Photochemistry of the PAH pyrene in water ice: the case for ion-mediated solid-state astrochemistry

Context. Icy dust grains play an important role in the formation of complex inter- and circumstellar molecules. Observational studies show that polycyclic aromatic hydrocarbons (PAHs) are abundantly present in the ISM in the gas phase. It is likely that these non-volatile species freeze out onto dust grains as well and participate in the astrochemical solid-state network, but experimental PAH ice studies are largely lacking. Methods. Near UV/VIS spectroscopy is used to track the in situ VUV driven photochemistry of pyrene containing ices at temperatures ranging from 10 to 125 K. Results. The main photoproducts of VUV photolyzed pyrene ices are spectroscopically identified and their band positions are listed for two host ices, \water and CO. Pyrene ionisation is found to be most efficient in \water ices at low temperatures. The reaction products, triplet pyrene and the 1-hydro-1-pyrenyl radical are most efficiently formed in higher temperature water ices and in low temperature CO ice. Formation routes and band strength information of the identified species are discussed. Additionally, the oscillator strengths of Py, Py^+ and PyH are derived and a quantitative kinetic analysis is performed by fitting a chemical reaction network to the experimental data. Conclusions. Pyrene is efficiently ionised in water ice at temperatures below 50 K. Hydrogenation reactions dominate the chemistry in low temperature CO ice with trace amounts of water. The results are put in an astrophysical context by determining the importance of PAH ionisation in a molecular cloud. The photoprocessing of a sample PAH in ice described in this manuscript indicates that PAH photoprocessing in the solid state should also be taken into account in astrochemical models.Comment: 11 pages, 8 figures, accepted for publication in A&

The composition and nature of the dust shell surrounding the binary AFGL 4106

We present infrared spectroscopy and imaging of AFGL~4106. The 2.4-5 micron ISO-SWS spectrum reveals the presence of a cool, luminous star (T_eff ~ 3750 K) in addition to an almost equally luminous F star (T_eff ~ 7250 K). The 5-195 micron SWS and LWS spectra are dominated by strong emission from circumstellar dust. We find that the dust consists of amorphous silicates, with a minor but significant contribution from crystalline silicates. The amorphous silicates consist of Fe-rich olivines. The presence of amorphous pyroxenes cannot be excluded but if present they contain much less Fe than the amorphous olivines. Comparison with laboratory data shows that the pure Mg-end members of the crystalline olivine and pyroxene solid solution series are present. In addition, we find strong evidence for simple oxides (FeO and Al2O3) as well as crystalline H2O ice. Several narrow emission features remain unidentified. Modelling of the dust emission using a dust radiation transfer code shows that large grains (~1 micron) must be present and that the abundance of the crystalline silicates is between 7 and 15% of the total dust mass, depending on the assumed enstatite to forsterite ratio, which is estimated to be between 1 and 3. The amorphous and crystalline dust components in the shell do not have the same temperature, implying that the different dust species are not thermally coupled. We find a dust mass of ~3.9 x 10^-2 M_sol expelled over a period of 4 x 10^3 years for a distance of 3.3 kpc. The F-star in the AFGL~4106 binary is likely a post-red-supergiant in transition to a blue supergiant or WR phase.Comment: 22 pages (including 12 figures), accepted by Astronomy and Astrophysic

Із зали засідань Президії НАН України

На черговому засіданні Президії НАН України 13 червня 2012 року члени Президії НАН України та запрошені заслухали такі питання: Спільне засідання Президії Національної академії наук України та Колегії Державної служби статистики України «Про затвердження проекту програми перепису населення» (доповідачі — заступник голови Держстату України Н.С. Власенко та академік НАН України Е.М. Лібанова); Про наукові підходи до вирішення проблеми збереження та відтворення лісів України (доповідач — член-кореспондент НААН України В.П. Ткач); Про нагородження відзнаками НАН України та Почесними грамотами НАН України і Центрального комітету профспілки працівників НАН України (доповідач — академік НАН України В.Ф. Мачулін); Кадрові та поточні питання

Medium-separation binaries do not affect the first steps of planet formation

The first steps of planet formation are marked by the growth and crystallization of sub-micrometer-sized dust grains accompanied by dust settling toward the disk midplane. In this paper we explore whether the first steps of planet formation are affected by the presence of medium-separation stellar companions. We selected two large samples of disks around single and binary T Tauri stars in Taurus that are thought to have only a modest age spread of a few Myr. The companions of our binary sample are at projected separations between 10 and 450 AU with masses down to about 0.1 solar masses. We used the strength and shape of the 10 micron silicate emission feature as a proxy for grain growth and for crystallization respectively. The degree of dust settling was evaluated from the ratio of fluxes at two different mid-infrared wavelengths. We find no statistically significant difference between the distribution of 10 micron silicate emission features from single and binary systems. In addition, the distribution of disk flaring is indistinguishable between the single and binary system samples. These results show that the first steps of planet formation are not affected by the presence of a companion at tens of AU.Comment: To appear in the Astrophysical Journa

9.7 um Silicate Features in AGNs: New Insights into Unification Models

We describe observations of 9.7 um silicate features in 97 AGNs, exhibiting a wide range of AGN types and of X-ray extinction toward the central nuclei. We find that the strength of the silicate feature correlates with the HI column density estimated from fitting the X-ray data, such that low HI columns correspond to silicate emission while high columns correspond to silicate absorption. The behavior is generally consistent with unification models where the large diversity in AGN properties is caused by viewing-angle-dependent obscuration of the nucleus. Radio-loud AGNs and radio-quiet quasars follow roughly the correlation between HI columns and the strength of the silicate feature defined by Seyfert galaxies. The agreement among AGN types suggests a high-level unification with similar characteristics for the structure of the obscuring material. We demonstrate the implications for unification models qualitatively with a conceptual disk model. The model includes an inner accretion disk (< 0.1 pc in radius), a middle disk (0.1-10 pc in radius) with a dense diffuse component and with embedded denser clouds, and an outer clumpy disk (10-300 pc in radius).Comment: Accepted for publication in ApJ, 14 pages, 5 figures. The on-line table is available at http://cztsy.as.arizona.edu/~yong/silicate_tab1.pd

The incubus phenomenon: prevalence, frequency and risk factors in psychiatric inpatients and university undergraduates

Stress and Psychopatholog

A multifunctional setup to record FTIR and UV-vis spectra of organic molecules and their photoproducts in astronomical ices

Laboratory astrophysics and astrochemistr