3,015 research outputs found
Unified model of ultracold molecular collisions
A scattering model is developed for ultracold molecular collisions, which
allows inelastic processes, chemical reactions, and complex formation to be
treated in a unified way. All these scattering processes and various
combinations of them are possible in ultracold molecular gases, and as such
this model will allow the rigorous parametrization of experimental results. In
addition we show how, once extracted, these parameters can be related to the
physical properties of the system, shedding light on fundamental aspects of
molecular collision dynamics.Comment: 16 Pages, 5 Figure
Monetary Union and the Interest-Exchange Rate Trade-off
By using a multi-country simulation model this paper analyzes the qualitative effects of joining a monetary union. The transition to EMU (European Monetary Union) is shown to produce interest and exchange rate changes with substantial and countervailing effects on the real economy which can be traced through the model. Observable anticipation effects in the wake of the EMU are substantiated; and some policy recommendations for joining any monetary union are derived. It is also shown that fixing conversion rates at last-day market rates produces a unique outcome and not exchange rate indeterminacy as argued by de Grauwe (1997), Obstfeld (1998), and others.
Mol. Cell. Proteomics
Chemical cross-linking in combination with mass spectrometric analysis offers the potential to obtain low-resolution structural information from proteins and protein complexes. Identification of peptides connected by a cross-link provides direct evidence for the physical interaction of amino acid side chains, information that can be used for computational modeling purposes. Despite impressive advances that were made in recent years, the number of experimentally observed cross-links still falls below the number of possible contacts of cross-linkable side chains within the span of the cross-linker. Here, we propose two complementary experimental strategies to expand cross-linking data sets. First, enrichment of cross-linked peptides by size exclusion chromatography selects cross-linked peptides based on their higher molecular mass, thereby depleting the majority of unmodified peptides present in proteolytic digests of cross-linked samples. Second, we demonstrate that the use of proteases in addition to trypsin, such as Asp-N, can additionally boost the number of observable cross-linking sites. The benefits of both SEC enrichment and multiprotease digests are demonstrated on a set of model proteins and the improved workflow is applied to the characterization of the 20S proteasome from rabbit and Schizosaccharomyces pombe
Decomposition in HTPB bonded HMX followed by heat generation rate and chemiluminescence
The decomposition in HTPB bonded HMX was characterized with two highly sensitive methods: heat flow microcalorimetry (HFMC) and Chemiluminescence (CL). The material is stabilized with a phenolic antioxidant. The heat generation (HFMC) rate was determined from 120 to 150°C using a TAM™ microcalorimeter and the oxidation of the substance was followed by the CL emission between 100 and 140°C directly from the solid state sample. The end of antioxidant activity results in both measurements sets in characteristic changes in the curves. Kinetic parameters were calculated applying Arrhenius parameterization for the times to the end of antioxidant activity and by applying modelling with an autocatalytic model extended by a side reaction, which is assigned to the antioxidant consumption. The evaluation with the characteristic times gives good agreement between the two methods; the modelling represents the different but supplementing probing of the two measurement method
Pair Wave Functions in Atomic Fermi Condensates
Recent experiments have observed condensation behavior in a strongly
interacting system of fermionic atoms. We interpret these observations in terms
of a mean-field version of resonance superfluidity theory. We find that the
objects condensed are not bosonic molecules composed of bound fermion pairs,
but are rather spatially correlated Cooper pairs whose coherence length is
comparable to the mean spacing between atoms. We propose experiments that will
help to further probe these novel pairs
Tunable asymmetric magnetoimpedance effect in ferromagnetic NiFe/Cu/Co films
We investigate the magnetization dynamics through the magnetoimpedance effect
in ferromagnetic NiFe/Cu/Co films. We observe that the magnetoimpedance
response is dependent on the thickness of the non-magnetic Cu spacer material,
a fact associated to the kind of the magnetic interaction between the
ferromagnetic layers. Thus, we present an experimental study on asymmetric
magnetoimpedance in ferromagnetic films with biphase magnetic behavior and
explore the possibility of tuning the linear region of the magnetoimpedance
curves around zero magnetic field by varying the thickness of the non-magnetic
spacer material, and probe current frequency. We discuss the experimental
magnetoimpedance results in terms of the different mechanisms governing the
magnetization dynamics at distinct frequency ranges, quasi-static magnetic
properties, thickness of the non-magnetic spacer material, and the kind of the
magnetic interaction between the ferromagnetic layers. The results place
ferromagnetic films with biphase magnetic behavior exhibiting asymmetric
magnetoimpedance effect as a very attractive candidate for application as probe
element in the development of auto-biased linear magnetic field sensors.Comment: 5 figure
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