595 research outputs found
Origin of the scatter in the X-ray luminosity of early-type galaxies observed with ROSAT
Statistical properties of X-ray luminosity and temperature are studied for 52
early-type galaxies based on the ROSAT PSPC data. All of the X-ray luminous
galaxies show largely extended emission with a radius of a few times of
10, while X-ray faint galaxies do not show such a component. This leads to
a division of early-type galaxies into two categories: X-ray extended and X-ray
compact galaxies. Except for a few galaxies in dense cluster environments, the
luminosity and temperature of X-ray compact galaxies are well explained by a
kinematical heating of the gas supplied by stellar mass loss. In contrast,
X-ray extended galaxies indicate large scatter in the X-ray luminosity. We
discuss that X-ray extended galaxies are the central objects of large potential
structures, and the presence and absence of this potential is the main origin
of the large scatter in the X-ray luminosity.Comment: 35 pages, including 8 figures, Accepted for publication in Ap
Phonon distributions of a single bath mode coupled to a quantum dot
The properties of an unconventional, single mode phonon bath coupled to a
quantum dot, are investigated within the rotating wave approximation. The
electron current through the dot induces an out of equilibrium bath, with a
phonon distribution qualitatively different from the thermal one. In selected
transport regimes, such a distribution is characterized by a peculiar selective
population of few phonon modes and can exhibit a sub-Poissonian behavior. It is
shown that such a sub-Poissonian behavior is favored by a double occupancy of
the dot. The crossover from a unequilibrated to a conventional thermal bath is
explored, and the limitations of the rotating wave approximation are discussed.Comment: 21 Pages, 7 figures, to appear in New Journal of Physics - Focus on
Quantum Dissipation in Unconventional Environment
Complex Dynamics and Multistability in a Damped Harmonic Oscillator with Delayed Negative Feedback
A center manifold reduction and numerical calculations are used to demonstrate the presence of limit cycles, two-tori, and multistability in the damped harmonic oscillator with delayed negative feedback. This model is the prototype of a mechanical system operating with delayed feedback. Complex dynamics are thus seen to arise in very plausible and commonly occurring mechanical and neuromechanical feedback systems
Microscopic mechanisms of dephasing due to electron-electron interactions
We develop a non-perturbative numerical method to study tunneling of a single
electron through an Aharonov-Bohm ring where several strongly interacting
electrons are bound. Inelastic processes and spin-flip scattering are taken
into account. The method is applied to study microscopic mechanisms of
dephasing in a non-trivial model. We show that electron-electron interactions
described by the Hubbard Hamiltonian lead to strong dephasing: the transmission
probability at flux is high even at small interaction strength. In
addition to inelastic scattering, we identify two energy conserving mechanisms
of dephasing: symmetry-changing and spin-flip scattering. The many-electron
state on the ring determines which of these mechanisms will be at play:
transmitted current can occur either in elastic or inelastic channels, with or
without changing the spin of the scattering electron.Comment: 11 pages, 16 figures Submitted to Phys. Rev.
Performance of ab initio and density functional methods for conformational equilibria of CnH2n+2 alkane isomers (n=2-8)
Conformational energies of n-butane, n-pentane, and n-hexane have been
calculated at the CCSD(T) level and at or near the basis set limit.
Post-CCSD(T) contribution were considered and found to be unimportant. The data
thus obtained were used to assess the performance of a variety of density
functional methods. Double-hybrid functionals like B2GP-PLYP and B2K-PLYP,
especially with a small Grimme-type empirical dispersion correction, are
capable of rendering conformational energies of CCSD(T) quality. These were
then used as a `secondary standard' for a larger sample of alkanes, including
isopentane and the branched hexanes as well as key isomers of heptane and
octane. Popular DFT functionals like B3LYP, B3PW91, BLYP, PBE, and PBE0 tend to
overestimate conformer energies without dispersion correction, while the M06
family severely underestimates GG interaction energies. Grimme-type dispersion
corrections for these overcorrect and lead to qualitatively wrong conformer
orderings. All of these functionals also exhibit deficiencies in the conformer
geometries, particularly the backbone torsion angles. The PW6B95 and, to a
lesser extent, BMK functionals are relatively free of these deficiencies.
Performance of these methods is further investigated to derive conformer
ensemble corrections to the enthalpy function, , and the Gibbs
energy function, , of these alkanes. While
is only moderately sensitive to the level of theory, exhibits more pronounced sensitivity. Once again, double hybrids
acquit themselves very well.Comment: J. Phys. Chem. A, revised [Walter Thiel festschrift
Universal conductance enhancement and reduction of the two-orbital Kondo effect
We investigate theoretically the linear and nonlinear conductance through a
nanostructure with two-fold degenerate single levels, corresponding to the
transport through nanostructures such as a carbon nanotube, or double dot
systems with capacitive interaction. It is shown that the presence of the
interaction asymmetry between orbits/dots affects significantly the profile of
the linear conductance at finite temperature, and, of the nonlinear
conductance, particularly around half-filling, where the two-particle Kondo
effect occurs. Within the range of experimentally feasible parameters, the
SU(4) universal behavior is suggested, and comparison with relevant experiments
is made.Comment: 10 pages, 16 figure
Charge densities and charge noise in mesoscopic conductors
We introduce a hierarchy of density of states to characterize the charge
distribution in a mesoscopic conductor. At the bottom of this hierarchy are the
partial density of states which represent the contribution to the local density
of states if both the incident and the out-going scattering channel is
prescribed. The partial density of states play a prominent role in measurements
with a scanning tunneling microscope on multiprobe conductors in the presence
of current flow. The partial density of states determine the degree of
dephasing generated by a weakly coupled voltage probe. In addition the partial
density of states determine the frequency-dependent response of mesoscopic
conductors in the presence of slowly oscillating voltages applied to the
contacts of the sample. The partial density of states permit the formulation of
a Friedel sum rule which can be applied locally. We introduce the off-diagonal
elements of the partial density of states matrix to describe charge fluctuation
processes. This generalization leads to a local Wigner-Smith life-time matrix.Comment: 10 pages, 2 figure
A Halomethane thermochemical network from iPEPICO experiments and quantum chemical calculations
Internal energy selected halomethane cations CH3Cl+, CH2Cl2+, CHCl3+, CH3F+, CH2F2+, CHClF2+ and CBrClF2+ were prepared by vacuum ultraviolet photoionization, and their lowest energy dissociation channel studied using imaging photoelectron photoion coincidence spectroscopy (iPEPICO). This channel involves hydrogen atom loss for CH3F+, CH2F2+ and CH3Cl+, chlorine atom loss for CH2Cl2+, CHCl3+ and CHClF2+, and bromine atom loss for CBrClF2+. Accurate 0 K appearance energies, in conjunction with ab initio isodesmic and halogen exchange reaction energies, establish a thermochemical network, which is optimized to update and confirm the enthalpies of formation of the sample molecules and their dissociative photoionization products. The ground electronic states of CHCl3+, CHClF2+ and CBrClF2+ do not confirm to the deep well assumption, and the experimental breakdown curve deviates from the deep well model at low energies. Breakdown curve analysis of such shallow well systems supplies a satisfactorily succinct route to the adiabatic ionization energy of the parent molecule, particularly if the threshold photoelectron spectrum is not resolved and a purely computational route is unfeasible. The ionization energies have been found to be 11.47 ± 0.01 eV, 12.30 ± 0.02 eV and 11.23 ± 0.03 eV for CHCl3, CHClF2 and CBrClF2, respectively. The updated 0 K enthalpies of formation, âfHo0K(g) for the ions CH2F+, CHF2+, CHCl2+, CCl3+, CCl2F+ and CClF2+ have been derived to be 844.4 ± 2.1, 601.6 ± 2.7, 890.3 ± 2.2, 849.8 ± 3.2, 701.2 ± 3.3 and 552.2 ± 3.4 kJ molâ1, respectively. The âfHo0K(g) values for the neutrals CCl4, CBrClF2, CClF3, CCl2F2 and CCl3F and have been determined to be â94.0 ± 3.2, â446.6 ± 2.7, â702.1 ± 3.5, â487.8 ± 3.4 and â285.2 ± 3.2 kJ molâ1, respectively
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