From ferromagnetism to spin-density wave: Magnetism in the two channel periodic Anderson model

The magnetic properties of the two-channel periodic Anderson model for uranium ions, comprised of a quadrupolar and a magnetic doublet are investigated through the crossover from the mixed-valent to the stable moment regime using dynamical mean field theory. In the mixed-valent regime ferromagnetism is found for low carrier concentration on a hyper-cubic lattice. The Kondo regime is governed by band magnetism with small effective moments and an ordering vector \q close to the perfect nesting vector. In the stable moment regime nearest neighbour anti-ferromagnetism dominates for less than half band filling and a spin density wave transition for larger than half filling. $T_m$ is governed by the renormalized RKKY energy scale \mu_{eff}^2 ^2 J^2\rho_0(\mu).Comment: 4 pages, RevTeX, 3 eps figure

Insulator-to-metal crossover induced by local spin fluctuations in strongly correlated systems

We study the simplified Hubbard (SH) model in the presence of a transverse field in the infinite dimension limit. The relevant one-particle Green's functions of the model are obtained by means a perturbative treatment of the hopping and of the transverse field around the atomic limit. We consider an analytical solution for the impurity problem. It is shown that this solution is very accurate in describing the spectral properties of the heavy-particles of the SH for intermediate and strong values of the on-site Coulomb interaction $U$. We find that for large values of $U$ an insulator-metal transition takes place as a function of the transverse field. We analyze the metallic phase through the behavior of the density of states and of the optical conductivity and static resistivity. Our results for the latter quantity agree with what is observed in experiments on $Bi_2Sr_2CuO_y$.Comment: 6 pages, 5 figures, to appear in Journal of Physics: Condensed Matte

Infrared spectra of one- and two-dimensional fullerene polymer structures: RbC60 and rhombohedral C-60

We compare the infrared spectra of two types of fullerene polymers: the linear-chain RbC60 and the two-dimensional pressure-polymerized rhombohedral C-60. Both the splitting of the F-1u modes and the structure of newly activated Lines are in agreement with fully ordered structures of molecular symmetry D-2h and D-3d, respectively

Theory of Distinct Crystal Structures of Polymerized Fullerides AC60, A=K, Rb, Cs: the Specific Role of Alkalis

The polymer phases of AC60 form distinct crystal structures characterized by the mutual orientations of the (C60-)n chains. We show that the direct electric quadrupole interaction between chains always favors the orthorhombic structure Pmnn with alternating chain orientations. However the specific quadrupolar polarizability of the alkali metal ions leads to an indirect interchain coupling which favors the monoclinic structure I2/m with equal chain orientations. The competition between direct and indirect interactions explains the structural difference between KC60 and RbC60, CsC60.Comment: 4 pages, 2 figures, 1 tabl

Electronic response of aligned multishell carbon nanotubes

We report calculations of the effective electronic response of aligned multishell carbon nanotubes. A local graphite-like dielectric tensor is assigned to every point of the multishell tubules, and the effective transverse dielectric function of the composite is computed by solving Maxwell's equations. Calculations of both real and imaginary parts of the effective dielectric function are presented, for various values of the filling fraction and the ratio of the internal and external radii of hollow tubules. Our full calculations indicate that the experimentally measured macroscopic dielectric function of carbon nanotube materials is the result of a strong electromagnetic coupling between the tubes, which cannot be accounted for with the use of simplified effective medium theories. The presence of surface plasmons is investigated, and both optical absorption cross sections and energy-loss spectra of aligned tubules are calculated.Comment: 4 pages, 4 figures, to appear in Phys. Rev.

Evidence for distinct polymer chain orientations in KC60 and RbC60

The KC60 and RbC60 polymer phases exhibit contrasting electronic properties while powder diffraction studies have revealed no definite structural difference. We have performed single crystal X-ray diffraction and diffuse scattering studies of these compounds. It is found that KC60 and RbC60 possess different chain orientations about their axes, which are described by distinct space groups Pmnn and I2/m, respectively. Such a structural difference will be of great importance to a complete understanding of the physical properties.Comment: To be published in Phys. Rev. Let

Infrared and optical properties of pure and cobalt-doped LuNi_2B_2C

We present optical conductivity data for Lu(Ni$_{1-x}$Co$_x$)$_2$B$_2$C over a wide range of frequencies and temperatures for x=0 and x=0.09. Both materials show evidence of being good Drude metals with the infrared data in reasonable agreement with dc resistivity measurements at low frequencies. An absorption threshold is seen at approximately 700 cm-1. In the cobalt-doped material we see a superconducting gap in the conductivity spectrum with an absorption onset at 24 +/- 2 cm-1 = 3.9$ +/- 0.4 k_BT_c suggestive of weak to moderately strong coupling. The pure material is in the clean limit and no gap can be seen. We discuss the data in terms of the electron-phonon interaction and find that it can be fit below 600 cm-1 with a plasma frequency of 3.3 eV and an electron-phonon coupling constant lambda_{tr}=0.33 using an alpha^{2}F(omega) spectrum fit to the resistivity.Comment: 10 pages with 10 embedded figures, submitted to PR

The polymer phase of the TDAE-C60_{60} organic ferromagnet

The high-pressure Electron Spin Resonance (ESR) measurements were preformed on TDAE-C$_{60}$ single crystals and stability of the polymeric phase was established in the $P - T$ parameter space. At 7 kbar the system undergoes a ferromagnetic to paramagnetic phase transition due to the pressure-induced polymerization. The polymeric phase remains stable after the pressure release. The depolymerization of the pressure-induced phase was observed at the temperature of 520 K. Below room temperature, the polymeric phase behaves as a simple Curie-type insulator with one unpaired electron spin per chemical formula. The TDAE$^+$ donor-related unpaired electron spins, formerly ESR-silent, become active above the temperature of 320 K and the Curie-Weiss behavior is re-established.Comment: Submitted to Phys. Rev.

Upper critical field pecularities of superconducting YNi2B2C and LuNi2B2C

We present new upper critical field Hc2(T) data in a broad temperature region from 0.3K to Tc for LuNi2B2C and YNi2B2C single crystals with well characterized low impurity scattering rates. The absolute values for all T, in particular Hc2(0), and the sizeable positive curvature (PC) of Hc2(T) at high and intermediate T are explained quantitatively within an effective two-band model. The failure of the isotropic single band approach is discussed in detail. Supported by de Haas van Alphen data, the superconductivity reveals direct insight into details of the electronic structure. The observed maximal PC near Tc gives strong evidence for clean limit type II superconductors.Comment: 4 pages, 2 figures, Phys. Rev. Lett. accepte

A study of the superconducting gap in RNi2_2B2_2C (R = Y, Lu) single crystals by inelastic light scattering

Superconductivity-induced changes in the electronic Raman scattering response were observed for the RNi$_2$B$_2$C (R = Y, Lu) system in different scattering geometries. In the superconducting state, 2$\Delta$-like peaks were observed in A$_{1g}$, B$_{1g}$, and B$_{2g}$ spectra from single crystals. The peaks in A$_{1g}$ and B$_{2g}$ symmetries are significantly sharper and stronger than the peak in B$_{1g}$ symmetry. The temperature dependence of the frequencies of the 2$\Delta$-like peaks shows typical BCS-type behavior, but the apparent values of the $2\Delta$ gap are strongly anisotropic for both systems. In addition, for both YNi$_2$B$_2$C and LuNi$_2$B$_2$C systems, there exists reproducible scattering strength below the $2\Delta$ gap which is roughly linear to the frequency in B$_{1g}$ and B$_{2g}$ symmetries. This discovery of scattering below the gap in non-magnetic borocarbide superconductors, which are thought to be conventional BCS-type superconductors, is a challenge for current understanding of superconductivity in this system.Comment: Added text, changed a figure, and added references. Will appear in Phys. Rev.