Is Hyperconjugation Responsible For The Gauche Effect In 1-Fluoropropane And Other 2-Substituted-1-Fluoroethanes?

The energies and geometries of a series of 2-substituted-1-fluoroethanes were computed at the MP2/6-311++G**(6D)//MP2/6-31+G* level of theory for both the maxima and minima of the rotation about the C-C bond. The results did not support the predictions of a hyperconjugative model, that both 1,2-difluoroethane and 1-chloro-2-fluoroethane would strongly prefer a gauche conformation, and that 1-fluoro-2-silylethane would strongly prefer an anti conformation. The existence of competing electrostatic interactions between the fluorine and the substituents at C-2 was indicated by the detailed geometries of the gauche conformers and by the calculated sensitivity of the gauche-anti energy differences to the presence of a polar solvent. However, Fourier analyses of the torsional potential energies were wholly consistent with hyperconjugative electron donation into the C-F sigma* orbital contributing to the conformational preferences of these 1-fluoroethanes. Fourier analyses also showed that hyperconjugation contributes to the small variations in C-C and C-F bond lengths and in fluorine atomic charges that were computed. The torsional potential energies, variations in geometry and atomic charge, and sensitivity to solvent were all in accord with the expected ranking of hyperconjugative electron donating ability of bonds to carbon, C-Si \u3e C-H \u3e C-C \u3e C-Cl \u3e C-F

High efficiency compound semiconductor concentrator photovoltaics

Special emphasis was given to the high yield pilot production of packaged AlGaAs/GaAs concentrator solar cells, using organometallic VPE for materials growth, the demonstration of a concentrator module using 12 of these cells which achieved 16.4 percent conversion efficiency at 50 C coolant inlet temperature, and the demonstration of a spectral splitting converter module that achieved in excess of 20 percent efficiency. This converter employed ten silicon and ten AlGaAs cells with a dichroic filter functioning as the beam splitter. A monolithic array of AlGaAs/GaAs solar cells is described

Do Job, Age, and Place of Residence Matter for Gaming Activity? A Study of the Mid-Colorado River Communities

A household survey in the mid-Colorado River communities of Laughlin, Nevada and Bullhead City, Arizona examined local residents\u27 gaming activities. A censored regression analysis distinguished between factors affecting gaming participation versus expenditures. Results suggest that gaming behavior can often be predicted with knowledge of individuals\u27 residence, workplace, and other household demographic characteristics. Both local government agencies and casino managers can use the results to make better-informed decisions

Progress toward cascade cells made by OM-VPE

Organometallic Vapor Phase Epitaxy (COM-VPE) was used to make a sophisticated monolithic cascade cell, with a peak AMO efficiency of 16.6%, not corrected for 14% grid coverage. The cell has 9 epitaxial layers. The top cell is 1.35 microns thick with a 0.1 micron thich emitter. Both cells are heteroface n-p structures. The cascade cell uses metal interconnects. Details of growth and processing are described

OM-VPE grown materials for high efficiency solar cells

Organometallic sources are available for all the III-V elements and a variety of dopants; thus it is possible to use the technique to grow a wide variety of semiconductor compounds. AlGaAsSb and AlGaInAs alloys for multijunction monolithic solar cells were grown by OM-VPE. While the effort concentrated on terrestrial applications, the success of OM-VPE grown GaAs/AlGaAs concentrator solar cells (23% at 400 suns) demonstrates that OM-VPE is suitable for growing high efficiency solar cells in large quantities for space applications. In addition, OM-VPE offers the potential for substantial cost reduction of photovoltaic devices with scale up and automation and due to high process yield from reproducible, uniform epitaxial growths with excellent surface morphology

Finding the Signal in the Noise: Information Governance, Analytics, and the Future of Legal Practice

In the watershed year of 2012, the world of law witnessed the first concrete discussion of how predictive analytics may be used to make legal practice more efficient. That the conversation about the use of predictive analytics has emerged out of the e-Discovery sector of the law is not all that surprising: in the last decade and with increasing force since 2006— with the passage of revised Federal Rules of Civil Procedure that expressly took into account the fact that lawyers must confront “electronically stored information” in all its varieties—there has been a growing recognition among courts and commentators that the practice of litigation is changing dramatically. What needs now to be recognized, however, is that the rapidly evolving tools and techniques that have been so helpful in providing efficient responses to document requests in complex litigation may be used in a variety of complementary ways to the discovery process itself

Oviposition deterrents for Aedes aegypti in extracts of Lemna minor

Dual choice bioassays demonstrated that water and methanolic extracts of <i>Lemna minor</i> L., in aqueous solution, deterred oviposition by <i>Aedes aegypti</i> L. The methanolic extracts were active at concentrations of 1000 and 10,000 PPM but were inactive at 1, 10, and 100 PPM. Pentane extracts and L. minor culture water showed no activity. None of the extracts bioassayed were biologically active against <i>Culex pipiens</i> L. Experiments in which physical contact with the extracts was prevented, provide evidence that a volatile chemical emanating from the extract is responsible for the deterrency