820 research outputs found
Blind Normalization of Speech From Different Channels
We show how to construct a channel-independent representation of speech that
has propagated through a noisy reverberant channel. This is done by blindly
rescaling the cepstral time series by a non-linear function, with the form of
this scale function being determined by previously encountered cepstra from
that channel. The rescaled form of the time series is an invariant property of
it in the following sense: it is unaffected if the time series is transformed
by any time-independent invertible distortion. Because a linear channel with
stationary noise and impulse response transforms cepstra in this way, the new
technique can be used to remove the channel dependence of a cepstral time
series. In experiments, the method achieved greater channel-independence than
cepstral mean normalization, and it was comparable to the combination of
cepstral mean normalization and spectral subtraction, despite the fact that no
measurements of channel noise or reverberations were required (unlike spectral
subtraction).Comment: 25 pages, 7 figure
High temperature strength retention of Cu/Nb nanolaminates through dynamic strain ageing
The mechanical properties of Cu/Nb metallic nanolaminates with different
layer thickness (7, 16, 34 and 63 nm) were studied by means of micropillar
compression tests from room temperature to 400 C. Both strain-rate jump and
constant strain rate tests were carried out and they showed evidence of dynamic
strain ageing in the nanolaminates with 7, 16 and 34 nm layer thickness
deformed at 200 C. Dynamic strain ageing was accompanied by a reduction of the
strain rate sensitivity to 0, high strength retention at 200 C and the
development of shear localization of the deformation at low strains (5%-6%)
that took place along the Nb layers in the nanolaminates. Atom probe tomography
of the deformed specimens revealed the presence of O in solid solution in the
Nb layers but not in the Cu layers. Thus, diffusion of O atoms to the mobile
dislocations in Nb was found to be the origin of the dynamic strain ageing in
the Cu/Nb nanolaminates around 200 C. This mechanism was not found at higher
temperatures (400 C) because deformation was mainly controlled by
stress-assisted diffusion in the Cu layers. This discovery shows a novel
strategy to enhance the strength retention at high temperature of metallic
nanolaminates through dynamic strain ageing of one the phases
Time-Resolved Measurement of Interatomic Coulombic Decay in Ne_2
The lifetime of interatomic Coulombic decay (ICD) [L. S. Cederbaum et al.,
Phys. Rev. Lett. 79, 4778 (1997)] in Ne_2 is determined via an extreme
ultraviolet pump-probe experiment at the Free-Electron Laser in Hamburg. The
pump pulse creates a 2s inner-shell vacancy in one of the two Ne atoms,
whereupon the ionized dimer undergoes ICD resulting in a repulsive
Ne^{+}(2p^{-1}) - Ne^{+}(2p^{-1}) state, which is probed with a second pulse,
removing a further electron. The yield of coincident Ne^{+} - Ne^{2+} pairs is
recorded as a function of the pump-probe delay, allowing us to deduce the ICD
lifetime of the Ne_{2}^{+}(2s^{-1}) state to be (150 +/- 50) fs in agreement
with quantum calculations.Comment: 5 pages, 3 figures, accepted by PRL on July 11th, 201
Imaging Molecular Structure through Femtosecond Photoelectron Diffraction on Aligned and Oriented Gas-Phase Molecules
This paper gives an account of our progress towards performing femtosecond
time-resolved photoelectron diffraction on gas-phase molecules in a pump-probe
setup combining optical lasers and an X-ray Free-Electron Laser. We present
results of two experiments aimed at measuring photoelectron angular
distributions of laser-aligned 1-ethynyl-4-fluorobenzene (C8H5F) and
dissociating, laseraligned 1,4-dibromobenzene (C6H4Br2) molecules and discuss
them in the larger context of photoelectron diffraction on gas-phase molecules.
We also show how the strong nanosecond laser pulse used for adiabatically
laser-aligning the molecules influences the measured electron and ion spectra
and angular distributions, and discuss how this may affect the outcome of
future time-resolved photoelectron diffraction experiments.Comment: 24 pages, 10 figures, Faraday Discussions 17
Charge transfer in dissociating iodomethane and fluoromethane molecules ionized by intense femtosecond X-ray pulses
Citation: Boll, R., Erk, B., Coffee, R., Trippel, S., Kierspel, T., Bomme, C., . . . Rudenko, A. (2016). Charge transfer in dissociating iodomethane and fluoromethane molecules ionized by intense femtosecond X-ray pulses. Structural Dynamics, 3(4). doi:10.1063/1.4944344Additional Authors: Marchenko, T.;Miron, C.;Patanen, M.;Osipov, T.;Schorb, S.;Simon, M.;Swiggers, M.;Techert, S.;Ueda, K.;Bostedt, C.;Rolles, D.;Rudenko, A.Ultrafast electron transfer in dissociating iodomethane and fluoromethane molecules was studied at the Linac Coherent Light Source free-electron laser using an ultraviolet-pump, X-ray-probe scheme. The results for both molecules are discussed with respect to the nature of their UV excitation and different chemical properties. Signatures of long-distance intramolecular charge transfer are observed for both species, and a quantitative analysis of its distance dependence in iodomethane is carried out for charge states up to I21+. The reconstructed critical distances for electron transfer are in good agreement with a classical over-the-barrier model and with an earlier experiment employing a near-infrared pump pulse. © 2016 Author(s)
Crystallographic ordering in a series of Al-containing refractory high entropy alloys Ta-Nb-Mo-Cr-Ti-Al
Direct observation of incommensurate magnetism in Hubbard chains
The interplay between magnetism and doping is at the origin of exotic
strongly correlated electronic phases and can lead to novel forms of magnetic
ordering. One example is the emergence of incommensurate spin-density waves
with a wave vector that does not match the reciprocal lattice. In one dimension
this effect is a hallmark of Luttinger liquid theory, which also describes the
low energy physics of the Hubbard model. Here we use a quantum simulator based
on ultracold fermions in an optical lattice to directly observe such
incommensurate spin correlations in doped and spin-imbalanced Hubbard chains
using fully spin and density resolved quantum gas microscopy. Doping is found
to induce a linear change of the spin-density wave vector in excellent
agreement with Luttinger theory predictions. For non-zero polarization we
observe a decrease of the wave vector with magnetization as expected from the
Heisenberg model in a magnetic field. We trace the microscopic origin of these
incommensurate correlations to holes, doublons and excess spins which act as
delocalized domain walls for the antiferromagnetic order. Finally, when
inducing interchain coupling we observe fundamentally different spin
correlations around doublons indicating the formation of a magnetic polaron
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