Atomistic Descriptions of Gas-Surface Interactions on Tin Dioxide

Historically, in gas sensing literature, the focus on “mechanisms” has been on oxygen species chemisorbed (ionosorbed) from the ambient atmosphere, but what these species actually represent and the location of the adsorption site on the surface of the solid are typically not well described. Recent advances in computational modelling and experimental surface science provide insights on the likely mechanism by which oxygen and other species interact with the surface of SnO_{2}, providing insight into future directions for materials design and optimisation. This article reviews the proposed models of adsorption and reaction of oxygen on SnO_{2}, including a summary of conventional evidence for oxygen ionosorption and recent operando spectroscopy studies of the atomistic interactions on the surface. The analysis is extended to include common target and interfering reducing gases, such as CO and H_{2}, cross-interactions with H_{2}O vapour, and NO_{2} as an example of an oxidising gas. We emphasise the importance of the surface oxygen vacancies as both the preferred adsorption site of many gases and in the self-doping mechanism of SnO_{2}

Distinguishing Solar Flare Types by Differences in Reconnection Regions

Observations show that magnetic reconnection and its slow shocks occur in solar flares. The basic magnetic structures are similar for long duration event (LDE) flares and faster compact impulsive (CI) flares, but the former require less non-thermal electrons than the latter. Slow shocks can produce the required non-thermal electron spectrum for CI flares by Fermi acceleration if electrons are injected with large enough energies to resonate with scattering waves. The dissipation region may provide the injection electrons, so the overall number of non-thermal electrons reaching the footpoints would depend on the size of the dissipation region and its distance from the chromosphere. In this picture, the LDE flares have converging inflows toward a dissipation region that spans a smaller overall length fraction than for CI flares. Bright loop-top X-ray spots in some CI flares can be attributed to particle trapping at fast shocks in the downstream flow, the presence of which is determined by the angle of the inflow field and velocity to the slow shocks.Comment: 15 pages TeX and 2 .eps figures, accepted to Ap.J.Let

Molecular gyroscopes and biological effects of weak ELF magnetic fields

Extremely-low-frequency magnetic fields are known to affect biological systems. In many cases, biological effects display `windows' in biologically effective parameters of the magnetic fields: most dramatic is the fact that relatively intense magnetic fields sometimes do not cause appreciable effect, while smaller fields of the order of 10--100 $\mu$T do. Linear resonant physical processes do not explain frequency windows in this case. Amplitude window phenomena suggest a nonlinear physical mechanism. Such a nonlinear mechanism has been proposed recently to explain those `windows'. It considers quantum-interference effects on protein-bound substrate ions. Magnetic fields cause an interference of ion quantum states and change the probability of ion-protein dissociation. This ion-interference mechanism predicts specific magnetic-field frequency and amplitude windows within which biological effects occur. It agrees with a lot of experiments. However, according to the mechanism, the lifetime $\Gamma^{-1}$ of ion quantum states within a protein cavity should be of unrealistic value, more than 0.01 s for frequency band 10--100 Hz. In this paper, a biophysical mechanism has been proposed that (i) retains the attractive features of the ion interference mechanism and (ii) uses the principles of gyroscopic motion and removes the necessity to postulate large lifetimes. The mechanism considers dynamics of the density matrix of the molecular groups, which are attached to the walls of protein cavities by two covalent bonds, i.e., molecular gyroscopes. Numerical computations have shown almost free rotations of the molecular gyros. The relaxation time due to van der Waals forces was about 0.01 s for the cavity size of 28 angstr\"{o}ms.Comment: 10 pages, 7 figure

Formation of Episodic Magnetically Driven Radiatively Cooled Plasma Jets in the Laboratory

We report on experiments in which magnetically driven radiatively cooled plasma jets were produced by a 1 MA, 250 ns current pulse on the MAGPIE pulsed power facility. The jets were driven by the pressure of a toroidal magnetic field in a ''magnetic tower'' jet configuration. This scenario is characterized by the formation of a magnetically collimated plasma jet on the axis of a magnetic ''bubble'', confined by the ambient medium. The use of a radial metallic foil instead of the radial wire arrays employed in our previous work allows for the generation of episodic magnetic tower outflows which emerge periodically on timescales of ~30 ns. The subsequent magnetic bubbles propagate with velocities reaching ~300 km/s and interact with previous eruptions leading to the formation of shocks.Comment: 6 pages, 5 figures. Accepted for publication in Astrophysics & Space Scienc

Accretion Disks and Dynamos: Toward a Unified Mean Field Theory

Conversion of gravitational energy into radiation in accretion discs and the origin of large scale magnetic fields in astrophysical rotators have often been distinct topics of research. In semi-analytic work on both problems it has been useful to presume large scale symmetries, necessarily resulting in mean field theories. MHD turbulence makes the underlying systems locally asymmetric and nonlinear. Synergy between theory and simulations should aim for the development of practical mean field models that capture essential physics and can be used for observational modeling. Mean field dynamo (MFD) theory and alpha-viscosity accretion theory exemplify such ongoing pursuits. 21st century MFD theory has more nonlinear predictive power compared to 20th century MFD theory, whereas accretion theory is still in a 20th century state. In fact, insights from MFD theory are applicable to accretion theory and the two are artificially separated pieces of what should be a single theory. I discuss pieces of progress that provide clues toward a unified theory. A key concept is that large scale magnetic fields can be sustained via local or global magnetic helicity fluxes or via relaxation of small scale magnetic fluctuations, without the kinetic helicity driver of 20th century textbooks. These concepts may help explain the formation of large scale fields that supply non-local angular momentum transport via coronae and jets in a unified theory of accretion and dynamos. In diagnosing the role of helicities and helicity fluxes in disk simulations, each disk hemisphere should be studied separately to avoid being misled by cancelation that occurs as a result of reflection asymmetry. The fraction of helical field energy in disks is expected to be small compared to the total field in each hemisphere as a result of shear, but can still be essential for large scale dynamo action.Comment: For the Proceedings of the Third International Conference and Advanced School "Turbulent Mixing and Beyond," TMB-2011 held on 21 - 28 August 2011 at the Abdus Salam International Centre for Theoretical Physics, Trieste, http://users.ictp.it/~tmb/index2011.html Italy, To Appear in Physica Scripta (corrected small items to match version in print

On particle acceleration and trapping by Poynting flux dominated flows

Using particle-in-cell (PIC) simulations, we study the evolution of a strongly magnetized plasma slab propagating into a finite density ambient medium. Like previous work, we find that the slab breaks into discrete magnetic pulses. The subsequent evolution is consistent with diamagnetic relativistic pulse acceleration of \cite{liangetal2003}. Unlike previous work, we use the actual electron to proton mass ratio and focus on understanding trapping vs. transmission of the ambient plasma by the pulses and on the particle acceleration spectra. We find that the accelerated electron distribution internal to the slab develops a double-power law. We predict that emission from reflected/trapped external electrons will peak after that of the internal electrons. We also find that the thin discrete pulses trap ambient electrons but allow protons to pass through, resulting in less drag on the pulse than in the case of trapping of both species. Poynting flux dominated scenarios have been proposed as the driver of relativistic outflows and particle acceleration in the most powerful astrophysical jets.Comment: 25 pages, Accepted by Plasma Physics and Controlled Fusio