detection (Type II diamonds). REE concentrations in ten peridotitic garnets indicate that the trace element pattern is in general agreement with the major element composition. Lherzolitic garnets show MREEN-HREEN enriched or slightly sinusoidal REE pattern, whereas harzburgitic garnets derived from depleted lithologies show sinusoidal shapes. Only one harzburgitic garnet shows an overall enriched REE pattern and an additional enrichment in Zr and Y. Combined enrichment in MREE-HREE and other HFSE is taken as evidence that metasomatic overprint in this case was caused by a silicate melt. A model for the evolution of the lithospheric and sublithospheric mantle beneath the Slave craton involves an early stage of melt depletion of a primitive source in the spinel stability field, causing the high Cr/Al ratios in garnets, typical for peridotitic garnets worldwide. In a second stage the depleted mantle is stacked beneath the early Slave craton and successively re-enriched in major and trace elements. The high geothermal regime for the separate inclusions and the inferred “rapid” cooling after diamond formation may relate diamond preciptitation and mantle metasomatism to short lived thermal perturbations (magmatic intrusions), which may also have introduced the sublithospheric diamond suite

Chalcophile and siderophile elements in sulphide inclusions in eclogitic diamonds and metal cycling in a Paleoproterozoic subduction zone

In the central Slave craton, eclogitic diamonds are suggested to have formed during Paleoproterozoic subduction in a meta-gabbroic substrate representing former lower oceanic crust that interacted with serpentinite-derived fluids at high fluid-rock ratios. In order to assess the behaviour of chalcophile and siderophile elements (CSE) during this process, we measured trace-element concentrations of sulphide inclusions in diamonds from the Diavik mine by laser ablation ICPMS. The nitrogen systematics of the diamonds (average N concentration of similar to 600 ppm and aggregation state 4% N as B-aggregates) indicate average mantle residence temperatures of similar to 1050 degrees C for a 1.85 Ga formation age, corresponding similar to 170 km depth. Based on the available evidence from natural samples and experiments, we suggest that the highly siderophile elements (HSE: Os, Ir, Ru, Rh, Pd, Pt, Re) except Au behaved largely conservatively during fluid-induced metamorphism, which may point to a reducing and Cl-poor nature of the fluid. The abundances of the moderately siderophile and chalcophile elements Cr, Co, Ni, Cu, Ag, Sn, Mo and W may also have changed little, whereas As, Sb, Tl, Pb and Bi may have been mobilised from the subducting lower oceanic crust. The partitioning of CSE in eclogite and geochemical behaviour during oceanic crust formation was assessed for inferred conservative elements. Assuming an average sulphide mode of 0.3 wt.% for the oceanic crust, its abundances of HSE, Cu, Mo, Se and Te can mostly be accounted for by sulphide minerals alone. Lithophile behaviour of W, Cd, In and Sn and enrichment in residual melts may explain their lower abundances in the gabbroic eclogitic sulphide inclusions compared to MORB sulphide. These elements, as well as Cr, Co, Ni, Zn and Ga require additional host phases both in eclogite, where rutile partitions significant amounts of Cr, Zn, W, Ga and Sn, and in the oceanic crust.22 page(s