Contact probing of stretched membranes and adhesive interactions: graphene and other two-dimensional materials

Contact probing is the preferable method for studying mechanical properties of thin two-dimensional (2D) materials. These studies are based on analysis of experimental force–displacement curves obtained by loading of a stretched membrane by a probe of an atomic force microscope or a nanoindenter. Both non-adhesive and adhesive contact interactions between such a probe and a 2D membrane are studied. As an example of the 2D materials, we consider a graphene crystal monolayer whose discrete structure is modelled as a 2D isotropic elastic membrane. Initially, for contact between a punch and the stretched circular membrane, we formulate and solve problems that are analogies to the Hertz-type and Boussinesq frictionless contact problems. A general statement for the slope of the force–displacement curve is formulated and proved. Then analogies to the JKR (Johnson, Kendall and Roberts) and the Boussinesq–Kendall contact problems in the presence of adhesive interactions are formulated. General nonlinear relations among the actual force, displacements and contact radius between a sticky membrane and an arbitrary axisymmetric indenter are derived. The dimensionless form of the equations for power-law shaped indenters has been analysed, and the explicit expressions are derived for the values of the pull-off force and corresponding critical contact radius

Molecular adhesive contact for indenters of non-ideal shapes

The JKR and the DMT theories of adhesive contact are developed to describe contact between an indenter and an elastic sample, when the distances between the surfaces are described as monomial functions of arbitrary degrees. The results are applied to depth-sensing nanoindentation of soft and hard materials by indenters of non-ideal shapes

The JKR-type adhesive contact problems for transversely isotropic elastic solids

The JKR (Johnson, Kendall, and Roberts) and Boussinesq–Kendall models describe adhesive frictionless contact between two isotropic elastic spheres or between a flat end punch and an elastic isotropic half-space. Here adhesive contact is studied for transversely isotropic materials in the framework of the JKR theory. The theory is extended to much more general shapes of contacting axisymmetric solids, namely the distance between the solids is described by a monomial (power-law) function of an arbitrary degree d⩾1d⩾1. The classic JKR and Boussinesq–Kendall models can be considered as two particular cases of these problems, when the degree of the punch d is equal to two or it goes to infinity, respectively. It is shown that the formulae for extended JKR contact model for transversely isotropic materials have the same mathematical form as the corresponding formulae for isotropic materials; however the effective elastic contact moduli have different expression for different materials. The dimensionless relations between the actual force, displacements and contact radius are given in explicit form. Connections of the problems to nanoindentation of transversely isotropic materials are discussed

Adhesive contact problems for a thin elastic layer : Asymptotic analysis and the JKR theory

Contact problems for a thin compressible elastic layer attached to a rigid support are studied. Assuming that the thickness of the layer is much less than the characteristic dimension of the contact area, a direct derivation of asymptotic relations for displacements and stress is presented. The proposed approach is compared with other published approaches. The cases are established when the leading-order approximation to the non-adhesive contact problems is equivalent to contact problem for a Winkler–Fuss elastic foundation. For this elastic foundation, the axisymmetric adhesive contact is studied in the framework of the Johnson–Kendall–Roberts (JKR) theory. The JKR approach has been generalized to the case of the punch shape being described by an arbitrary blunt axisymmetric indenter. Connections of the results obtained to problems of nanoindentation in the case that the indenter shape near the tip has some deviation from its nominal shape are discussed. For indenters whose shape is described by power-law functions, the explicit expressions are derived for the values of the pull-off force and for the corresponding critical contact radius

The JKR-type adhesive contact problems for power-law shaped axisymmetric punches

The JKR (Johnson, Kendall, and Roberts) and Boussinesq–Kendall models describe adhesive frictionless contact between two isotropic elastic spheres, and between a flat-ended axisymmetric punch and an elastic half-space respectively. However, the shapes of contacting solids may be more general than spherical or flat ones. In addition, the derivation of the main formulae of these models is based on the assumption that the material points within the contact region can move along the punch surface without any friction. However, it is more natural to assume that a material point that came to contact with the punch sticks to its surface, i.e. to assume that the non-slipping boundary conditions are valid. It is shown that the frictionless JKR model may be generalized to arbitrary convex, blunt axisymmetric body, in particular to the case of the punch shape being described by monomial (power-law) punches of an arbitrary degree d≥1d≥1. The JKR and Boussinesq–Kendall models are particular cases of the problems for monomial punches, when the degree of the punch d is equal to two or it goes to infinity respectively. The generalized problems for monomial punches are studied under both frictionless and non-slipping (or no-slip) boundary conditions. It is shown that regardless of the boundary conditions, the solution to the problems is reduced to the same dimensionless relations among the actual force, displacements and contact radius. The explicit expressions are derived for the values of the pull-off force and for the corresponding critical contact radius. Connections of the results obtained for problems of nanoindentation in the case of the indenter shape near the tip has some deviation from its nominal shape and the shape function can be approximated by a monomial function of radius, are discussed

Mechanical, structural and scaling properties of coals: depth sensing indentation studies

This paper discusses special features of mechanical behaviour of coals discovered using depth-sensing indentation (DSI) techniques along with other traditional methods of material testing. Many of the special features are caused by the presence of multiscale complex heterogeneous internal structures within the samples and brittleness of some coal components. Experimental methodology for studying mechanical properties of coals and other natural extreme materials like bones is discussed. It is argued that values of microhardness of bituminous coals correlate strongly with the maximum load; therefore, the use of this parameter in application to coals may be meaningless. For analysis of the force-displacement curves obtained by DSI, both Oliver–Pharr and Galanov–Dub approaches are employed. It is argued that during nanoindentation, the integrity of the internal structure of a coal sample within a small area of high stress field near the tip of indenter may be destroyed. Hence, the standard approaches to mechanical testing of coals should be re-examine

Contact probing of prestressed adhesive membranes of living cells

Atomic force microscopy (AFM) studies of living biological cells is one of main experimental tools that enable quantitative measurements of deformation of the cells and extraction of information about their structural and mechanical properties. However, proper modelling of AFM probing and related adhesive contact problems are of crucial importance for interpretation of experimental data. The Johnson–Kendall–Roberts (JKR) theory of adhesive contact has often been used as a basis for modelling of various phenomena including cell-cell interactions. However, strictly speaking the original JKR theory is valid only for contact of isotropic linearly elastic spheres, while the cell membranes are often prestressed. For the first time, effects caused by molecular adhesion for living cells are analytically studied taking into account the mechanical properties of cell membranes whose stiffness depends on the level of the tensile prestress. Another important question is how one can extract the work of adhesion between the probe and the cell. An extended version of the Borodich-Galanov method for non-direct extraction of elastic and adhesive properties of contacted materials is proposed to apply to experiments of cell probing. Evidently, the proposed models of adhesive contact for cells with prestressed membranes do not cover all types of biological cells because the structure and properties of the cells may vary considerably. However, the obtained results can be applied to many types of smooth cells and can be used to describe initial stages of contact and various other processes when effects of adhesion are of crucial importance. This article is part of a discussion meeting issue ‘A cracking approach to inventing new tough materials: fracture stranger than friction’

Self-similar problems of elastic contact for non-convex punches

Self-similar problems of contact for non-convex punches are considered. The non-convexity of the punch shapes introduces differences from the traditional self-similar contact problems when punch profiles are convex and their shapes are described by homogeneous functions. First, three-dimensional Hertz type contact problems are considered for non-convex punches whose shapes are described by parametric-homogeneous functions. Examples of such functions are numerous including both fractal Weierstrass type functions and smooth log-periodic sine functions. It is shown that the region of contact in the problems is discrete and the solutions obey a non-classical self-similar law. Then the solution to a particular case of the contact problem for an isotropic linear elastic half-space when the surface roughness is described by a log-periodic function, is studied numerically, i.e. the contact problem for rough punches is studied as a Hertz type contact problem without employing additional assumptions of the multi-asperity approach. To obtain the solution, the method of non-linear boundary integral equations is developed. The problem is solved only on the fundamental domain for the parameter of self-similarity because solutions for other values of the parameter can be obtained by renormalization of this solution. It is shown that the problem has some features of chaotic systems, namely the global character of the solution is independent of fine distinctions between parametric-homogeneous functions describing roughness, while the stress field of the problem is sensitive to small perturbations of the punch shape

Non-direct estimations of adhesive and elastic properties of materials by depth-sensing indentation

Using the connection between depth-sensing indentation by spherical indenters and mechanics of adhesive contact, a new method for non-direct determination of adhesive and elastic properties of contacting materials is proposed. At low loads, the force–displacement curves reflect not only elastic properties but also adhesive properties of the contact, and therefore one can try to extract from experiments both the elastic characteristics of contacting materials (such as the reduced elastic modulus) and characteristics of molecular adhesion (such as the work of adhesion and the pull-off force) using a non-direct approach. The direct methods of estimations of the adhesive characteristics of materials currently used in experiments are rather complicated due to the instability of the experimental force–displacement diagrams for ultra-low tensile forces. The proposed method is based on the use of the stable experimental data for the elastic stage of the force–displacement curve and the mechanics of adhesive contact for spherical indenters. Since the experimental data always have some measurement errors, mathematical techniques for solving ill-posed problems are employed

Adhesive depth-sensing indentation tests: Slopes of the force-displacement curves

Depth-sensing indentation experiments are a very important tool for estimating mechanical properties of modern materials. A review of various aspects of contact problems that used as the theoretical basis for interpretation of depth-sensing nanoindentation experiments is presented. Usually, analytical treatment of the indentation tests is based on analysis of the slopes of the force–displacement curves according to the non-adhesive Hertz contact theory. However, molecular adhesion is crucially important for many physical processes at the micro/nano-scales. Here, depth-sensing indentation techniques are reviewed and analyzed using the recent results obtained for adhesive contact problems. Fundamental relations for adhesive nanoindentation tests are derived for both frictionless and no-slip boundary conditions within the contact region. It is argued that the adhesive effects may be very important for treatment of the nanoindentation tests because the slopes of the force–displacement curves may considerably differ from the slopes derived using the non-adhesive contact theory