1,038 research outputs found
A hierarchy of models related to nanoflows and surface diffusion
In last years a great interest was brought to molecular transport problems at
nanoscales, such as surface diffusion or molecular flows in nano or
sub-nano-channels. In a series of papers V. D. Borman, S. Y. Krylov, A. V.
Prosyanov and J. J. M. Beenakker proposed to use kinetic theory in order to
analyze the mechanisms that determine mobility of molecules in nanoscale
channels. This approach proved to be remarkably useful to give new insight on
these issues, such as density dependence of the diffusion coefficient. In this
paper we revisit these works to derive the kinetic and diffusion models
introduced by V. D. Borman, S. Y. Krylov, A. V. Prosyanov and J. J. M.
Beenakker by using classical tools of kinetic theory such as scaling and
systematic asymptotic analysis. Some results are extended to less restrictive
hypothesis
Melting Point and Lattice Parameter Shifts in Supported Metal Nanoclusters
The dependencies of the melting point and the lattice parameter of supported
metal nanoclusters as functions of clusters height are theoretically
investigated in the framework of the uniform approach. The vacancy mechanism
describing the melting point and the lattice parameter shifts in nanoclusters
with decrease of their size is proposed. It is shown that under the high vacuum
conditions (p<10^-7 torr) the essential role in clusters melting point and
lattice parameter shifts is played by the van der Waals forces of
cluster-substrate interation. The proposed model satisfactorily accounts for
the experimental data.Comment: 6 pages, 3 figures, 1 tabl
Correlation effects during liquid infiltration into hydrophobic nanoporous mediums
Correlation effects arising during liquid infiltration into hydrophobic
porous medium are considered. On the basis of these effects a mechanism of
energy absorption at filling porous medium by nonwetting liquid is suggested.
In accordance with this mechanism, the absorption of mechanical energy is a
result expenditure of energy for the formation of menisci in the pores on the
shell of the infinite cluster and expenditure of energy for the formation of
liquid-porous medium interface in the pores belonging to the infinite cluster
of filled pores. It was found that in dependences on the porosity and,
consequently, in dependences on the number of filled pores neighbors, the
thermal effect of filling can be either positive or negative and the cycle of
infiltration-defiltration can be closed with full outflow of liquid. It can
occur under certain relation between percolation properties of porous medium
and the energy characteristics of the liquid-porous medium interface and the
liquid-gas interface. It is shown that a consecutive account of these
correlation effects and percolation properties of the pores space during
infiltration allow to describe all experimental data under discussion
Semisimplicity of the quantum cohomology for smooth Fano toric varieties associated with facet symmetric polytopes
The degree zero part of the quantum cohomology algebra of a smooth Fano toric
symplectic manifold is determined by the superpotential function, W, of its
moment polytope. In particular, this algebra is semisimple, i.e. splits as a
product of fields, if and only if all the critical points of W are
non-degenerate. In this paper we prove that this non-degeneracy holds for all
smooth Fano toric varieties with facet-symmetric duals to moment polytopes.Comment: 16 pages; corrected version, published in Electron. Res. Announc.
Math. Sc
Effects of neo-adjuvant chemotherapy for oesophago-gastric cancer on neuro-muscular gastric function
Delayed gastric emptying symptoms are often reported after chemotherapy. This study aims to characterise the effects of chemotherapy on gastric neuro-muscular function. Patients undergoing elective surgery for oesophago-gastric cancer were recruited. Acetylcholinesterase, nNOS, ghrelin receptor and motilin expressions were studied in gastric sections from patients receiving no chemotherapy (n = 3) or oesophageal (n = 2) or gastric (n = 2) chemotherapy. A scoring system quantified staining intensity (0–3; no staining to strong). Stomach sections were separately suspended in tissue baths for electrical field stimulation (EFS) and exposure to erythromycin or carbachol; three patients had no chemotherapy; four completed cisplatin-based chemotherapy within 6 weeks prior to surgery. AChE expression was markedly decreased after chemotherapy (scores 2.3 ± 0.7, 0.5 ± 0.2 and 0 ± 0 in non-chemotherapy, oesophageal- and gastric-chemotherapy groups (p < 0.03 each) respectively. Ghrelin receptor and motilin expression tended to increase (ghrelin: 0.7 ± 0.4 vs 2.0 ± 0.4 and 1.2 ± 0.2 respectively; p = 0.04 and p = 0.2; motilin: 0.7 ± 0.5 vs 2.2 ± 0.5 and 2.0 ± 0.7; p = 0.06 and p = 0.16). Maximal contraction to carbachol was 3.7 ± 0.7 g and 1.9 ± 0.8 g (longitudinal muscle) and 3.4 ± 0.4 g and 1.6 ± 0.6 (circular) in non-chemotherapy and chemotherapy tissues respectively (p < 0.05 each). There were loss of AChE and reduction in contractility to carbachol. The tendency for ghrelin receptors to increase suggests an attempt to upregulate compensating systems. Our study offers a mechanism by which chemotherapy markedly alters neuro-muscular gastric function
Modelling Mechanically Induced non-Newtonian Flows to Improve the Energy Efficiency of Anaerobic Digesters
In this paper, a finite volume based computational fluid dynamics (CFD) model has been developed for investigating the mixing of non-Newtonian flows and operating conditions of an anaerobic digester. A CFD model using the multiple reference frame has been implemented in order to model the mixing in an anaerobic digester. Two different agitator designs have been implemented: a design currently used in a full-scale anaerobic mixing device, SCABA, and an alternative helical ribbon design. Lab-scale experiments have been conducted with these two mixing device designs using a water-glycerol mixture to replicate a slurry with total solids concentration of 7.5%, which have been used to validate the CFD model. The CFD model has then been scaled up in order to replicate a full-scale anaerobic digester under real operating parameters that is mechanically stirred with the SCABA design. The influence of the non-Newtonian behaviour has been investigated and found to be important for the power demand calculation. Furthermore, the other helical mixing device has been implemented at full scale and a case study comparing the two agitators has been performed; assessing the mixing capabilities and power consumption of the two designs. It was found that, for a total solids concentrations of 7.5%, the helical design could produce similar mixing capabilities as the SCABA design at a lower power consumption. Finally, the potential power savings of the more energy efficient helical design has been estimated if implemented across the whole of the United Kingdom (UK)/Austria
Multifrequency Photo-polarimetric WEBT Observation Campaign on the Blazar S5 0716+714: Source Microvariability and Search for Characteristic Timescales
Here we report on the results of the WEBT photo-polarimetric campaign
targeting the blazar S5~0716+71, organized in March 2014 to monitor the source
simultaneously in BVRI and near IR filters. The campaign resulted in an
unprecedented dataset spanning \,h of nearly continuous, multi-band
observations, including two sets of densely sampled polarimetric data mainly in
R filter. During the campaign, the source displayed pronounced variability with
peak-to-peak variations of about and "bluer-when-brighter" spectral
evolution, consisting of a day-timescale modulation with superimposed hourlong
microflares characterized by \,mag flux changes. We performed an
in-depth search for quasi-periodicities in the source light curve; hints for
the presence of oscillations on timescales of \,h and \,h do
not represent highly significant departures from a pure red-noise power
spectrum. We observed that, at a certain configuration of the optical
polarization angle relative to the positional angle of the innermost radio jet
in the source, changes in the polarization degree led the total flux
variability by about 2\,h; meanwhile, when the relative configuration of the
polarization and jet angles altered, no such lag could be noted. The
microflaring events, when analyzed as separate pulse emission components, were
found to be characterized by a very high polarization degree () and
polarization angles which differed substantially from the polarization angle of
the underlying background component, or from the radio jet positional angle. We
discuss the results in the general context of blazar emission and energy
dissipation models.Comment: 16 pages, 17 Figures; ApJ accepte
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