Novel fiber-reinforced composite materials based on sustainable geopolymer matrix

Geopolymers are representing the most promising green and eco-friendly alternative to ordinary Portland cement and cementitious materials, thanks to their proven durability, mechanical and thermal properties. However, despite these features, the poor tensile and bending strengths usually exhibited by geopolymers due to their brittle and ceramic-like nature, can easily lead to catastrophic failure and represent the main drawback limiting the use of those materials in several applications. Fiber reinforced geopolymer composites may be considered a solution to improve flexural strength and fracture toughness. Different types of dispersed short fibers are here investigated as a reinforcing fraction for a geopolymer matrix based on an alkali-activated ladle-slag. It has been demonstrated that both organic and inorganic fibers can lead to a significant flexural strength enhancement. Moreover, the investigated geopolymers exhibit an increase in toughness, thus determining a switch from a brittle failure mode to a more ductile one

Gender Balance in Construction Material Research: The Analysis of Alkali-Activated Materials by a Bibliometric Study Using Scopus Database

Research in alkali-activated materials (AAMs) is an innovative and dynamic material science topic. This is due to the relevant performances in terms of physico-mechanical properties comparable to traditional construction materials (e.g., ordinary Portland cement). The sustainability of AAMs is often highlighted since they can be developed by using many natural or industrial by-products–based precursors. This leads to challenges with the optimization of AAM production due to their different performances, availability, and costs. However, they are flexible and locally adapted materials. The research interest in AAMs has rapidly increased in the early 2000s. In recent years, about 1,000 international articles have been published each year. This study aims at assessing the gender balance of this specific research topic to investigate the relevance of women’s participation. Author lists of the published articles were analyzed throughout the Scopus database, applying “alkali-activated material” and “geopolymers” as keywords in the titles, abstracts, and keywords search. The last 10 years (2009–2019) were taken into account. The gender of the most prolific authors was analyzed, and a focus of European authors on this topic was considered, as more than 25% of the research in AAMs have been carried out in Europe. The analysis of 5,900 publications in the last decade shows that there is currently a shift toward men in the gender balance in this specific research, and female authors only covered 22% of the most productive authors worldwide. Considering European authors, a more equal gender distribution is reached, when the first author is considered, with a concentration of women in the range of 36–56%, recorded over 1,396 articles

INTRAOPERATIVE CLINICAL TEST FOR KINEMATIC ASSESSMENT OF ACl GRAFT BEHAVIOUR WITH COMPUTER ASSISTED PROCEDURE

This paper describes a protocol for an accurate and extensive computer-assisted in vivo evaluation of joint laxities durinQl reconstructions of anterior cruciate ,ligament (ACL). The operating technique is a double bundle with over the top graft. Kinematic tests are performed, intraoperatively, before the ACL reconstruction, with ACL deficient knees, and after the ACL reconstruction. Results of first four in vivo cases, highlight that the reconstruction gives a complete restore of stability, in the antero-posterior direction, at 30° and 90° degrees giving and increased stability up to 73%, confirming the role of the ACL in the control of AP dislocation. Internal and external rotations were also satisfactorily restored after the graft fixation; in particular at 30° of tlexion, the reconstruction gives a good control of the joint, reducing laxity up to 43%

Efficient Anodically Grown WO3 for Photoelectrochemical Water Splitting

Abstract The potentiostatic anodization of metallic tungsten has been investigated in different solvent/electrolyte compositions with the aim of improving the photoelectrochemical performances of the tungsten oxide layer. Among the explored electrolytes, the anodization in the NMF/H2O/NH4F solvent mixture was found to produce the most efficient WO3 photoanodes, which, combining spectral sensitivity, high electrochemically active surface and improved charge transfer kinetics, outperform, under simulated solar illumination, most of the reported nanocrystalline substrates produced by anodization in aqueous electrolytes and by sol gel methods. While the preparation of the photoelectrodes is a slow process at room temperature (20 °C), it could be greatly accelerated (x 10) by carrying out the anodization at 40-50 °C, thus proving to be a fast and convenient approach to the production of high performing WO3 photoactive substrates directly connected to a metal electron collector

A new strategy against peri-implantitis: Antibacterial internal coating

The bacterial biofilm formation in the oral cavity and the microbial activity around the implant tissue represent a potential factor on the interface between bone and implant fixture that could induce an inflammatory phenomenon and generate an increased risk for mucositis and peri-implantitis. The aim of the present clinical trial was to investigate the bacterial quality of a new antibacterial coating of the internal chamber of the implant in vivo at six months. The PIXIT implant (Edierre srl, Genova Italy) is prepared by coating the implant with an alcoholic solution containing polysiloxane oligomers and chlorhexidine gluconate at 1%. A total of 15 healthy patients (60 implants) with non-contributory past medical history (nine women and six men, all non-smokers, mean age of 53 years, ranging from 45–61 years) were scheduled to receive bilateral fixed prostheses or crown restorations supported by an implant fixture. No adverse effects and no implant failure were reported at four months. All experimental sites showed a good soft tissue healing at the experimental point times and no local evidence of inflammation was observed. Real-Time Polymerase Chain Reaction (PCR) analysis on coated and uncoated implants showed a decrease of the bacterial count in the internal part of the implant chamber. The mean of total bacteria loading (TBL) detected in each PCR reaction was lower in treated implants (81,038 units/reaction) compared to untreated implants (90,057 units/reaction) (p < 0.01). The polymeric chlorhexydine coating of the internal chamber of the implant showed the ability to control the bacterial loading at the level of the peri-implant tissue. Moreover, the investigation demonstrated that the coating is able to influence also the quality of the microbiota, in particular on the species involved in the pathogenesis of peri-implantitis that are involved with a higher risk of long-term failure of the dental implant restoration

LH supplementation of ovarian stimulation protocols influences follicular fluid steroid composition contributing to the improvement of ovarian response in poor responder women.

Abstract In this prospective study, we evaluated the steroid levels in 111 follicular fluids (FF) collected from 13 women stimulated with FSH monotherapy and 205 FF collected from 28 women stimulated with FSH + LH because of a previous history of hypo-responsiveness to FSH. Steroid levels were measured by HPLC/MS–MS and related to ovarian stimulation protocol, oocyte maturity, fertilization and quality of blastocysts, after individually tracking the fate of all retrieved oocytes. 17-Hydroxy-Progesterone, Androstenedione, Estradiol and Estrone were significantly higher in the FSH + LH protocol. Progesterone, 17-Hydroxy-Progesterone and Estradiol were more expressed in FF yielding a mature oocyte (p < 0.01) in the FSH + LH protocol. FF Progesterone concentration was correlated with the rate of normal fertilization in the FSH protocol. None of the FF steroids measured were associated with blastocyst quality and achievement of pregnancy. Our results indicate that LH supplementation in hypo-responsive women modifies ovarian steroid production, mimicking physiological production better and likely contributing to an improved ovarian response. Employing a correct methodological procedure to evaluate the relationship between FF steroid hormones and assisted reproduction outcomes, our study reveals that some steroids in single follicles may be helpful in predicting oocyte maturity and fertilization

Copper Complexes as Effective Competitors for Iodine-free Electrolytes in Dye-Sensitized Solar Cells

Dye-sensitized solar cells, DSSCs, are photoelectrochemical devices well contextualized within the global commitment for the progressive increase of the percentage of electric energy produced by renewable resources. In the last decade the development of novel redox mediators alternative to the ubiquitous iodine-based electrolyte (identified as one of the principal causes of the stagnant PCE values in which the research got bogged down) has been one of the hottest topic of research. Efforts of many scientists have been catalyzed by metal complexes as promising single electron mediators characterized by an easy modulation of many electrochemical and optical features requested to ideal electron shuttles. While tris(diimine) cobalt complexes largely monopolize recent literature, our group has focused on homoleptic 1,10-phenanthroline-based copper complexes relying on the fact that their intrinsic limitations, if suitable tailored, could represent the turning point toward a new generation of electron shuttles. Starting from \u201cstructure vs activity maps\u201d correlating ligand substitutions with the electrochemical features of this class of complexes, we have proposed convenient Cu-based redox couples based on bulky 2-substituted phenanthrolines that reached efficiency higher than 6%, more than doubling the PCE of cells filled with the unique benchmark copper-based redox shuttle (12/22, in figure below) and even exceeding performance of a control I\u2013/I3\u2013-based electrolyte