New findings of ancient Greek silver sources

Over the last 60 years, much analytical research has sought to determine the ore sources of ancient Greek silver artefacts. Lead isotopic analysis has played a key role in this endeavor. While most studies so far have limited their search to places mentioned in historical sources, the present study takes a different approach by first identifying Ag-bearing ore sources in the Aegean world based on their geological characteristics and then using Pb isotopes to determine whether they were exploited in antiquity. To this end, we have geolocated, sampled, and measured high-precision Pb isotopic compositions of 17 Ag-bearing mineralizations in Greece for which we have evidence of ancient mining activity, and a further 10 exhibiting minor Ag occurrences that may also have been exploited in ancient times. We found that Pb model ages provide better discrimination of ore sources than the more conventional plots of raw Pb isotope data

Rome’s urban history inferred from Pb-contaminated waters trapped in its ancient harbor basins

Heavy metals from urban runoff preserved in sedimentary deposits record long-term economic and industrial development via the expansion and contraction of a city’s infrastructure. Lead concentrations and isotopic compositions measured in the sediments of the harbor of Ostia—Rome’s first harbor—show that lead pipes used in the water supply networks of Rome and Ostia were the only source of radiogenic Pb, which, in geologically young central Italy, is the hallmark of urban pollution. High-resolution geochemical, isotopic, and 14C analyses of a sedimentary core from Ostia harbor have allowed us to date the commissioning of Rome’s lead pipe water distribution system to around the second century BC, considerably later than Rome’s first aqueduct built in the late fourth century BC. Even more significantly, the isotopic record of Pb pollution proves to be an unparalleled proxy for tracking the urban development of ancient Rome over more than a millennium, providing a semiquantitative record of the water system’s initial expansion, its later neglect, probably during the civil wars of the first century BC, and its peaking in extent during the relative stability of the early high Imperial period. This core record fills the gap in the system’s history before the appearance of more detailed literary and inscriptional evidence from the late first century BC onward. It also preserves evidence of the changes in the dynamics of the Tiber River that accompanied the construction of Rome’s artificial port, Portus, during the first and second centuries AD

A lead isotope perspective on urban development in ancient Naples

The influence of a sophisticated water distribution system on urban development in Roman times is tested against the impact of Vesuvius volcanic activity, in particular the great eruption of AD 79, on all of the ancient cities of the Bay of Naples (Neapolis). Written accounts on urbanization outside of Rome are scarce and the archaeological record sketchy, especially during the tumultuous fifth and sixth centuries AD when Neapolis became the dominant city in the region. Here we show that isotopic ratios of lead measured on a well-dated sedimentary sequence from Neapolis’ harbor covering the first six centuries CE have recorded how the AD 79 eruption was followed by a complete overhaul of Neapolis’ water supply network. The Pb isotopic signatures of the sediments further reveal that the previously steady growth of Neapolis’ water distribution system ceased during the collapse of the fifth century AD, although vital repairs to this critical infrastructure were still carried out in the aftermath of invasions and volcanic eruptions

The record of human impact in the sedimentary record at Portus, the harbor of ancient Rome

International audienceThe present study focuses on the analysis of palaeo-pollutions and the sedimentary environments in which they were trapped in the Roman Portus harbor. Portus received heavy-metals pollution both from local foundries, fulling, and tanning and from distal upstream development in Rome. Rome wastewaters, which accounted for up to 3 percent of the total Tiber discharge, were forwarded to Portus through a network of canals (Canale Romano and Canale Trasverso) connecting the river to the sea. In this manner, harbor basins accumulated both allochthonous and autochthonous heavy metals. We determined major and trace element concentrations as well as Pb isotope compositions in a high-resolution set of samples from sediment cores recovered in the Portus area. Principal component analysis of elements that are less prone to the influence of human activities, such as Ca, Mg, Mn, Zr, K, Al, Ti, Na, Sr, and Mn, was used in conjunction with metallic elements to break down the sedimentary load into local and regional components. The record of Pb concentrations and isotopic compositions reveals an overall general trend on which other signatures are superimposed. The geochemical background of the Tiber catchment (24.7-26.2 ppm Pb and 206 Pb/ 207 Pb ~ 1.198) represents geologically young (model age Tm <50 Ma) Pb derived from natural runoff over young sediments and volcanics in the Latium. From the 1 st century AD to the end of the roman period, the harbor regime evolved from a dominant fluvial (enriched in Al, Ti, Mg, K, and Zr) to a more marine influence (high Ca/Mg, Na/Al, Sr, and CaCO3) in the upper part of the harbor unit. "Imperial" Pb (90.5-35.4 ppm Pb and 20

Geodynamic implications for zonal and meridional isotopic patterns across the northern Lau and North Fiji Basins

We present new Sr-Nd-Pb-Hf-He isotopic data for sixty-five volcanic samples from the northern Lau and North Fiji Basin. This includes forty-seven lavas obtained from forty dredge sites spanning an east-west transect across the Lau and North Fiji basins, ten ocean island basalt (OIB)-type lavas collected from seven Fijian islands, and eight OIB lavas sampled on Rotuma. For the first time we are able to map clear north-south and east-west geochemical gradients in 87Sr/86Sr across the northern Lau and North Fiji Basins: lavas with the most geochemically enriched radiogenic isotopic signatures are located in the northeast Lau Basin, while signatures of geochemical enrichment are diminished to the south and west away from the Samoan hotspot. Based on these geochemical patterns and plate reconstructions of the region, these observations are best explained by the addition of Samoa, Rurutu, and Rarotonga hotspot material over the past 4 Ma. We suggest that underplated Samoan material has been advected into the Lau Basin over the past ∼4 Ma. As the slab migrated west (and toward the Samoan plume) via rollback over time, younger and hotter (and therefore less viscous) underplated Samoan plume material was entrained. Thus, entrainment efficiency of underplated plume material was enhanced, and Samoan plume signatures in the Lau Basin became stronger as the trench approached the Samoan hotspot. The addition of subducted volcanoes to the Cook-Austral Volcanic Lineament material, first from the Rarotonga hotspot, then followed by the Rurutu hotspot, contributes to the extreme geochemical signatures observed in the northeast Lau Basin

Definition of a new approach in ancient harbor geoarchaeology: geochemistry and ostracod analyses at Portus (Tiber delta, central Italy)

International audiencePortus constituted the harbour complex of imperial Rome from the 1st century AD onward. Located in a deltaic environment, the harbour was subject to influences of the Tyrrhenian marine environment and of the fluvial waters of the Tiber River. Such complex sedimentary processes registered also rapid environ-mental changes. Our research is based on the study of a sediment core (TR14) drilled in the access channel of the hexagonal basin of Trajan (Fig. 1). The goal of our study is the reconstruction the palaeo-environmental dynamics of the water column of the harbour according to a geochemical and an ostra-codological approach. The analysis of the ostracod assemblage has evidenced several palaeo-environmental phases. These phases could be identified through the autoeco-logical analysis of the 25 recognised taxa and their classification in four eco-logical groups (MAZZINI et al., 2011). The results obtained present a succession of four environments, defined by variations in salinity and oxygenation. From the bottom to a depth of 643 cm, the environment was a marine to brackish lagoon influenced by strong marine inputs as evidenced by the vic-ariance of Cyprideis torosa and Pontocythere turbida. P. turbida is a typical phy-tal ostracod often found together with Posidonia oceanica remains. From 600 to 454 cm the coastal marine environment becomes more stable. This could be linked to the establishment of the harbour activities and maintenance. The sta-bility of the environment is still evident in the subsequent group, from 435 to 305 cm, characterised by the dominance of C. torosa and the lack of any fresh-water influence. The increase in salinity could be related to evaporative effects on a closed body of water. From 300 cm the freshwater input becomes clear and constant although the influence of the close sea/brackish body of water is still noticeable. In the last metres a typical freshwater assemblage is represent-ed, dominated by truly freshwater taxa (Candona sp. and Pseudocandona marchica), evidence for the occurrence of a freshwater marsh. The geochemical results were analysed by Principal Components Analy-sis (PCA). The samples were assembled in several groups based on a Hierar-chical Ascendant Classification (cluster analysis). Through PCA analysis, the geochemical and ostracological results of the "functional" harbour unit (800-300 cm) were combined. The different elements recorded in the geochemical analysis are distributed according to the main ostracod assemblages (from fresh water to brackish water and sea water). These elements have been grouped according to the model proposed by SAGEMAN & LYONS (2003). An evolution of these deposits in three stages is proposed. While the fluvial envi-ronments were quite well oxygenated, the harbour environment was more characterised by an increasing anoxia of the water column as it was observed by ELMALEH et al. (2012) in the harbor of Tyre. In a second phase, the varia-tions in salinity distinguished the nature of the fluvial environments and the degree of openness to the sea of the harbour environment. The final phase is specific to a body of water completely isolated from fluviatile and marin

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Evidence for a broadly distributed Samoan-plume signature in the northern Lau and North Fiji Basins

Author Posting. © American Geophysical Union, 2014. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry, Geophysics, Geosystems 15 (2014): 986–1008, doi:10.1002/2013GC005061.Geochemical enrichment of lavas in the northern Lau Basin may reflect the influx of Samoan-plume mantle into the region. We report major and trace element abundances and He-Sr-Nd-Hf-Pb-isotopic measurements for 23 submarine volcanic glasses covering 10 locations in the northern Lau and North Fiji Basins, and for three samples from Wallis Island, which lies between Samoa and the Lau Basin. These data extend the western limit of geochemical observations in the Basins and improve the resolution of North-South variations in isotopic ratios. The Samoan hot spot track runs along the length of the northern trace of the Lau and North Fiji Basins. We find evidence for a Samoan-plume component in lavas as far West as South Pandora Ridge (SPR), North Fiji Basin. Isotopic signatures in SPR samples are similar to those found in Samoan Upolu shield lavas, but show a slight shift toward MORB-like compositions. We explain the origin of the enriched signatures by a model in which Samoan-plume material and ambient depleted mantle undergo decompression melting during upwelling after transiting from beneath the thick Pacific lithosphere to beneath the thin lithosphere in the northern Lau and North Fiji Basins. Other lavas found in the region with highly depleted isotopic signatures may represent isolated pockets of depleted mantle in the basins that evaded this enrichment process. We further find that mixing between the two components in our model, a variably degassed high-3He/4He Samoan component and depleted MORB, can explain the diversity among geochemical data from the northern Lau Basin.M.G.J. acknowledges support from NSF grants OCE-1061134, OCE-1153894, and EAR-1145202 and J.B.T. acknowledges support from the French Agence Nationale de la Recherche (grant ANR-10-BLANC-0603 M&Ms—Mantle Melting—Measurements, Models, Mechanisms).2014-10-1

Geochemical evidence in the northeast Lau Basin for subduction of the Cook-Austral volcanic chain in the Tonga Trench

Author Posting. © American Geophysical Union, 2016. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry, Geophysics, Geosystems 17 (2016): 1694–1724, doi:10.1002/2015GC006237.Lau Basin basalts host an array of geochemical signatures that suggest incorporation of enriched mantle source material often associated with intraplate hotspots, but the origin of these signatures remain uncertain. Geochemical signatures associated with mantle material entrained from the nearby Samoan hotspot are present in northwest Lau Basin lavas, and subducted seamounts from the Louisville hotspot track may contribute geochemical signatures to the Tonga Arc. However, lavas in the northeast Lau Basin (NELB) have unique enriched geochemical signatures that cannot be related to these hotspots, but can be attributed to the subduction of seamounts associated with the Cook-Austral volcanic lineament. Here we present geochemical data on a new suite of NELB lavas—ranging in 40Ar/39Ar age from 1.3 Ma to 0.365 ka—that have extreme signatures of geochemical enrichment, including lavas with the highest 206Pb/204Pb (19.580) and among the lowest 143Nd/144Nd (0.512697) encountered in the Lau Basin to date. These signatures are linked to the canonical EM1 (enriched mantle 1) and HIMU (high-μ = 238U/204Pb) mantle end-members, respectively. Using a plate reconstruction model, we show that older portions of the traces of two of the Cook-Austral hotspots that contributed volcanism to the Cook-Austral volcanic lineament—the Rarotonga and Rurutu hotspots—were potentially subducted in the Tonga Trench beneath the NELB. The geochemical signatures of the Rarotonga, Rurutu, and Samoan hotspots provide a compelling match to the extreme geochemical components observed in the new NELB lavas.NSF. Grant Number OCE-1153894, EAR-1347377, EAR-1145202, and EAR-1348082; French Agence Nationale de la Recherche Grant Number: ANR-10-BLANC-0603; NSF Grant Numbers: OCE-1154070, OCE-1232985, OCE-1153959 and OCE-14330972016-11-1