Experimental Overlay of Glazon over Two Bridge Decks

In accordance with a Personal Service Agreement entered into with the Glazon Industries, Inc., on July 2, 1971, the two subject decks were patched and overlayed with Glazon. On July 27, 1971, work started on RP 106-286-HG3, KY 395 bridge over I 64 in Shelby County. Work consisted of routing old concrete and sandblasting the surface (Figures 1 and 2). State personnel and equipment were used for all cleaning operations. The same procedures were followed to clean HM 99-1324A-MB3 in Powell County near Clay City. On July 28, 1971, Glazon personnel and equipment arrived at the work site in Shelby County. Glazon representatives judged the cleaning adequate and proceeded with patching the southbound lane (Figure 3). No accurate information is available as to the exact formulation of the Glazon used or proportions in the mix. Glazon Industries declined disclosure of such information since their material was not patented. Before patching, the holes were thoroughly dried. Shrinkage and cracking were noticed in the patches shortly after drying (Figure 4). Later, on other lanes, patch holes were primed with a Glazon liquid before patching (Figures 5 and 6). After a short drying period, the deck was sprayed with a Glazon mix similar to that for patching but more fluid (Figures 7 and 8). Some problems were encountered due to weak air supply, but were shortly overcome. The sprayed deck looked satisfactory to Glazon personnel who did most of the work in patching and overlaying the deck. The operation was moved to the Clay City bridge and the same procedures were followed in working the northbound lane. Two wingwalls on the Shelby County bridge were sprayed with a Glazon mix made with white cement. On August 3, 1971, both bridges were completed though work was interrupted by rain several times. On August 5, 1971, both bridges were reopened to two-lane traffic. This Division closely observed these operations from the beginning. It was later learned from the Division of Maintenance that the northbound lane of the Shelby County deck, which was badly deteriorating, had been repaired on September 15, 1971

Regime-based TRMM and GV Microphysical Studies at MSFC and UAH

Differences in rain rate between TMI and PR vary systematically with PR Z-profile statistics, whose frequency of occurrence is modified to create seasonal biases in the sub-tropical Southeastern U.S. (and almost certainly elsewhere). Tropical (non-tropical) DSDs in N. Alabama exhibit larger (smaller) D(sub 0), and larger (smaller) N(sub 0) and mu. The formulation process for empirical retrievals of DSD using dual-pol radar is sensitive to D(sub max) assumptions used in the scattering model stage. 4. DSD retrievals from Parsivel disdrometers compare favorably to those of the 2DVD unless rain rates exceed 25 mm/hr and D(sub m) exceeds 2 mm (at which point the Parsivels overestimate D(sub m) and rain rate)

Benchmarking calculations of excitonic couplings between bacteriochlorophylls

Excitonic couplings between (bacterio)chlorophyll molecules are necessary for simulating energy transport in photosynthetic complexes. Many techniques for calculating the couplings are in use, from the simple (but inaccurate) point-dipole approximation to fully quantum-chemical methods. We compared several approximations to determine their range of applicability, noting that the propagation of experimental uncertainties poses a fundamental limit on the achievable accuracy. In particular, the uncertainty in crystallographic coordinates yields an uncertainty of about 20% in the calculated couplings. Because quantum-chemical corrections are smaller than 20% in most biologically relevant cases, their considerable computational cost is rarely justified. We therefore recommend the electrostatic TrEsp method across the entire range of molecular separations and orientations because its cost is minimal and it generally agrees with quantum-chemical calculations to better than the geometric uncertainty. We also caution against computationally optimizing a crystal structure before calculating couplings, as it can lead to large, uncontrollable errors. Understanding the unavoidable uncertainties can guard against striving for unrealistic precision; at the same time, detailed benchmarks can allow important qualitative questions--which do not depend on the precise values of the simulation parameters--to be addressed with greater confidence about the conclusions

Molecular Mechanics Simulations and Improved Tight-binding Hamiltonians for Artificial Light Harvesting Systems: Predicting Geometric Distributions, Disorder, and Spectroscopy of Chromophores in a Protein Environment

We present molecular mechanics {and spectroscopic} calculations on prototype artificial light harvesting systems consisting of chromophores attached to a tobacco mosaic virus (TMV) protein scaffold. These systems have been synthesized and characterized spectroscopically, but information about the microscopic configurations and geometry of these TMV-templated chromophore assemblies is largely unknown. We use a Monte Carlo conformational search algorithm to determine the preferred positions and orientations of two chromophores, Coumarin 343 together with its linker, and Oregon Green 488, when these are attached at two different sites (104 and 123) on the TMV protein. The resulting geometric information shows that the extent of disorder and aggregation properties, and therefore the optical properties of the TMV-templated chromophore assembly, are highly dependent on the choice of chromophores and protein site to which they are bound. We used the results of the conformational search as geometric parameters together with an improved tight-binding Hamiltonian to simulate the linear absorption spectra and compare with experimental spectral measurements. The ideal dipole approximation to the Hamiltonian is not valid since the distance between chromophores can be very small. We found that using the geometries from the conformational search is necessary to reproduce the features of the experimental spectral peaks

Airborne radar sounding evidence for deformable sediments and outcropping bedrock beneath Thwaites Glacier, West Antarctica

The geologic and morphologic records of prior ice sheet configurations show evidence of rapid, back-stepping, meltwater intensive retreats. However, the potential for such a retreat in a contemporary glacier depends on the lithology of the current ice sheet bed, which lies beneath kilometers of ice, making its physical properties difficult to constrain. We use radar sounding and marine bathymetry data to compare the bed configuration of Thwaites Glacier to the bed of paleo-Pine Island Glacier. Using observed and modeled radar scattering, we show that the tributaries and upper trunk of Thwaites Glacier are underlain by ice flow-aligned bedforms consistent with deformable sediment and that the lower trunk is grounded on a region of high bed roughness consistent with outcropping bedrock. This is the same configuration as paleo-Pine Island Glacier during its retreat across the inner continental shelf

Impact of AIRS Thermodynamic Profiles on Precipitation Forecasts for Atmospheric River Cases Affecting the Western United States

No abstract availabl

Distribution of entanglement in light-harvesting complexes and their quantum efficiency

Recent evidence of electronic coherence during energy transfer in photosynthetic antenna complexes has reinvigorated the discussion of whether coherence and/or entanglement has any practical functionality for these molecular systems. Here we investigate quantitative relationships between the quantum yield of a light-harvesting complex and the distribution of entanglement among its components. Our study focusses on the entanglement yield or average entanglement surviving a time scale comparable to the average excitation trapping time. As a prototype system we consider the Fenna-Matthews-Olson (FMO) protein of green sulphur bacteria and show that there is an inverse relationship between the quantum efficiency and the average entanglement between distant donor sites. Our results suggest that longlasting electronic coherence among distant donors might help modulation of the lightharvesting function.Comment: Version accepted for publication in NJ

The Extrapolation of High Altitude Solar Cell I(V) Characteristics to AM0

The high altitude aircraft method has been used at NASA GRC since the early 1960's to calibrate solar cell short circuit current, ISC, to Air Mass Zero (AMO). This method extrapolates ISC to AM0 via the Langley plot method, a logarithmic extrapolation to 0 air mass, and includes corrections for the varying Earth-Sun distance to 1.0 AU and compensating for the non-uniform ozone distribution in the atmosphere. However, other characteristics of the solar cell I(V) curve do not extrapolate in the same way. Another approach is needed to extrapolate VOC and the maximum power point (PMAX) to AM0 illumination. As part of the high altitude aircraft method, VOC and PMAX can be obtained as ISC changes during the flight. These values can then the extrapolated, sometimes interpolated, to the ISC(AM0) value. This approach should be valid as long as the shape of the solar spectra in the stratosphere does not change too much from AMO. As a feasibility check, the results are compared to AMO I(V) curves obtained using the NASA GRC X25 based multi-source simulator. This paper investigates the approach on both multi-junction solar cells and sub-cells