Thermal effects in phase-conjugation in saturable absorbers with picosecond pulses

Phase conjugation reflcction with efficiencies of 400% for microsecond pulses and ~50% Tur picosecond pulses has been obtained in saturable absorber dye Solutions. The effect of difTcrcnt solvcnls on thc gencration of the thermal pitase grating involved was investigated

Picosecond phase-conjugate reflection from organic dye saturable absorbers

Phase conjugation with conversion efficiences of up to 50% has been obtained in DODCI and other saturable absorbers with picosecond pulses from a mode-locked dye laser. Reflectivity shows a quadratic dependence on pump intensity up to $latex \sim 500 \ MW cm-2

Collision-induced dissociation of bradykinin ions in the interface region of an ESI-MS

AbstractBy applying different electric field strengths to the orifice–skimmer region of an electrospray ionization mass spectrometer, the rate of dissociation can be varied based on the amount of internal energy acquired by an ion through collisions with the curtain gas molecules. Both the Arrhenius equation and Rice-Ramsperger-Kassel (RRK) theory can be used to predict the rate of dissociation of internally excited molecules. A previously determined model for collision-induced dissociation is tested by comparison of predicted and experimentally observed orifice–skimmer potential differences for dissociation of ions. The rate of collision-induced dissociation of bradykinin ions is determined by monitoring the fragments produced in a mass spectrometer. The semi-quantitative model is found to yield effective predictions when accurate Arrhenius and RRK parameters are utilized

The Origins of Phase Transitions in Small Systems

The identification and classification of phases in small systems, e.g. nuclei, social and financial networks, clusters, and biological systems, where the traditional definitions of phase transitions are not applicable, is important to obtain a deeper understanding of the phenomena observed in such systems. Within a simple statistical model we investigate the validity and applicability of different classification schemes for phase transtions in small systems. We show that the whole complex temperature plane contains necessary information in order to give a distinct classification.Comment: 3 pages, 4 figures, revtex 4 beta 5, for further information see http://www.smallsystems.d

In situ tryptophan-like fluorometers: assessing turbidity and temperature effects for freshwater applications

Tryptophan-like fluorescence (TLF) is an indicator of human influence on water quality as TLF peaks are associated with the input of labile organic carbon (e.g. sewage or farm waste) and its microbial breakdown. Hence, real-time measurement of TLF could be particularly useful for monitoring water quality at a higher temporal resolution than available hitherto. However, current understanding of TLF quenching/interference is limited for field deployable sensors. We present results from a rigorous test of two commercially available submersible tryptophan fluorometers (ex _ 285, em _ 350). Temperature quenching and turbidity interference were quantified in the laboratory and compensation algorithms developed. Field trials were then undertaken involving: (i) an extended deployment (28 days) in a small urban stream; and, (ii) depth profiling of an urban multi-level borehole. TLF was inversely related to water temperature (regression slope range: _1.57 to _2.50). Sediment particle size was identified as an important control on the turbidity specific TLF response, with signal amplification apparent 200 NTU for clay particles. Compensation algorithms significantly improved agreement between in situ and laboratory readings for baseflow and storm conditions in the stream. For the groundwater trial, there was an excellent agreement between laboratory and raw in situ TLF; temperature compensation provided only a marginal improvement, and turbidity corrections were unnecessary. These findings highlight the potential utility of real time TLF monitoring for a range of environmental applications (e.g. tracing polluting sources and monitoring groundwater contamination). However, in situations where high/ variable suspended sediment loads or rapid changes in temperature are anticipated concurrent monitoring of turbidity and temperature is required and site specific calibration is recommended for long term, surface water monitoring

Health insurance is associated with decreased odds for undiagnosed prediabetes and type 2 diabetes in American adults

Over a third of adults in the United States have prediabetes, and many of those with prediabetes will progress to type 2 diabetes within 3–5 years. Health insurance status may factor into a proper diagnosis of prediabetes and diabetes. This study sought to determine the associations between health insurance and undiagnosed prediabetes and diabetes in a national sample of American adults. Publicly available data from 13,029 adults aged 18–64 years from the 2005–2016 waves of the National Health and Nutrition Examination Survey were analyzed. Health insurance type (Medicaid, Private, Other, None) was self-reported. Prediabetes and diabetes status were assessed with measures of self-report, glycohemoglobin, fasting plasma glucose, and two-hour glucose. Covariate-adjusted logistic models were used for the analyses. Overall, 5976 (45.8%) participants had undiagnosed prediabetes, while 897 (6.8%) had undiagnosed diabetes. Having health insurance was associated with decreased odds ratios for undiagnosed prediabetes: 0.87 (95% confidence interval (CI: 0.79, 0.95)) for private insurance, 0.84 (CI: 0.73, 0.95) for other insurance, and 0.78 (CI: 0.67, 0.90) for Medicaid. Moreover, having private health insurance was associated with 0.82 (CI: 0.67, 0.99) decreased odds for undiagnosed diabetes. Health insurance coverage and screening opportunities for uninsured individuals may reduce prediabetes and diabetes misclassifications

Spatio-temporal Organization During Ventricular Fibrillation in the Human Heart

In this paper, we present a novel approach to quantify the spatio-temporal organization of electrical activation during human ventricular fibrillation (VF). We propose three different methods based on correlation analysis, graph theoretical measures and hierarchical clustering. Using the proposed approach, we quantified the level of spatio-temporal organization during three episodes of VF in ten patients, recorded using multi-electrode epicardial recordings with 30 s coronary perfusion, 150 s global myocardial ischaemia and 30 s reflow. Our findings show a steady decline in spatio-temporal organization from the onset of VF with coronary perfusion. We observed transient increases in spatio-temporal organization during global myocardial ischaemia. However, the decline in spatio-temporal organization continued during reflow. Our results were consistent across all patients, and were consistent with the numbers of phase singularities. Our findings show that the complex spatio-temporal patterns can be studied using complex network analysis

Towards manufacture of ultralow loss hollow core photonic bandgap fiber

Hollow core photonic bandgap fibers (HC-PBGFs) are a class of optical fibers which guide light in a low index core region surrounded by a triangular lattice of air holes separated by a delicate silica web. The precise nature of this cladding structure requires extremely fine control of the fabrication parameters. While HC-PBGFs have found wide range of exciting research applications the initially anticipated potential for ultralow loss below that of single mode fiber (SMF) has yet to be realized. To date loss figures as low as 1.7 dB/km have been reported, however surface roughness at the core cladding interface limited further loss reduction. The loss of HC-PBGFs can potentially be decreased further by increasing the core dimensions and through optimisation of the fabrication process. To date, the manufacture of HC-PBGFs is reliant upon the two stage stack and draw process. To target ultralow loss below what has been reported to date it has become necessary to ensure repeatability and uniformity in the labor intensive stack and draw process. Repeatability is ensured through rigorous cleanliness throughout preform preparation and by precise fabrication control at each stage of manufacture. Figure 1. a) Scanning electron micrograph of a 19 cell core defect HC-PBGF, b) Attenuation scaling of the photonic bandgap (PBG) versus central guidance wavelength of 19 cell core defect HC-PBGF.Greater than 1 km lengths of HC-PBGF (Fig. 1a) can now be drawn with typical attenuations of the order of 2-3 dB/km and with significantly improved optical bandwidth (~ 100 nm) compared with previously reported. These developments open up HC-PBGF for a range of applications such as telecommunications, laser power delivery, gas sensing and strong light matter interactions, for which they have a clear advantage over conventional fibers. The attenuation scaling of the photonic bandgap (PBG) (solid curves) with central operating wavelength has been investigated in 19 cell core defect fibres (Fig. 1b). The expected attenuation proportional to lambda[-3] relationship (dashed red curve) is observed until the infrared absorption edge of silica (black dot dash curve) is breached and the attenuation increases (green curve). Through strategic fabrication improvements we have achieved repeatable low loss manufacture of HC-PBGFs. Future developments in fabrication control and fiber design will allow the realization of ultralow loss HC-PBGF

Inspection of defect-induced mode coupling in hollow-core photonic bandgap fibers using time-of-flight

We analyze defect-induced mode coupling in a hollow-core photonic bandgap fiber using time-of-flight, and show its utility in complementing optical time-domain reflectometry

Photon-axion conversion in intergalactic magnetic fields and cosmological consequences

Photon-axion conversion induced by intergalactic magnetic fields causes an apparent dimming of distant sources, notably of cosmic standard candles such as supernovae of type Ia (SNe Ia). We review the impact of this mechanism on the luminosity-redshift relation of SNe Ia, on the dispersion of quasar spectra, and on the spectrum of the cosmic microwave background. The original idea of explaining the apparent dimming of distant SNe Ia without cosmic acceleration is strongly constrained by these arguments. However, the cosmic equation of state extracted from the SN Ia luminosity-redshift relation remains sensitive to this mechanism. For example, it can mimic phantom energy.Comment: (14 pages, 9 eps figures) Contribution to appear in a volume of Lecture Notes in Physics (Springer-Verlag) on Axion