Thin film solar cells based on the ternary compound Cu2SnS3

Alongside with Cu2ZnSnS4 and SnS, the p-type semiconductor Cu2SnS3 also consists of only Earth abundant and low-cost elements and shows comparable opto-electronic properties, with respect to Cu2ZnSnS4 and SnS, making it a promising candidate for photovoltaic applications of the future. In this work, the ternary compound has been produced via the annealing of an electrodeposited precursor in a sulfur and tin sulfide environment. The obtained absorber layer has been structurally investigated by X-ray diffraction and results indicate the crystal structure to be monoclinic. Its optical properties have been measured via photoluminescence, where an asymmetric peak at 0.95 eV has been found. The evaluation of the photoluminescence spectrum indicates a band gap of 0.93 eV which agrees well with the results from the external quantum efficiency. Furthermore, this semiconductor layer has been processed into a photovoltaic device with a power conversion efficiency of 0.54%, a short circuit current of 17.1 mA/cm2, an open circuit voltage of 104 mV hampered by a small shunt resistance, a fill factor of 30.4%, and a maximal external quantum efficiency of just less than 60%. In addition, the potential of this Cu2SnS3 absorber layer for photovoltaic applications is discussed

Le SIG, un outil de gestion de l'eau dans un périmètre irrigué: cas du secteur S7 au Gharb, Maroc

International audienceDepuis un siècle, la création de réseaux collectifs d'irrigation a été un moyen au service de la puissance publique pour atteindre ses objectifs de politique agricole et d'aménagement du territoire. En 1961, l'office national des irrigations s'est fixé une doctrine de l'intervention en matière de développement hydro agricole : priorité à la grande hydraulique, création de grands périmètres irrigués, mise au point d'un modèle d'aménagement, introduction des cultures sucrières et du contrat de cultures entre l'Etat et les agriculteurs, création de structures locales d'intervention plus proches des agriculteurs (les centres de mise en valeur). Ce modèle technique de l'aménagement hydro-agricole, notamment dans le périmètre irrigué du Gharb, résolvait, avec élégance, le problème majeur de l'articulation et de la gestion de nombreuses données dans un aménagement intégré : satisfaction des besoins en eau, disposition des cultures et des propriétés de façon à permettre le respect de l'assolement préconisé et la distribution des doses d'eau appropriées aux besoins des cultures. Le début des années1990 a été marqué par le désengagement de l'Etat du suivi de la gestion des périmètres irrigués et la libéralisation des assolements. Ainsi, libres dans leurs choix de production, les agriculteurs ont transformé leur système de production pour faire face à la nouvelle conjoncture économique (signature des accords de libre échange avec l'Europe et les USA, etc.). Dans ce nouveau contexte, le rôle des offices régionaux de mise en valeur agricole (Ormva) s'est limité à la prestation du service de vente de l'eau d'irrigation, de la gestion du réseau d'irrigation et de l'encadrement des agriculteurs. Les Ormva, se sont trouvés incapables de suivre la quasi-totalité des agriculteurs faisant partie de leur zone d'action. Cela est dû d'une part, à l'immensité des périmètres irrigués et, d'autre part, au manque de moyens humains et logistiques mis à la disposition des Ormva. La représentation cartographique reste le meilleur outil de la présentation de l'espace, mais pour la rendre dynamique, et en faire un outil de la création de dialogue entre les acteurs il faut lui donner un caractère dynamique. Une première analyse du système d'information de l'Ormva du Gharb a montré l'existence de nombreuses informations sur les cultures pratiquées, les consommations en eau qui peuvent générer de la connaissance sur ce qui se passe réellement sur le périmètre, mais ces informations sont dispersées dans les différents services, entre lesquels la circulation de ces données est presque inexistante. Ces données ne sont pas exploitées, ni vérifiées à cause de la difficulté de l'outil de gestion des données mis en place par l'Ormva et de l'immensité de l'effectif des détenteurs de codes (agriculteurs). Pour faire face à cette situation, la mise en place d'un dispositif d'observation territorial demeure une démarche indispensable pour la gestion des périmètres irrigués. Pour surmonter le problème d'accès à l'information, il est préconisé de mettre en place une cellule d'observation, qui sera formée des agents de plusieurs départements de l'Ormva, ce qui facilitera la disponibilité, la fluidité, le traitement des données et la circulation de l'information

Determinants of methicillin-susceptible Staphylococcus aureus native bone and joint infection treatment failure: a retrospective cohort study.

BACKGROUND: Although methicillin-susceptible Staphylococcus aureus (MSSA) native bone and joint infection (BJI) constitutes the more frequent clinical entity of BJI, prognostic studies mostly focused on methicillin-resistant S. aureus prosthetic joint infection. We aimed to assess the determinants of native MSSA BJI outcomes. METHODS: Retrospective cohort study (2001-2011) of patients admitted in a reference hospital centre for native MSSA BJI. Treatment failure determinants were assessed using Kaplan-Meier curves and binary logistic regression. RESULTS: Sixty-six patients (42 males [63.6%]; median age 61.2 years; interquartile range [IQR] 45.9-71.9) presented an acute (n = 38; 57.6%) or chronic (n = 28; 42.4%) native MSSA arthritis (n = 15; 22.7%), osteomyelitis (n = 19; 28.8%) or spondylodiscitis (n = 32; 48.5%), considered as "difficult-to-treat" in 61 cases (92.4%). All received a prolonged (27.1 weeks; IQR, 16.9-36.1) combined antimicrobial therapy, after surgical management in 37 cases (56.1%). Sixteen treatment failures (24.2%) were observed during a median follow-up period of 63.3 weeks (IQR, 44.7-103.1), including 13 persisting infections, 1 relapse after treatment disruption, and 2 super-infections. Independent determinants of treatment failure were the existence of a sinus tract (odds ratio [OR], 5.300; 95% confidence interval [CI], 1.166-24.103) and a prolonged delay to infectious disease specialist referral (OR, 1.134; 95% CI 1.013-1.271). CONCLUSIONS: The important treatment failure rate pinpointed the difficulty of cure encountered in complicated native MSSA BJI. An early infectious disease specialist referral is essential, especially in debilitated patients or in presence of sinus tract

Dilemma of nitrogen management for future food security in sub-Saharan Africa – a review

Article purchased; Published online: 13 July 2017Food security entails having sufficient, safe, and nutritious food to meet dietary needs. The need to optimise nitrogen (N) use for nutrition security while minimising environmental risks in sub-Saharan Africa (SSA) is overdue. Challenges related to managing N use in SSA can be associated with both insufficient use and excessive loss, and thus the continent must address the ‘too little’ and ‘too much’ paradox. Too little N is used in food production (80% of countries have N deficiencies), which has led to chronic food insecurity and malnutrition. Conversely, too much N load in water bodies due mainly to soil erosion, leaching, limited N recovery from wastewater, and atmospheric deposition contributes to eutrophication (152 Gg N year–1 in Lake Victoria, East Africa). Limited research has been conducted to improve N use for food production and adoption remains low, mainly because farming is generally practiced by resource-poor smallholder farmers. In addition, little has been done to effectively address the ‘too much’ issues, as a consequence of limited research capacity. This research gap must be addressed, and supportive policies operationalised, to maximise N benefits, while also minimising pollution. Innovation platforms involving key stakeholders are required to address N use efficiency along the food supply chain in SSA, as well as other world regions with similar challenges

Comparative study of methodologies to compute the intrinsic Gilbert damping: interrelations, validity and physical consequences

Relaxation effects are of primary importance in the description of magnetic excitations, leading to a myriad of methods addressing the phenomenological damping parameters. In this work, we consider several well-established forms of calculating the intrinsic Gilbert damping within a unified theoretical framework, mapping out their connections and the approximations required to derive each formula. This scheme enables a direct comparison of the different methods on the same footing and a consistent evaluation of their range of validity. Most methods lead to very similar results for the bulk ferromagnets Fe, Co and Ni, due to the low spin-orbit interaction strength and the absence of the spin pumping mechanism. The effects of inhomogeneities, temperature and other sources of finite electronic lifetime are often accounted for by an empirical broadening of the electronic energy levels. We show that the contribution to the damping introduced by this broadening is additive, and so can be extracted by comparing the results of the calculations performed with and without spin-orbit interaction. Starting from simulated ferromagnetic resonance spectra based on the underlying electronic structure, we unambiguously demonstrate that the damping parameter obtained within the constant broadening approximation diverges for three-dimensional bulk magnets in the clean limit, while it remains finite for monolayers. Our work puts into perspective the several methods available to describe and compute the Gilbert damping, building a solid foundation for future investigations of magnetic relaxation effects in any kind of material.Comment: 16 pages, 5 figure

Full-length and C-terminal neurogranin in Alzheimer's disease cerebrospinal fluid analyzed by novel ultrasensitive immunoassays

Background: Neurogranin (Ng) is a neuron-specific and postsynaptic protein that is abundantly expressed in the brain, particularly in the dendritic spine of the hippocampus and cerebral cortex. The enzymatic cleavage of Ng produces fragments that are released into cerebrospinal (CSF), which have been shown to be elevated in Alzheimer’s disease (AD) patients and predict cognitive decline. Thus, quantification of distinctive cleavage products of Ng could elucidate different features of the disease. Methods: In this study, we developed novel ultrasensitive single molecule array (Simoa) assays for measurement of full-length neurogranin (FL-Ng) and C-terminal neurogranin (CT-Ng) fragments in CSF. The Ng Simoa assays were evaluated in CSF samples from AD patients (N = 23), mild cognitive impairment due to AD (MCI-AD) (N = 18), and from neurological controls (N = 26). Results: The intra-assay repeatability and inter-assay precision of the novel methods had coefficients of variation below 7% and 14%, respectively. CSF FL-Ng and CSF CT-Ng median concentrations were increased in AD patients (6.02 ng/L, P < 0.00001 and 452 ng/L, P = 0.00001, respectively) and in patients with MCI-AD (5.69 ng/L, P < 0.00001 and 566 ng/L, P < 0.00001) compared to neurological controls (0.644 ng/L and 145 ng/L). The median CSF ratio of CT-Ng/FL-Ng were decreased in AD patients (ratio = 101, P = 0.008) and in patients with MCI-AD (ratio = 115, P = 0.016) compared to neurological controls (ratio = 180). CSF of FL-Ng, CT-Ng, and ratio of CT-Ng/FL-Ng could each significantly differentiate AD patients from controls (FL-Ng, AUC = 0.907; CT-Ng, AUC = 0.913; CT-Ng/FL-Ng, AUC = 0.775) and patients with MCI-AD from controls (FL-Ng, AUC = 0.937; CT-Ng, AUC = 0.963; CT-Ng/FL-Ng, AUC = 0.785). Conclusions: Assessments of the FL-Ng and CT-Ng levels in CSF with the novel sensitive immunoassays provide a high separation of AD from controls, even in early phase of the disease. The novel Ng assays are robust and highly sensitive and may be valuable tools to study synaptic alteration in AD, as well as to monitor the effect on synaptic integrity of novel drug candidates in clinical trials