EPR identification of defects responsible for thermoluminescence in Cu-doped lithium tetraborate (Li2B4O7) crystals

Electron paramagnetic resonance (EPR) is used to identify the electron and hole traps responsible for thermoluminescence (TL) peaks occurring near 100 and 200 ◦C in copper-doped lithium tetraborate (Li2B4O7) crystals. As-grown crystals have Cu+ and Cu2+ ions substituting for lithium and have Cu+ ions at interstitial sites. All of the substitutional Cu2+ ions in the as-grown crystals have an adjacent lithium vacancy and give rise to a distinct EPR spectrum. Exposure to ionizing radiation at room temperature produces a second and different Cu2+ EPR spectrum when a hole is trapped by substitutional Cu+ ions that have no nearby defects. These two Cu2+ trapped-hole centers are referred to as Cu2+-VLi and Cu2+active, respectively. Also during the irradiation, two trapped-electron centers in the form of interstitial Cu0 atoms are produced when interstitial Cu+ ions trap electrons. They are observed with EPR and are labeled Cu0A and Cu0B. When an irradiated crystal is warmed from 25 to 150 ◦C, the Cu2+active centers have a partial decay step that correlates with the TL peak near 100 ◦C. The concentrations of Cu0A and Cu0B centers, however, increase as the crystal is heated through this range. As the crystal is futher warmed between 150 and 250 ◦C, the EPR signals from the Cu2+active hole centers and Cu0A and Cu0B electron centers decay simultaneously. This decay step correlates with the intense TL peak near 200 ◦C

Insertion of Lithium Ions into TiO\u3csub\u3e2\u3c/sub\u3e (rutile) Crystals: An Electron Paramagnetic Resonance Study of the Li-associated Ti\u3csup\u3e3+\u3c/sup\u3e Small Polaron

Electron paramagnetic resonance (EPR) and electron-nuclear double resonance (ENDOR) are used to identify a Ti3+-Li+ complex in TiO2 crystals having the rutile structure. This defect consists of an interstitial Li+ ion adjacent to a substitutional Ti3+ ion (the unpaired electron on the Ti3+ ion provides charge compensation for the Li+ ion). The neutral Ti3+-Li+ complex is best described as a donor-bound small polaron and is similar in structure to the recently reported neutral fluorine and hydrogen donors in TiO2 (rutile). Lithium ions are diffused into the crystals at temperatures near 450 °C. Following the diffusion, an EPR spectrum containing groups of four closely spaced lines is observed at 36 K without laser illumination. ENDOR data verify that the four lines within each group are due to a weak hyperfine interaction with one lithium nucleus. Spin-Hamiltonian parameters are obtained from the angular dependence of the EPR spectra. Principal values are 1.9688, 1.9204, and 1.9323 for the g matrix and –2.14, –2.20, and +3.44 MHz for the 7Li hyperfine matrix

Hydrogen Donors and Ti\u3csup\u3e3+\u3c/sup\u3e ions in reduced TiO\u3csub\u3e2\u3c/sub\u3e crystals

Electron paramagnetic resonance (EPR) and electron-nuclear double resonance (ENDOR) are used to identify and characterize the neutral hydrogen donor in TiO2 crystals having the rutile structure. These spectra are best observed near 5 K. The neutral donors are present without photoexcitation in crystals that have been slightly reduced at high temperature in a nitrogen atmosphere. The same defects can be photoinduced at low temperature in oxidized crystals. The neutral hydrogen donor in this lattice consists of a substitutional Ti3+ ion adjacent to a substitutional OH– molecular ion. The axis of the OH– molecule lies in the basal plane with the hydrogen ion extending out from the oxygen in a direction perpendicular to the Ti-O bonds. Spin-Hamiltonian parameters are obtained from the angular dependence of the EPR and ENDOR spectra (principal values are 1.9732, 1.9765, and 1.9405 for the g matrix and –0.401, + 0.616, and –0.338 MHz for the 1H hyperfine matrix). The principal axis associated with the + 0.616 MHz principal value is in the basal plane 22.9° from a [110] direction and the principal axis associated with the –0.338 MHz principal value is along the [001] direction. Our results show that interstitial Ti3+ ions are not the dominant shallow donors in slightly reduced TiO2 (rutile) crystals

EPR identification of defects responsible for thermoluminescence in Cu-doped lithium tetraborate (Li2B4O7) crystals

Electron paramagnetic resonance (EPR) is used to identify the electron and hole traps responsible for thermoluminescence (TL) peaks occurring near 100 and 200 ◦C in copper-doped lithium tetraborate (Li2B4O7) crystals. As-grown crystals have Cu+ and Cu2+ ions substituting for lithium and have Cu+ ions at interstitial sites. All of the substitutional Cu2+ ions in the as-grown crystals have an adjacent lithium vacancy and give rise to a distinct EPR spectrum. Exposure to ionizing radiation at room temperature produces a second and different Cu2+ EPR spectrum when a hole is trapped by substitutional Cu+ ions that have no nearby defects. These two Cu2+ trapped-hole centers are referred to as Cu2+-VLi and Cu2+active, respectively. Also during the irradiation, two trapped-electron centers in the form of interstitial Cu0 atoms are produced when interstitial Cu+ ions trap electrons. They are observed with EPR and are labeled Cu0A and Cu0B. When an irradiated crystal is warmed from 25 to 150 ◦C, the Cu2+active centers have a partial decay step that correlates with the TL peak near 100 ◦C. The concentrations of Cu0A and Cu0B centers, however, increase as the crystal is heated through this range. As the crystal is futher warmed between 150 and 250 ◦C, the EPR signals from the Cu2+active hole centers and Cu0A and Cu0B electron centers decay simultaneously. This decay step correlates with the intense TL peak near 200 ◦C

Oxygen Vacancies Adjacent to Cu(2+) Ions in TiO(2) (Rutile) Crystals

Electron paramagnetic resonance (EPR) and electron-nuclear double resonance (ENDOR) are used to characterize Cu2+ ions substituting for Ti4+ ions in nominally undoped TiO2 crystals having the rutile structure. Illumination at 25 K with 442 nm laser light reduces the concentration of Cu2+ ions by more than a factor of 2. The laser light also reduces the EPR signals from Fe3+ and Cr3+ ions and introduces signals from Ti3+ ions. Warming in the dark to room temperature restores the crystal to its preilluminated state. Monitoring the recovery of the photoinduced changes in the Cu2+ ions and the other paramagnetic electron and hole traps as the temperature is raised from 25 K to room temperature provides evidence that the Cu2+ ions have an adjacent doubly ionized oxygen vacancy. These oxygen vacancies serve as charge compensators for the substitutional Cu2+ ions and lead to the formation of electrically neutral Cu2+-VO complexes during growth of the crystals. The Cu2+-VO complexes act as electron traps and convert to nonparamagnetic Cu+-VO complexes when the crystals are illuminated at low temperature. Complete sets of spin-Hamiltonian parameters describing the electron Zeeman, hyperfine, and nuclear electric quadrupole interactions for both the 63Cu and 65Cu nuclei are obtained from the EPR and ENDOR data. This study suggests that other divalent cation impurities in TiO2 such as Co2+ and Ni2+ may also have an adjacent oxygen vacancy for charge compensation

The Relation Between Quasar and Merging Galaxy Luminosity Functions and the Merger-Induced Star Formation Rate of the Universe

Using a model for self-regulated growth of black holes (BHs) in mergers involving gas-rich galaxies, we study the relationship between quasars and the population of merging galaxies and predict the merger-induced star formation rate density of the Universe. Mergers drive nuclear gas inflows, fueling starbursts and 'buried quasars' until accretion feedback expels the gas, rendering a briefly visible optical quasar. Star formation is shut down and accretion declines, leaving a passively evolving remnant with properties typical of red, elliptical galaxies. Based on evolution of these events in our simulations, we demonstrate that the observed statistics of merger rates, luminosity functions (LFs) and mass functions, SFR distributions, specific SFRs, quasar and quasar host galaxy LFs, and elliptical/red galaxy LFs are self-consistent and follow from one another as predicted by the merger hypothesis. We use our simulations to de-convolve both quasar and merging galaxy LFs to determine the birthrate of black holes of a given final mass and merger rates as a function of stellar mass. We use this to predict the merging galaxy LF in several observed wavebands, color-magnitude relations, mass functions, absolute and specific SFR distributions and SFR density, and quasar host galaxy LFs, as a function of redshift from z=0-6. We invert this and predict e.g. quasar LFs from observed merger LFs or SFR distributions. Our results agree well with observations, but idealized models of quasar lightcurves are ruled out by comparison of merger and quasar observations at >99.9% confidence. Using only observations of quasars, we estimate the contribution of mergers to the SFR density of the Universe even to high redshifts z~4.Comment: 26 pages, 15 figures, matches version accepted to Ap

A Theoretical Interpretation of the Black Hole Fundamental Plane

We examine the origin and evolution of correlations between properties of supermassive black holes (BHs) and their host galaxies using simulations of major galaxy mergers, including the effects of gas dissipation, cooling, star formation, and BH accretion and feedback. We demonstrate that the simulations predict the existence of a BH 'fundamental plane' (BHFP), of the form M_BH sigma^(3.0+-0.3)*R_e^(0.43+-0.19) or M_BH M_bulge^(0.54+-0.17)*sigma^(2.2+-0.5), similar to relations found observationally. The simulations indicate that the BHFP can be understood roughly as a tilted intrinsic correlation between BH mass and spheroid binding energy, or the condition for feedback coupling to power a pressure-driven outflow. While changes in halo circular velocity, merger orbital parameters, progenitor disk redshifts and gas fractions, ISM gas pressurization, and other parameters can drive changes in e.g. sigma at fixed M_bulge, and therefore changes in the M_BH-sigma or M_BH-M_bulge relations, the BHFP is robust. Given the empirical trend of decreasing R_e for a given M_bulge at high redshift, the BHFP predicts that BHs will be more massive at fixed M_bulge, in good agreement with recent observations. This evolution in the structural properties of merger remnants, to smaller R_e and larger sigma (and therefore larger M_BH, conserving the BHFP) at a given M_bulge, is driven by the fact that bulge progenitors have characteristically larger gas fractions at high redshifts. Adopting the observed evolution of disk gas fractions with redshift, our simulations predict the observed trends in both R_e(M_bulge) and M_BH(M_bulge).Comment: 22 pages, 19 figures, replaced with version accepted to ApJ. Companion paper to arXiv:0707.400

Broadband Terahertz Pulse Emission from ZnGeP\u3csub\u3e2\u3c/sub\u3e

Optical rectification is demonstrated in (110)-cut ZnGeP2 (ZGP) providing broadband terahertz (THz) generation. The source is compared to both GaP and GaAs over a wavelength range of 1150 nm to 1600 nm and peak intensity range of 0.5 GW/cm2 to 40 GW/cm2. ZGP peak-to-peak field amplitude is larger than in the other materials due to either lower nonlinear absorption or larger second order nonlinearity. This material is well suited for broadband THz generation across a wide range of infrared excitation wavelengths

Diffractive Photoproduction in the Framework of Fracture Functions

Recent data on diffractive photoproduction of dijets are analyzed within the framework of fracture functions and paying special attention to the consequences of the use of different rapidity gap definitions in order to identify diffractive events. Although these effects are found to be significant, it is shown that once they are properly taken into account, a very precise agreement between diffractive DIS and diffractive dijet photoproduction emerges without any significant hint of hard factorization breaking.Comment: 13 pages, 4 figures. To appear in Phys.Rev.