The Influence of Parental Alcoholism on Parent–Adolescent Relationships From Adolescence Into Emerging Adulthood: A Qualitative Inquiry

Exposure to parental alcoholism can inhibit a child’s ability to become a successfully functioning young adult. Based on qualitative interviews, this study provides a deeper understanding of how those parent–adolescent relationships are associated with risky internalizing and externalizing behaviors. This qualitative study explores the lives of 13 young adult children of alcoholics (ACOAs) and provides a unique perspective through an adaptive developmental approach by evaluating emerging adults who were ACOAs and successfully functioning. Compelling findings emerged with respect to how young adults define alcoholism and being a child of alcoholism and how the parent–adolescent relationship adapts in the unstable environment associated with family alcoholism. Salient findings revealed that when emotional and physical detachment from a parent’s alcoholic behaviors in addition to an acceptance that those behaviors are not the adolescent’s responsibility, individuals gained better control of their environment aiding them in becoming healthy, functioning young adults

Alkali metal derivatives of an ortho-phenylene diamine

Treatment of the ortho-phenylene diamine C6H4-1,2-{N(H)Tripp}2 (1, PDAH2, Tripp = 2,4,6-triisopropylphenyl) with two equivalents of MR (M = Li, R = Bun; M = Na or K, R = CH2C6H5) afforded the dimetallated alkali metal ortho-phenylene diamide dianion complexes [(PDALi2)(THF)3] (2), [{(PDANa2)(THF)2}2] (3), and [{(PDAK2)(THF)3}2] (4). In contrast, treatment of 2 with two equivalents of rubidium or cesium 2-ethylhexoxide, or treatment of 1 with two equivalents of MR (M = Rb or Cs, R = CH2C6H5) did not afford the anticipated dialkali metal ortho-phenylene diamide dianion derivatives and instead formally afforded the monometallic ortho-diiminosemiquinonate radical anion species [PDAM] (M = Rb, 5; M = Cs, 6). The structure of 2 is monomeric with one lithium coordinated to the two nitrogen centres and the other lithium η4-coordinated to the diazabutadiene portion of the PDA scaffold. Similar structural cores are observed for 3 and 4, except that the larger sodium and potassium ions give dimeric structures linked by multi-hapto interactions from the PDA backbone phenyl ring to an alkali metal centre. Complex 5 was not characterised in the solid state, but the structure of 6 reveals coordination of cesium ions to both PDA amide centres and multi-hapto interactions to a PDA backbone phenyl ring in the next unit to generate a one-dimensional polymer. Complexes 2–6 have been variously characterised by X-ray crystallography, multi-nuclear NMR, FTIR, and EPR spectroscopies, and CHN microanalyses