Processing of laser formed SiC powder

Superior SiC characteristics can be achieved through the use of ideal constituent powders and careful post-synthesis processing steps. High purity SiC powders of approx. 1000 A uniform diameter, nonagglomerated and spherical were produced. This required major revision of the particle formation and growth model from one based on classical nucleation and growth to one based on collision and coalescence of Si particles followed by their carburization. Dispersions based on pure organic solvents as well as steric stabilization were investigated. Although stable dispersions were formed by both, subsequent part fabrication emphasized the pure solvents since fewer problems with drying and residuals of the high purity particles were anticipated. Test parts were made by the colloidal pressing technique; both liquid filtration and consolidation (rearrangement) stages were modeled. Green densities corresponding to a random close packed structure (approx. 63%) were achieved; this highly perfect structure has a high, uniform coordination number (greater than 11) approaching the quality of an ordered structure without introducing domain boundary effects. After drying, parts were densified at temperatures ranging from 1800 to 2100 C. Optimum densification temperatures will probably be in the 1900 to 2000 C range based on these preliminary results which showed that 2050 C samples had experienced substantial grain growth. Although overfired, the 2050 C samples exhibited excellent mechanical properties. Biaxial tensile strengths up to 714 MPa and Vickers hardness values of 2430 kg/sq mm 2 were both more typical of hot pressed than sintered SiC. Both result from the absence of large defects and the confinement of residual porosity (less than 2.5%) to small diameter, uniformly distributed pores

Processing of laser formed SiC powder

Processing research was undertaken to demonstrate that superior SiC characteristics could be achieved through the use of ideal constituent powders and careful post-synthesis processing steps. Initial research developed the means to produce approximately 1000 A uniform diameter, nonagglomerated, spherical, high purity SiC powders. Accomplishing this goal required major revision of the particle formation and growth model from one based on classical nucleation and growth to one based on collision and coalescence of Si particles followed by their carburization. Dispersions based on pure organic solvents as well as steric stabilization were investigated. Test parts were made by the colloidal pressing technique; both liquid filtration and consolidation (rearrangement) stages were modeled. Green densities corresponding to a random close packed structure were achieved. After drying, parts were densified at temperatures ranging from 1800 to 2100 C. This research program accomplished all of its major objectives. Superior microstructures and properties were attained by using powders having ideal characteristics and special post-synthesis processing procedures

Ion yields and erosion rates for Si1−xGex(0x1) ultralow energy O2+ secondary ion mass spectrometry in the energy range of 0.25–1 keV

We report the SIMS parameters required for the quantitative analysis of Si1−xGex across the range of 0 ≤ x ≤ 1 when using low energy O2+ primary ions at normal incidence. These include the silicon and germanium secondary ion yield [i.e., the measured ion signal (ions/s)] and erosion rate [i.e., the speed at which the material sputters (nm/min)] as a function of x. We show that the ratio Rx of erosion rates, Si1−xGex/Si, at a given x is almost independent of beam energy, implying that the properties of the altered layer are dominated by the interaction of oxygen with silicon. Rx shows an exponential dependence on x. Unsurprisingly, the silicon and germanium secondary ion yields are found to depart somewhat from proportionality to (1−x) and x, respectively, although an approximate linear relationship could be used for quantification across around 30% of the range of x (i.e., a reference material containing Ge fraction x would give reasonably accurate quantification across the range of ±0.15x). Direct comparison of the useful (ion) yields [i.e., the ratio of ion yield to the total number of atoms sputtered for a particular species (ions/atom)] and the sputter yields [i.e., the total number of atoms sputtered per incident primary ion (atoms/ions)] reveals a moderate matrix effect where the former decrease monotonically with increasing x except at the lowest beam energy investigated (250 eV). Here, the useful yield of Ge is found to be invariant with x. At 250 eV, the germanium ion and sputter yields are proportional to x for all x

The materials processing research base of the Materials Processing Center

The goals and activities of the center are discussed. The center activities encompass all engineering materials including metals, ceramics, polymers, electronic materials, composites, superconductors, and thin films. Processes include crystallization, solidification, nucleation, and polymer synthesis

Recovery of continuous wave squeezing at low frequencies

We propose and demonstrate a system that produces squeezed vacuum using a pair of optical parametric amplifiers. This scheme allows the production of phase sidebands on the squeezed vacuum which facilitate phase locking in downstream applications. We observe strong, stably locked, continuous wave vacuum squeezing at frequencies as low as 220 kHz. We propose an alternative resonator configuration to overcome low frequency squeezing degradation caused by the optical parametric amplifiers.Comment: 9 pages, 4 figure

Squeezed light at sideband frequencies below 100 kHz from a single OPA

Quantum noise of the electromagnetic field is one of the limiting noise sources in interferometric gravitational wave detectors. Shifting the spectrum of squeezed vacuum states downwards into the acoustic band of gravitational wave detectors is therefore of challenging demand to quantum optics experiments. We demonstrate a system that produces nonclassical continuous variable states of light that are squeezed at sideband frequencies below 100 kHz. A single optical parametric amplifier (OPA) is used in an optical noise cancellation scheme providing squeezed vacuum states with coherent bright phase modulation sidebands at higher frequencies. The system has been stably locked for half an hour limited by thermal stability of our laboratory.Comment: 3 pages, 3 figure

A FUSE survey of high-latitude Galactic molecular hydrogen

Measurements of molecular hydrogen (H_2) column densities are presented for the first six rotational levels (J=0 to 5) for 73 extragalactic targets observed with FUSE. All of these have a final signal-to-noise ratio larger than \snlimit, and are located at galactic latitude |b|>20 deg. The individual observations were calibrated with the FUSE calibration pipeline CalFUSE version 2.1 or higher, and then carefully aligned in velocity. The final velocity shifts for all the FUSE segments are listed. H_2 column densities or limits are determined for the 6 lowest rotational (J) levels for each HI component in the line of sight, using a curve-of-growth approach at low column densities ~16.5), and Voigt-profile fitting at higher column densities. Detections include 73 measurements of low-velocity H_2 in the Galactic Disk and lower Halo. Eight sightlines yield non-detections for Galactic H_2. The measured column densities range from log N(H_2)=14 to log N(H_2)=20. Strong correlations are found between log N(H_2) and T_01, the excitation temperature of the H_2, as well as between log N(H_2) and the level population ratios (log (N(J')/N(J))). The average fraction of nuclei in molecular hydrogen (f(H_2)) in each sightline is calculated; however, because there are many HI clouds in each sightline, the physics of the transition from HI to H_2 can not be studied. Detections also include H2 in 16 intermediate-velocity clouds in the Galactic Halo (out of 35 IVCs). Molecular hydrogen is seen in one high-velocity cloud (the Leading Arm of the Magellanic Stream), although 19 high-velocity clouds are intersected; this strongly suggests that dust is rare or absent in these objects. Finally, there are five detections of H_2 in external galaxies.Comment: Accepted for ApJ Supplement. Note: figs 7 and 8 not included because astro-ph rejects them as too bi

Superhalogen properties of CumCln clusters: Theory and experiment

Using a combination of density functional theory and anion photoelectron spectroscopy experiment, we have studied the structure and electronic properties of CuCl n − (n = 1–5) and Cu2Cl n − (n = 2–5) clusters. Prominent peaks in the mass spectrum of these clusters occurring at n = 2, 3, and 4 in CuCl n − and at n = 3, 4, and 5 in Cu2Cl n − are shown to be associated with the large electron affinities of their neutral clusters that far exceed the value of Cl. While CuCl n(n ≥ 2) clusters are conventional superhalogens with a metal atom at the core surrounded by halogen atoms, Cu2Cl n (n ≥ 3) clusters are also superhalogens but with (CuCl)2 forming the core. The good agreement between our calculated and measured electron affinities and vertical detachment energies confirm not only the calculated geometries of these superhalogens but also our interpretation of their electronic structure and relative stability