463 research outputs found
Financial work incentives in Britain: comparisons over time and between family types
This paper reviews various techniques for quantifying financial incentives to work, shows how financial work incentives have changed across the population since 1979, and estimates how much of these changes are due to changes in the tax and benefit system.
Quantitative NMR monitoring of liquid ingress into repellent heterogeneous layered fabrics
Fabrics which are water repellent and repellent to other liquids are often constructed using multiple layers of material. Such a construction is preferable to a single layer of a liquid-repellent textile because, under the action of an applied pressure, ingress of a liquid through the first layer can be halted by the second or subsequent layers. In the quantitative investigation of this problem, current techniques provide limited information on the progress and distribution of the liquid as it ingresses into a fabric. Moreover, many techniques require that the material is delaminated prior to analysis, and cannot be conducted in real time to measure the progress of a liquid through the textile substrate. In this work we demonstrate that unilateral NMR, which allows signal to be collected from a volume of interest in a material residing above the instrument, can be a powerful tool to quantitatively monitor the ingress of a liquid through a layered sample exhibiting pronounced heterogeneities in repellency. A known volume of oil was placed on the top of a model textile sample composed of three 80 ÎŒm thick layers. Spatially resolved one dimensional vertical NMR profiles of the system were acquired as a function of the pressure vertically applied to the top of the sample. These profiles show that the absolute liquid volume present in each layer of textile can routinely be measured within 4 min with a spatial resolution of 15 ÎŒm. If each individual layer exhibits different repellency to the test liquid, the complexity of the dynamics of the ingress can be investigated in great detail. An elegant application of the unilateral instrument was obtained in which the sensitive volume matched the region of interest of the individual layers of the textile under investigation
The Protective Effect of Male Circumcision as a Faith Lift for the Troubled Paradigm of HIV Epidemiology in Sub-Saharan Africa
Procedural Guide for Establishing an Electronic Data Processing System in a Food Service Organization
Food, Nutrition and Institution Administratio
Doubly Robust Inference when Combining Probability and Non-probability Samples with High-dimensional Data
Non-probability samples become increasingly popular in survey statistics but
may suffer from selection biases that limit the generalizability of results to
the target population. We consider integrating a non-probability sample with a
probability sample which provides high-dimensional representative covariate
information of the target population. We propose a two-step approach for
variable selection and finite population inference. In the first step, we use
penalized estimating equations with folded-concave penalties to select
important variables for the sampling score of selection into the
non-probability sample and the outcome model. We show that the penalized
estimating equation approach enjoys the selection consistency property for
general probability samples. The major technical hurdle is due to the possible
dependence of the sample under the finite population framework. To overcome
this challenge, we construct martingales which enable us to apply Bernstein
concentration inequality for martingales. In the second step, we focus on a
doubly robust estimator of the finite population mean and re-estimate the
nuisance model parameters by minimizing the asymptotic squared bias of the
doubly robust estimator. This estimating strategy mitigates the possible
first-step selection error and renders the doubly robust estimator root-n
consistent if either the sampling probability or the outcome model is correctly
specified
Recommended from our members
Supramolecular self-assembled network formation containing N···Br halogen bonds in physisorbed overlayers.
The formation of a halogen bonded self-assembled co-crystal physisorbed monolayer containing N···Br interactions is reported for the first time. The co-crystal monolayer is identified experimentally by synchrotron X-ray diffraction and the structure determined. Density functional theory (DFT) calculations are also employed to assess the magnitudes of the different interactions in the layer. Significantly, compared to other halogen bonds in physisorbed monolayers we have reported recently, the N···Br bond here is found to be non-linear. It is proposed that the increasing importance of the lateral hydrogen bond interactions, relative to the halogen bond strength, leads to the bending of the halogen bonds.We acknowledge financial support for AB from EPSRC DTA award from the Department of Chemistry, University of Cambridge. We acknowledge Diamond Light Source for time on beamline I11 under proposals EE6511 and EE7761.This is the final version of the article. It first appeared from the Royal Society of Chemistry via http://dx.doi.org/10.1039/C4CP03379
Infrared spectra and fragmentation dynamics of isotopologue-selective mixed-ligand complexes â
Isolated mixed-ligand complexes provide tractable model systems in which to study competitive and cooperative binding effects as well as controlled energy flow. Here, we report spectroscopic and isotopologue-selective infrared photofragmentation dynamics of mixed gas-phase Au(12/13CO)n(N2O)m+ complexes. The rich infrared action spectra, which are reproduced well using simulations of calculated lowest energy structures, clarify previous ambiguities in the assignment of vibrational bands, especially accidental coincidence of CO and N2O bands. The fragmentation dynamics exhibit the same unexpected behaviour as reported previously in which, once CO loss channels are energetically accessible, these dominate the fragmentation branching ratios, despite the much lower binding energy of N2O. We have investigated the dynamics computationally by considering anharmonic couplings between a relevant subset of normal modes involving both ligand stretch and intermolecular modes. Discrepancies between correlated and uncorrelated model fit to the ab initio potential energy curves are quantified using a Boltzmann sampled root mean squared deviation providing insight into efficiency of vibrational energy transfer between high frequency ligand stretches and the softer intermolecular modes which break during fragmentation
Planet Hunters VII. Discovery of a New Low-Mass, Low-Density Planet (PH3 c) Orbiting Kepler-289 with Mass Measurements of Two Additional Planets (PH3 b and d)
We report the discovery of one newly confirmed planet ( days,
) and mass determinations of two previously
validated Kepler planets, Kepler-289 b ( days,
) and Kepler-289-c ( days,
), through their transit timing variations
(TTVs). We also exclude the possibility that these three planets reside in a
Laplace resonance. The outer planet has very deep (), high
signal-to-noise transits, which puts extremely tight constraints on its host
star's stellar properties via Kepler's Third Law. The star PH3 is a young
( Gyr as determined by isochrones and gyrochronology), Sun-like star
with , , and
K. The middle planet's large TTV amplitude (
hours) resulted either in non-detections or inaccurate detections in previous
searches. A strong chopping signal, a shorter period sinusoid in the TTVs,
allows us to break the mass-eccentricity degeneracy and uniquely determine the
masses of the inner, middle, and outer planets to be ,
, and , which we designate PH3 b, c, and
d, respectively. Furthermore, the middle planet, PH3 c, has a relatively low
density, g/cm for a planet of its mass, requiring a
substantial H/He atmosphere of by mass, and joins a
growing population of low-mass, low-density planets.Comment: 21 pages, 10 figures, 5 tables, accepted into Ap
Planet Hunters. V. A Confirmed Jupiter-Size Planet in the Habitable Zone and 42 Planet Candidates from the Kepler Archive Data
We report the latest Planet Hunter results, including PH2 b, a Jupiter-size
(R_PL = 10.12 \pm 0.56 R_E) planet orbiting in the habitable zone of a
solar-type star. PH2 b was elevated from candidate status when a series of
false positive tests yielded a 99.9% confidence level that transit events
detected around the star KIC 12735740 had a planetary origin. Planet Hunter
volunteers have also discovered 42 new planet candidates in the Kepler public
archive data, of which 33 have at least three transits recorded. Most of these
transit candidates have orbital periods longer than 100 days and 20 are
potentially located in the habitable zones of their host stars. Nine candidates
were detected with only two transit events and the prospective periods are
longer than 400 days. The photometric models suggest that these objects have
radii that range between Neptune to Jupiter. These detections nearly double the
number of gas giant planet candidates orbiting at habitable zone distances. We
conducted spectroscopic observations for nine of the brighter targets to
improve the stellar parameters and we obtained adaptive optics imaging for four
of the stars to search for blended background or foreground stars that could
confuse our photometric modeling. We present an iterative analysis method to
derive the stellar and planet properties and uncertainties by combining the
available spectroscopic parameters, stellar evolution models, and transiting
light curve parameters, weighted by the measurement errors. Planet Hunters is a
citizen science project that crowd-sources the assessment of NASA Kepler light
curves. The discovery of these 43 planet candidates demonstrates the success of
citizen scientists at identifying planet candidates, even in longer period
orbits with only two or three transit events.Comment: 35 pages, 11 figures, 6 tables, accepted and published on ApJ ApJ,
776, 1
- âŠ