Improved bulk density of bamboo pellets as biomass for energy production

To the best of our knowledge, there is the lack of sufficient information concerning bamboo pellets. In the preliminary research, bamboo pellets showed a low bulk density which could not meet requirement of Pellet Fuels Institute Standard Specification for Residential/Commercial Densified (PFI). To improve its bulk density, pellets were manufactured using mixtures of bamboo and pine particles and the properties were investigated. It was found that adding pine particles to bamboo particles was an effective way to improve bulk density of bamboo pellets. When adding 40% pine particles to bamboo particles, bulk density of pellets increased from 0.54 g/cm3 to 0.60 g/cm3, meeting grade requirement of PFI utility. Furthermore, length, diameter and inorganic ash of pellets were also improved. Fine contents of pellets decreased from premium grade to utility grade according to PFI standard. Net calorific value also slightly decreased but it could meet the requirement of DIN 51731 (\u3e17,500 J/g). The effect of this interaction on bulk density, inorganic ash, Net calorific value, combustion rate and heat release rate were significant. The results from this research will be very helpful to develop bamboo pellets and provide guidelines for further research

Improved bulk density of bamboo pellets as biomass for energy production

To the best of our knowledge, there is the lack of sufficient information concerning bamboo pellets. In the preliminary research, bamboo pellets showed a low bulk density which could not meet requirement of Pellet Fuels Institute Standard Specification for Residential/Commercial Densified (PFI). To improve its bulk density, pellets were manufactured using mixtures of bamboo and pine particles and the properties were investigated. It was found that adding pine particles to bamboo particles was an effective way to improve bulk density of bamboo pellets. When adding 40% pine particles to bamboo particles, bulk density of pellets increased from 0.54 g/cm3 to 0.60 g/cm3, meeting grade requirement of PFI utility. Furthermore, length, diameter and inorganic ash of pellets were also improved. Fine contents of pellets decreased from premium grade to utility grade according to PFI standard. Net calorific value also slightly decreased but it could meet the requirement of DIN 51731 (\u3e17,500 J/g). The effect of this interaction on bulk density, inorganic ash, Net calorific value, combustion rate and heat release rate were significant. The results from this research will be very helpful to develop bamboo pellets and provide guidelines for further research

Nitrogen-Doped Porous Carbon Derived from Bamboo Shoot as Solid Base Catalyst for Knoevenagel Condensation and Transesterification Reactions

Highly porous nitrogen-doped carbons derived from bamboo shoots (BSNCs) were prepared through an in-situ synthesis method. The results showed that BSNCs had a large specific surface area, a relatively high nitrogen content and hierarchically porous structures. The catalytic properties of BSNCs were evaluated based on Knoevenagel condensation and transesterification reactions. Deprotonated BSNC-700 exhibited high efficiency for the model reactions as a solid base catalyst, and the superior sample deprotonated in tBuOK solution with a concentration of 0.1 increased the conversion rate from 16.1% to 76.0% for Knoevenagel condensation. The two reactions proceeded smoothly in the presence of deprotonated BSNC-700. The results also showed that the catalyst could be recycled for several times for Knoevenagel condensation. The results from this research will provide a guideline to develop bamboo shoot as a precursor to fabricate a superb solid base catalyst

Nitrogen Self-Doped Activated Carbons Derived from Bamboo Shoots as Adsorbent for Methylene Blue Adsorption

Bamboo shoots, a promising renewable biomass, mainly consist of carbohydrates and other nitrogen-related compounds, such as proteins, amino acids and nucleotides. In this work, nitrogen self-doped activated carbons derived from bamboo shoots were prepared via a simultaneous carbonization and activation process. The adsorption properties of the prepared samples were evaluated by removing methylene blue from waste water. The factors that affect the adsorption process were examined, including initial concentration, contact time and pH of methylene blue solution. The resulting that BSNC-800-4 performed better in methylene blue removal from waste water, due to its high specific surface area (2270.9 m2 g−1), proper pore size (2.19 nm) and relatively high nitrogen content (1.06%). Its equilibrium data were well fitted to Langmuir isotherm model with a maximum monolayer adsorption capacity of 458 mg g−1 and a removal efficiency of 91.7% at methylene blue concentration of 500 mg L−1. The pseudo-second-order kinetic model could be used to accurately estimate the carbon material’s (BSNC-800-4) adsorption process. The adsorption mechanism between methylene blue solution and BSNC-800-4 was controlled by film diffusion. This study provides an alternative way to develop nitrogen self-doped activated carbons to better meet the needs of the adsorption applications

Responses of dry matter accumulation and partitioning to drought and subsequent rewatering at different growth stages of maize in Northeast China

IntroductionDry matter accumulation (DMA) and dry matter partitioning (DMP) are important physiological processes determining crop yield formation. Deep understanding of the DMA and DMP processes and their responses to drought are limited by difficulty in acquiring total root biomass.MethodsPot experiments with treatments quitting and ceasing ear growth (QC) and controlling soil water (WC) during vegetative (VP) and reproductive (RP) growth stages of maize (Zea mays) were conducted in Jinzhou in 2019 and 2020 to investigate the effects of drought and rewatering on DMW and DMP of different organs.ResultsThe response of DMW of reproductive organ to drought was more sensitive than those of vegetative organs, and was maintained after rehydration. Drought during VP (VPWC) reduced more sharply DMW of stalk than of leaves, and that during RP (RPWC) decreased more substantially leaves DMW. The effect of drought on DMPR was inconsistent with that on DMW for each organ. The DMP patterns of maize in different growth stages have adaptability to some level of water stress, and their responses increased with drought severity. Drought increased significantly DMP rates (DMPRs) of vegetative organs and reduced the ear DMPR and harvest index (HI), attributing to the suppressed photosynthates partitioning into ear and dry matter redistribution (DMRD) of vegetative organs, especially for stalk DMRD decreasing 26%. The persistence of drought impact was related to its occurrence stage and degree as well as the duration during rewatering to maturity. The aftereffect of drought during different growth periods on DMP were various, and that of VPWC enlarged and drastically induced the reduction of HI, also was larger than that of RPWC which demonstrated obvious alleviation in the previous responses of DMP and HI. Root-shoot ratio (RSR) increased under VPWC and RPWC and subsequent rehydration.DiscussionThe DMWs of stalk, roots and leaves were affected by VPWC in order from large to small, and were close to or larger than the controls after rehydration, indicating the compensation effect of rewatering after drought. The DMPRs, RSR AND HI are the important parameters in agricultural production, and are often used as the constants, but in fact they vary with plant growth. In addition, the interannual differences in ear and stalk DMPRs in response to drought were probably caused by the difference in degree and occurrence stage of drought, further reflecting the variation in response of allometry growth among organs to the environment. Besides, the persistence of drought impact was related to the occurrence stage and degree of drought, which is also associated with the duration during rewatering to maturity. Notably, the effect of drought on DMW was inconsistent with that on DMPR for each organ meaning that the two variables should be discussed separately. The QC did not affect total DMW but increased RSR, changed and intensified the effect and aftereffect of RPWC on DMP, respectively, indicating that the DMP pattern and its response to drought occur change under the condition of QC

INVESTIGATING GASEOUS CARBON, NITROGEN, AND SULFUR COMPOUNDS OF BAMBOO, WOOD, AND COAL DURING PYROLYSIS PROCESS

Bamboo, wood, and coal were pyrolyzed by a thermogravimetric analyzer coupled with Fourier transform infrared spectrometry to investigate gaseous carbon, nitrogen, and sulfur compounds from fuels. It was found that the main gas compounds of fuels included carbon dioxide, carbon monoxide, methane, sulfur dioxide, hydrogen sulfide, ammonia gas, and hydrogen cyanide. Compared with masson pine, bamboo had a higher gas release and more mass loss due to its lower pyrolysis temperatures when temperature was lower than 350°C. Coal had the lowest gas release and the least mass loss due to the higher pyrolysis temperature during the whole pyrolysis process. The char-C, N, and S contents of all fuels increased with increase in pyrolysis temperature. The results from this research will be helpful to utilize the wastes of masson pine and bamboo for energy products. 

INVESTIGATING SYNERGISTIC INTERACTION OF BAMBOO AND TORREFIED BAMBOO WITH COAL DURING COCOMBUSTION

To investigate if there is synergistic interaction between bamboo with coal, or between torrefied bamboo with coal during cocombustion, bamboo and torrefied bamboo separately were respectively uniformly mixed with coal and the weight percentage of bamboo or torrefied bamboo in the mixture were 10%, 20%, 30%, and 40%. The combustion behaviors of blends were characterized using thermogravimentric analyzer at heating rates of 10°C/min, 20°C/min, 30°C/min, and 40°C/min. Results showed that the combustion process of bamboo and coal combustion was separated during cocombustion, and the higher temperature zone corresponding to coal combustion had a higher activation energy. Cocombustion of torrefied bamboo and coal had a combustion zone. Combustion characteristics gradually increased with increase in heating rates and decrease in mixing ratios. Theoretical combustion characteristics obviously shifted to higher temperatures, indicating synergistic interactions between bamboo/torrefied bamboo and coal. Cocombustion of torrefied bamboo and coal was more feasible with a stabler combustion process. The results might be helpful to promote bamboo resources as a blend fuel for co-firing application with coal

An Efficient Processing Approach for Colored Point Cloud-Based High-Throughput Seedling Phenotyping

Plant height and leaf area are important morphological properties of leafy vegetable seedlings, and they can be particularly useful for plant growth and health research. The traditional measurement scheme is time-consuming and not suitable for continuously monitoring plant growth and health. Individual vegetable seedling quick segmentation is the prerequisite for high-throughput seedling phenotype data extraction at individual seedling level. This paper proposes an efficient learning- and model-free 3D point cloud data processing pipeline to measure the plant height and leaf area of every single seedling in a plug tray. The 3D point clouds are obtained by a low-cost red–green–blue (RGB)-Depth (RGB-D) camera. Firstly, noise reduction is performed on the original point clouds through the processing of useable-area filter, depth cut-off filter, and neighbor count filter. Secondly, the surface feature histograms-based approach is used to automatically remove the complicated natural background. Then, the Voxel Cloud Connectivity Segmentation (VCCS) and Locally Convex Connected Patches (LCCP) algorithms are employed for individual vegetable seedling partition. Finally, the height and projected leaf area of respective seedlings are calculated based on segmented point clouds and validation is carried out. Critically, we also demonstrate the robustness of our method for different growth conditions and species. The experimental results show that the proposed method could be used to quickly calculate the morphological parameters of each seedling and it is practical to use this approach for high-throughput seedling phenotyping

Antimicrobial Bamboo Materials Functionalized with ZnO and Graphene Oxide Nanocomposites

Bamboo materials with improved antibacterial performance based on ZnO and graphene oxide (GO) were fabricated by vacuum impregnation and hydrothermal strategies. The Zn2+ ions and GO nanosheets were firstly infiltrated into the bamboo structure, followed by dehydration and crystallization upon hydrothermal treatment, leading to the formation of ZnO/GO nanocomposites anchored in the bulk bamboo. The bamboo composites were characterized by several techniques including scanning electron microscopy (SEM), Fourier transform infrared spectra (FTIR), and X-ray diffraction (XRD), which confirmed the existence of GO and ZnO in the composites. Antibacterial performances of bamboo samples were evaluated by the bacteriostatic circle method. The introduction of ZnO/GO nanocomposites into bamboo yielded ZnO/GO/bamboo materials which exhibited significant antibacterial activity against Escherichia coli (E. coli, Gram-negative) and Bacillus subtilis (B. subtilis, Gram-positive) bacteria and high thermal stability. The antimicrobial bamboo would be expected to be a promising material for the application in the furniture, decoration, and construction industry

INVESTIGATING CHEMICAL PROPERTIES AND COMBUSTION CHARACTERISTICS OF TORREFIED MASSON PINE

To investigate chemical properties and combustion characteristics, masson pine was torrefied using GSL 1600X tube furnance in the argon atmosphere. The properties of torrefied masson pine were respectively determined through thermogravimetry (TGA), fourier transform infrared spectrometer (FTIR) and X-ray diffraction (XRD). Results showed that thermal decomposition of hemicelluloses, cellulose and lignin occurred during torrefaction process. Crystalline region of cellulose was destroyed when temperature was up to 250℃. The effect of torrefaction temperature was more significant than that of residence time. Torrefaction improved combustion characteristics of masson pine. The optimum process was 300℃ of torrefaction temperature and 2.0h of residence time. Combustion process of torrefied masson pine included drying, oxidative pyrolysis and char combustion. Torrefied masson pine had a lower H/C and O/C ratios, peak temperature of oxidative pyrolysis and char combustion and burnout temperature. It had a higher energy density, ignition temperature and activation energy. This data will be significant to understand the torrefied masson pine for energy product to directly combustion