185 research outputs found

    A Unified Theoretical Description of the Thermodynamical Properties of Spin Crossover with Magnetic Interactions

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    After the discovery of the phenomena of light-induced excited spin state trapping (LIESST), the functional properties of metal complexes have been studied intensively. Among them, cooperative phenomena involving low spin-high spin (spin-crossover) transition and magnetic ordering have attracted interests, and it has become necessary to formulate a unified description of both phenomena. In this work, we propose a model in which they can be treated simultaneously by extending the Wajnflasz-Pick model including a magnetic interaction. We found that this new model is equivalent to Blume-Emery-Griffiths (BEG) Hamiltonian with degenerate levels. This model provides a unified description of the thermodynamic properties associated with various types of systems, such as spin-crossover (SC) solids and Prussian blue analogues (PBA). Here, the high spin fraction and the magnetization are the order parameters describing the cooperative phenomena of the model. We present several typical temperature dependences of the order parameters and we determine the phase diagram of the system using the mean-field theory and Monte Carlo simulations. We found that the magnetic interaction drives the SC transition leading to re-entrant magnetic and first-order SC transitions.Comment: 30pages, 11figure

    The formation of passive margins: constraints from the crustal structure and segmentation of the deep Galicia margin, Spain

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    The crustal structure of the Mesozoic deep Galicia margin and adjacent ocean-continent boundary (OCB) was investigated by seismic reflection (including pre-stack depth migration and attenuation of seismic waves with time). The seismic data were calibrated using numerous geological samples recovered by drilling and/or by diving with submersible. The N-S trending margin and OCB are divided in two distinct segments by NE-SW synrift transverse faults locally reactivated and inverted by Cenozoic tectonics. The transverse faulting and OCB segmentation result from crustal stretching probably in a NE-SW direction during the rifting stage of the margin in early Cretaceous times. The Cenozoic tectonics are related to Iberia-Eurasia convergence in Palaeogene times (Pyrenean event). In both segments of the deep margin, the seismic crust is made of four horizontal layers: (1) two sedimentary layers corresponding to post- and syn-rift sequences, where velocity ranges from 1.9 to 3.5 km s−1, and where the Q factor is low, the two sedimentary layers being separated by a strong reflector marking the break-up unconformity; (2) a faulted layer, where velocity ranges from 4.0 to 5.2 km s−1, and where the Q factor is high. This layer corresponds to the margin tilted blocks, where continental basement and lithified pre-rift sediments were sampled; (3) the lower seismic crust, where the velocity (7 km s−1 and more) and the Q factor are the highest. This layer, probably made of partly serpentinized peridotite, is roofed by a strong S-S’ seismic reflector, and resting on a scattering, poorly reflective Moho. A composite model, based both on analogue modelling of lithosphere stretching and on available structural data, accounts for the present structure of the margin and OCB. Stretching and thinning of the lithosphere are accommodated by boudinage of the brittle levels (upper crust and uppermost mantle) and by simple shear in the ductile levels (lower crust and upper lithospheric mantle). Two main conjugate shear zones may account for the observations and seismic data: one (SZ1), located in the lower ductile continental crust, is synthetic to the tilting sense of the margin crustal blocks; another (SZ2), located in the ductile mantle, accounts for the deformation of mantle terranes and their final unroofing and exposure at the continental rift axis (now the OCB). The S-S′ reflector is interpreted as the seismic signature of the tectonic contact between crustal terranes and mantle rocks partly transformed into serpentinite by syn-rift hydrothermal activity. It is probably related to both shear zones SZ1 and SZ2. The seismic Moho is lower within the lithosphere, at the fresh-serpentinized peridotite boundary

    Robotic Wireless Sensor Networks

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    In this chapter, we present a literature survey of an emerging, cutting-edge, and multi-disciplinary field of research at the intersection of Robotics and Wireless Sensor Networks (WSN) which we refer to as Robotic Wireless Sensor Networks (RWSN). We define a RWSN as an autonomous networked multi-robot system that aims to achieve certain sensing goals while meeting and maintaining certain communication performance requirements, through cooperative control, learning and adaptation. While both of the component areas, i.e., Robotics and WSN, are very well-known and well-explored, there exist a whole set of new opportunities and research directions at the intersection of these two fields which are relatively or even completely unexplored. One such example would be the use of a set of robotic routers to set up a temporary communication path between a sender and a receiver that uses the controlled mobility to the advantage of packet routing. We find that there exist only a limited number of articles to be directly categorized as RWSN related works whereas there exist a range of articles in the robotics and the WSN literature that are also relevant to this new field of research. To connect the dots, we first identify the core problems and research trends related to RWSN such as connectivity, localization, routing, and robust flow of information. Next, we classify the existing research on RWSN as well as the relevant state-of-the-arts from robotics and WSN community according to the problems and trends identified in the first step. Lastly, we analyze what is missing in the existing literature, and identify topics that require more research attention in the future

    Nuclear DNA content variation in life history phases of the Bonnemaisoniaceae (Rhodophyta)

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    Nuclear DNA content in gametophytes and sporophytes or the prostrate phases of the following species of Bonnemaisoniaceae (Asparagopsis armata, Asparagopsis taxiformis, Bonnemaisonia asparagoides, Bonnemaisonia clavata and Bonnemaisonia hamifera) were estimated by image analysis and static microspectrophotometry using the DNA-localizing fluorochrome DAPI (4′, 6-diamidino-2-phenylindole, dilactate) and the chicken erythrocytes standard. These estimates expand on the Kew database of DNA nuclear content. DNA content values for 1C nuclei in the gametophytes (spermatia and vegetative cells) range from 0.5 pg to 0.8 pg, and for 2C nuclei in the sporophytes or the prostrate phases range from 1.15-1.7 pg. Although only the 2C and 4C values were observed in the sporophyte or the prostrate phase, in the vegetative cells of the gametophyte the values oscillated from 1C to 4C, showing the possible start of endopolyploidy. The results confirm the alternation of nuclear phases in these Bonnemaisoniaceae species, in those that have tetrasporogenesis, as well as those that have somatic meiosis. The availability of a consensus phylogenetic tree for Bonnemaisoniaceae has opened the way to determine evolutionary trends in DNA contents. Both the estimated genome sizes and the published chromosome numbers for Bonnemaisoniaceae suggest a narrow range of values consistent with the conservation of an ancestral genome

    Polymorphisms of genes coding for insulin-like growth factor 1 and its major binding proteins, circulating levels of IGF-I and IGFBP-3 and breast cancer risk: results from the EPIC study

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    Insulin-like growth factor I (IGF-I) stimulates cell proliferation and can enhance the development of tumours in different organs. Epidemiological studies have shown that an elevated level of circulating IGF-I is associated with increased risk of breast cancer, as well as of other cancers. Most of circulating IGF-I is bound to an acid-labile subunit and to one of six insulin-like growth factor binding proteins (IGFBPs), among which the most important are IGFBP-3 and IGFBP-1. Polymorphisms of the IGF1 gene and of genes encoding for the major IGF-I carriers may predict circulating levels of IGF-I and have an impact on cancer risk. We tested this hypothesis with a case–control study of 807 breast cancer patients and 1588 matched control subjects, nested within the European Prospective Investigation into Cancer and Nutrition. We genotyped 23 common single nucleotide polymorphisms in IGF1, IGFBP1, IGFBP3 and IGFALS, and measured serum levels of IGF-I and IGFBP-3 in samples of cases and controls. We found a weak but significant association of polymorphisms at the 5′ end of the IGF1 gene with breast cancer risk, particularly among women younger than 55 years, and a strong association of polymorphisms located in the 5′ end of IGFBP3 with circulating levels of IGFBP-3, which confirms previous findings. Common genetic variation in these candidate genes does not play a major role in altering breast cancer risk in Caucasians

    Space as a Tool for Astrobiology: Review and Recommendations for Experimentations in Earth Orbit and Beyond

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