14,901 research outputs found
Microrheological Characterisation of Anisotropic Materials
We describe the measurement of anisotropic viscoelastic moduli in complex
soft materials, such as biopolymer gels, via video particle tracking
microrheology of colloid tracer particles. The use of a correlation tensor to
find the axes of maximum anisotropy, and hence the mechanical director, is
described. The moduli of an aligned DNA gel are reported, as a test of the
technique; this may have implications for high DNA concentrations in vivo. We
also discuss the errors in microrheological measurement, and describe the use
of frequency space filtering to improve displacement resolution, and hence
probe these typically high modulus materials.Comment: 5 pages, 5 figures. Replaced after refereeing/ improvement. Main
results are the same. The final, published version of the paper is here
http://link.aps.org/abstract/PRE/v73/e03190
Interfacial friction between semiflexible polymers and crystalline surfaces
The results obtained from molecular dynamics simulations of the friction at
an interface between polymer melts and weakly attractive crystalline surfaces
are reported. We consider a coarse-grained bead-spring model of linear chains
with adjustable intrinsic stiffness. The structure and relaxation dynamics of
polymer chains near interfaces are quantified by the radius of gyration and
decay of the time autocorrelation function of the first normal mode. We found
that the friction coefficient at small slip velocities exhibits a distinct
maximum which appears due to shear-induced alignment of semiflexible chain
segments in contact with solid walls. At large slip velocities the decay of the
friction coefficient is independent of the chain stiffness. The data for the
friction coefficient and shear viscosity are used to elucidate main trends in
the nonlinear shear rate dependence of the slip length. The influence of chain
stiffness on the relationship between the friction coefficient and the
structure factor in the first fluid layer is discussed.Comment: 31 pages, 12 figure
The relationship between induced fluid structure and boundary slip in nanoscale polymer films
The molecular mechanism of slip at the interface between polymer melts and
weakly attractive smooth surfaces is investigated using molecular dynamics
simulations. In agreement with our previous studies on slip flow of
shear-thinning fluids, it is shown that the slip length passes through a local
minimum at low shear rates and then increases rapidly at higher shear rates. We
found that at sufficiently high shear rates, the slip flow over atomically flat
crystalline surfaces is anisotropic. It is demonstrated numerically that the
friction coefficient at the liquid-solid interface (the ratio of viscosity and
slip length) undergoes a transition from a constant value to the power-law
decay as a function of the slip velocity. The characteristic velocity of the
transition correlates well with the diffusion velocity of fluid monomers in the
first fluid layer near the solid wall at equilibrium. We also show that in the
linear regime, the friction coefficient is well described by a function of a
single variable, which is a product of the magnitude of surface-induced peak in
the structure factor and the contact density of the adjacent fluid layer. The
universal relationship between the friction coefficient and induced fluid
structure holds for a number of material parameters of the interface: fluid
density, chain length, wall-fluid interaction energy, wall density, lattice
type and orientation, thermal or solid walls.Comment: 33 pages, 14 figure
Quantum dot dephasing by edge states
We calculate the dephasing rate of an electron state in a pinched quantum
dot, due to Coulomb interactions between the electron in the dot and electrons
in a nearby voltage biased ballistic nanostructure. The dephasing is caused by
nonequilibrium time fluctuations of the electron density in the nanostructure,
which create random electric fields in the dot. As a result, the electron level
in the dot fluctuates in time, and the coherent part of the resonant
transmission through the dot is suppressed
Gaussian approximation for finitely extensible bead-spring chains with hydrodynamic interaction
The Gaussian Approximation, proposed originally by Ottinger [J. Chem. Phys.,
90 (1) : 463-473, 1989] to account for the influence of fluctuations in
hydrodynamic interactions in Rouse chains, is adapted here to derive a new
mean-field approximation for the FENE spring force. This "FENE-PG" force law
approximately accounts for spring-force fluctuations, which are neglected in
the widely used FENE-P approximation. The Gaussian Approximation for
hydrodynamic interactions is combined with the FENE-P and FENE-PG spring force
approximations to obtain approximate models for finitely-extensible bead-spring
chains with hydrodynamic interactions. The closed set of ODE's governing the
evolution of the second-moments of the configurational probability distribution
in the approximate models are used to generate predictions of rheological
properties in steady and unsteady shear and uniaxial extensional flows, which
are found to be in good agreement with the exact results obtained with Brownian
dynamics simulations. In particular, predictions of coil-stretch hysteresis are
in quantitative agreement with simulations' results. Additional simplifying
diagonalization-of-normal-modes assumptions are found to lead to considerable
savings in computation time, without significant loss in accuracy.Comment: 26 pages, 17 figures, 2 tables, 75 numbered equations, 1 appendix
with 10 numbered equations Submitted to J. Chem. Phys. on 6 February 200
Evaluating the Applicability of the Fokker-Planck Equation in Polymer Translocation: A Brownian Dynamics Study
Brownian dynamics (BD) simulations are used to study the translocation
dynamics of a coarse-grained polymer through a cylindrical nanopore. We
consider the case of short polymers, with a polymer length, N, in the range
N=21-61. The rate of translocation is controlled by a tunable friction
coefficient, gamma_{0p}, for monomers inside the nanopore. In the case of
unforced translocation, the mean translocation time scales with polymer length
N as ~ (N-N_p)^alpha, where N_p is the average number of monomers in the
nanopore. The exponent approaches the value alpha=2 when the pore friction is
sufficiently high, in accord with the prediction for the case of the
quasi-static regime where pore friction dominates. In the case of forced
translocation, the polymer chain is stretched and compressed on the cis and
trans sides, respectively, for low gamma_{0p}. However, the chain approaches
conformational quasi-equilibrium for sufficiently large gamma_{0p}. In this
limit the observed scaling of with driving force and chain length
supports the FP prediction that is proportional to N/f_d for sufficiently
strong driving force. Monte Carlo simulations are used to calculate
translocation free energy functions for the system. The free energies are used
with the Fokker-Planck equation to calculate translocation time distributions.
At sufficiently high gamma_{0p}, the predicted distributions are in excellent
agreement with those calculated from the BD simulations. Thus, the FP equation
provides a valid description of translocation dynamics for sufficiently high
pore friction for the range of polymer lengths considered here. Increasing N
will require a corresponding increase in pore friction to maintain the validity
of the FP approach. Outside the regime of low N and high pore friction, the
polymer is out of equilibrium, and the FP approach is not valid.Comment: 13 pages, 11 figure
Thermodiffusion in model nanofluids by molecular dynamics simulations
In this work, a new algorithm is proposed to compute single particle
(infinite dilution) thermodiffusion using Non-Equilibrium Molecular Dynamics
simulations through the estimation of the thermophoretic force that applies on
a solute particle. This scheme is shown to provide consistent results for
simple Lennard-Jones fluids and for model nanofluids (spherical non-metallic
nanoparticles + Lennard-Jones fluid) where it appears that thermodiffusion
amplitude, as well as thermal conductivity, decrease with nanoparticles
concentration. Then, in nanofluids in the liquid state, by changing the nature
of the nanoparticle (size, mass and internal stiffness) and of the solvent
(quality and viscosity) various trends are exhibited. In all cases the single
particle thermodiffusion is positive, i.e. the nanoparticle tends to migrate
toward the cold area. The single particle thermal diffusion 2 coefficient is
shown to be independent of the size of the nanoparticle (diameter of 0.8 to 4
nm), whereas it increases with the quality of the solvent and is inversely
proportional to the viscosity of the fluid. In addition, this coefficient is
shown to be independent of the mass of the nanoparticle and to increase with
the stiffness of the nanoparticle internal bonds. Besides, for these
configurations, the mass diffusion coefficient behavior appears to be
consistent with a Stokes-Einstein like law
XMM-Newton and INTEGRAL analysis of the Supergiant Fast X-ray Transient IGR J17354-3255
We present the results of combined INTEGRAL and XMM-Newton observations of
the supergiant fast X-ray transient (SFXT) IGR J173543255. Three XMM-Newton
observations of lengths 33.4 ks, 32.5 ks and 21.9 ks were undertaken, the first
an initial pointing to identify the correct source in the field of view and the
latter two performed around periastron. Simultaneous INTEGRAL observations
across of the orbital cycle were analysed but the source was neither
detected by IBIS/ISGRI nor by JEM-X. The XMM-Newton light curves display a
range of moderately bright X-ray activity but there are no particularly strong
flares or outbursts in any of the three observations. We show that the spectral
shape measured by XMM-Newton can be fitted by a consistent model throughout the
observation, suggesting that the observed flux variations are driven by
obscuration from a wind of varying density rather than changes in accretion
mode. The simultaneous INTEGRAL data rule out simple extrapolation of the
simple powerlaw model beyond the XMM-Newton energy range.Comment: 13 pages, 9 figures, This article has been accepted for publication
in Monthly Notices of the Royal Astronomical Society Published by Oxford
University Pres
Signature of elasticity in the Faraday instability
We investigate the onset of the Faraday instability in a vertically vibrated
wormlike micelle solution. In this strongly viscoelastic fluid, the critical
acceleration and wavenumber are shown to present oscillations as a function of
driving frequency and fluid height. This effect, unseen neither in simple
fluids nor in previous experiments on polymeric fluids, is interpreted in terms
of standing elastic waves between the disturbed surface and the container
bottom. It is shown that the model of S. Kumar [Phys. Rev. E, {\bf 65}, 026305
(2002)] for a viscoelastic fluid accounts qualitatively for our experimental
observations. Explanations for quantitative discrepancies are proposed, such as
the influence of the nonlinear rheological behaviour of this complex fluid.Comment: 4 pages, 4 figure
Parallel Temperatures in Supersonic Beams: Ultra Cooling of Light Atoms seeded in a Heavier Carrier Gas
We have found recently that, in a supersonic expansion of a mixture of two
monoatomic gases, the parallel temperatures of the two gases can be very
different. This effect is large if the seeded gas is highly diluted and if its
atomic mass is considerably smaller than the one of the carrier gas. In the
present paper, we present a complete derivation of our theoretical analysis of
this effect. Our calculation is a natural extension of the existing theory of
supersonic cooling to the case of a gas mixture, in the high dilution limit.
Finally, we describe a set of temperature measurements made on a beam of
lithium seeded in argon. Our experimental results are in very good agreement
with the results of our calculation.Comment: 24 novembre 200
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