Limiting the valence: advancements and new perspectives on patchy colloids, soft functionalized nanoparticles and biomolecules

Limited bonding valence, usually accompanied by well-defined directional interactions and selective bonding mechanisms, is nowadays considered among the key ingredients to create complex structures with tailored properties: even though isotropically interacting units already guarantee access to a vast range of functional materials, anisotropic interactions can provide extra instructions to steer the assembly of specific architectures. The anisotropy of effective interactions gives rise to a wealth of self-assembled structures both in the realm of suitably synthesized nano- and micro-sized building blocks and in nature, where the isotropy of interactions is often a zero-th order description of the complicated reality. In this review, we span a vast range of systems characterized by limited bonding valence, from patchy colloids of new generation to polymer-based functionalized nanoparticles, DNA-based systems and proteins, and describe how the interaction patterns of the single building blocks can be designed to tailor the properties of the target final structures

Towards Baselines for Shoulder Surfing on Mobile Authentication

Given the nature of mobile devices and unlock procedures, unlock authentication is a prime target for credential leaking via shoulder surfing, a form of an observation attack. While the research community has investigated solutions to minimize or prevent the threat of shoulder surfing, our understanding of how the attack performs on current systems is less well studied. In this paper, we describe a large online experiment (n=1173) that works towards establishing a baseline of shoulder surfing vulnerability for current unlock authentication systems. Using controlled video recordings of a victim entering in a set of 4- and 6-length PINs and Android unlock patterns on different phones from different angles, we asked participants to act as attackers, trying to determine the authentication input based on the observation. We find that 6-digit PINs are the most elusive attacking surface where a single observation leads to just 10.8% successful attacks, improving to 26.5\% with multiple observations. As a comparison, 6-length Android patterns, with one observation, suffered 64.2% attack rate and 79.9% with multiple observations. Removing feedback lines for patterns improves security from 35.3\% and 52.1\% for single and multiple observations, respectively. This evidence, as well as other results related to hand position, phone size, and observation angle, suggests the best and worst case scenarios related to shoulder surfing vulnerability which can both help inform users to improve their security choices, as well as establish baselines for researchers.Comment: Will appear in Annual Computer Security Applications Conference (ACSAC

Time series analysis for financial market meltdowns

There appears to be a consensus that the recent instability in global financial markets may be attributable in part to the failure of financial modeling. More specifically, current risk models have failed to properly assess the risks associated with large adverse stock price behavior. In this paper, we first discuss the limitations of classical time series models for forecasting financial market meltdowns. Then we set forth a framework capable of forecasting both extreme events and highly volatile markets. Based on the empirical evidence presented in this paper, our framework offers an improvement over prevailing models for evaluating stock market risk exposure during distressed market periods. --ARMA-GARCH model,»-stable distribution,tempered stable distribution,value-at-risk (VaR),average value-at-risk (AVaR)

Scalable Spatiotemporal Graph Neural Networks

Source at https://ojs.aaai.org/index.php/AAAI/index.Neural forecasting of spatiotemporal time series drives both research and industrial innovation in several relevant application domains. Graph neural networks (GNNs) are often the core component of the forecasting architecture. However, in most spatiotemporal GNNs, the computational complexity scales up to a quadratic factor with the length of the sequence times the number of links in the graph, hence hindering the application of these models to large graphs and long temporal sequences. While methods to improve scalability have been proposed in the context of static graphs, few research efforts have been devoted to the spatiotemporal case. To fill this gap, we propose a scalable architecture that exploits an efficient encoding of both temporal and spatial dynamics. In particular, we use a randomized recurrent neural network to embed the history of the input time series into high-dimensional state representations encompassing multi-scale temporal dynamics. Such representations are then propagated along the spatial dimension using different powers of the graph adjacency matrix to generate node embeddings characterized by a rich pool of spatiotemporal features. The resulting node embeddings can be efficiently pre-computed in an unsupervised manner, before being fed to a feed-forward decoder that learns to map the multi-scale spatiotemporal representations to predictions. The training procedure can then be parallelized node-wise by sampling the node embeddings without breaking any dependency, thus enabling scalability to large networks. Empirical results on relevant datasets show that our approach achieves results competitive with the state of the art, while dramatically reducing the computational burden

On the apparent horizon in fluid-gravity duality

This article develops a computational framework for determining the location of boundary-covariant apparent horizons in the geometry of conformal fluid-gravity duality in arbitrary dimensions. In particular, it is shown up to second order and conjectured to hold to all orders in the gradient expansion that there is a unique apparent horizon which is covariantly expressible in terms of fluid velocity, temperature and boundary metric. This leads to the first explicit example of an entropy current defined by an apparent horizon and opens the possibility that in the near-equilibrium regime there is preferred foliation of apparent horizons for black holes in asymptotically-AdS spacetimes

Efeito do período de suplementação com altrenogest no desempenho reprodutivo de fêmeas suínas em transição para o manejo em bandas

The synthetic progestin altrenogest (ALT) has been widely used in sow farms to concentrate artificial inseminations (AIs) during the transition of weekly productive flow for the batch farrowing system of 14 or 21 days. The objective of the present study was to investigate the effect of the duration of ALT treatment on the reproductive performance of weaned sows during transition to batch farrowing. Retrospective data was evaluated regarding the reproductive performance of primiparous and multiparous sows that were either not treated (control, n = 165) or treated with 20 mg ALT during 7 days (ALT7, n = 161) or 14 days (ALT14, n = 199) post-weaning. The interval between weaning or the end of ALT supplementation and first AI did not differ among the groups, as well as the percentage of sows inseminated up to 7 or 10 days after the end of treatment or weaning (P ≥ 0.16). There was a tendency for a lower farrowing rate (P = 0.06) in ALT7 (77.2%) when compared to ALT14 (84.5%) and control (86.3%) groups. The total number of piglets born did not differ among groups (P = 0.35). In conclusion, despite the slight delay in the estrus onset, the proportion of estrous sows was not affected, whereas the adjusted farrowing rate was reduced when ALT was administered for 7 days after weaning in multiparous sows during transition to 21 days batch farrowing system.O progestágeno sintético altrenogest (ALT) tem sido amplamente utilizado na suinocultura para agrupamento da inseminação, na transição de fluxo produtivo semanal para manejo em bandas de 14 ou 21 dias. O presente estudo investigou o efeito da duração do tratamento com ALT sobre o desempenho reprodutivo de fêmeas desmamadas na transição para o manejo em bandas. Foram coletados dados retrospectivos do desempenho reprodutivo de fêmeas primíparas e pluríparas desmamadas (n = 525) que não foram tratadas (controle, n = 165) ou tratadas diariamente com 20 mg de ALT durante 7 dias (ALT7, n = 161) ou 14 dias (ALT14, n = 199) pós-desmame. O intervalo entre o desmame ou final da suplementação de ALT e a primeira IA não diferiu entre os grupos, bem como o percentual de fêmeas inseminadas até 7 e 10 dias pós a remoção da suplementação hormonal (P ≥ 0,16). Houve uma tendência para menor taxa de parto ajustada (P = 0,06) no grupo ALT7 (77,2%), quando comparada aos grupos ALT14 (84,5%) e controle (86,3%). O número total de leitões nascidos não diferiu entre os grupos (P = 0,35). Conclui-se que, apesar do pequeno atraso no início do estro, não houve impactos na taxa de manifestação estral. Entretanto, a taxa de parto ajustada foi reduzida quando o ALT foi administrado por sete dias após o desmame na transição para o manejo em bandas de 21 dias

The excitation mechanisms of X-ray oxygen emission-lines

We present the Catalogue of High REsolution Spectra of Obscured Sources (CHRESOS) from the XMM-Newton Science Archive. It comprises soft X-ray emission-lines from C to Si and the Fe 3C and Fe 3G L-shell transitions. Here, we concentrate on the oxygen emission-lines O VII(f) and O VIII Lyα to shed light onto the physical processes with which their formation can be related to: active galactic nucleus vs. star-forming regions. We are analysing the relationships between the oxygen lines and the luminosities of: [OIII]λ5007, [OIV]25.89μm, MIR-12μm, FIR-60μm, FIR-100μm, and hard X-rays continuum bands.Fil: Reynaldi, María Victoria. Universidad Nacional de La Plata. Facultad de Ciencias Astronómicas y Geofísicas; ArgentinaFil: Guainazzi, Matteo. Agencia Espacial Europea. European Space Research And Technology Centre.; Países BajosFil: Bianchi, Stefano. Università Roma Tre Iii.; ItaliaFil: Andruchow, Ileana. Universidad Nacional de La Plata. Facultad de Ciencias Astronómicas y Geofísicas; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Astrofísica La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Astronómicas y Geofísicas. Instituto de Astrofísica La Plata; ArgentinaFil: García, Federico. Kapteyn Astronomical Institute; Países Bajos. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Instituto Argentino de Radioastronomía. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto Argentino de Radioastronomía; ArgentinaFil: Lopez, Ivan. Universidad Nacional de La Plata. Facultad de Ciencias Astronómicas y Geofísicas; ArgentinaFil: Salerno, Nicolás. Universidad Nacional de La Plata. Facultad de Ciencias Astronómicas y Geofísicas; ArgentinaSymposium S359: Galaxy Evolution and Feedback across Different EnvironmentsBento GonçalvesBrasilInternational Astronomical Unio

ESTRATÉGIAS NUTRICIONAIS PARA SUÍNOS EM FASE DE CRECHE NUTRITIONAL

A fase de creche, que sucede ao desmame, é um ponto crítico da criação de suínos,pois o desmame causa muito estresse no animal devido à separação da matriz,alteração da dieta e mistura de leitegadas, o que pode trazer prejuízos. Amenizar osefeitos negativos do desmame é um desafio que recebe cada vez mais atenção dospesquisadores e produtores. Uma das estratégias possíveis para a diminuição dosproblemas da fase da creche, como o baixo ganho de peso, é o uso de aditivosnutricionais na dieta destes animais. O aditivo nutricional AminoGut (Ajinomoto®)consiste em L-glutamina e L-ácido glutâmico, que são aminoácidos não essenciaismas que podem ser limitantes na fase de creche, pois são diretamente ligados àintegridade da mucosa intestinal e estão em concentrações altas no leite da matrizsuína. O objetivo deste estudo foi analisar efeitos da adição de AminoGut na dietasobre os índices zootécnicos. Foi realizado experimento na Master Agroindustrialunidade São Roque, utilizou-se 560 leitões de fase de creche desmamados aos 21 ±1 dias. Os animais foram distribuídos em 28 baias com pesos homogêneos eseparados de acordo com sexo, sendo 14 baias com machos, 12 baias com fêmease 2 baias mistas. Os tratamentos realizados foram de 0%, 0,4%, 0,8% e 1,2% deinclusão de AminoGut na dieta destes animais. Foram realizadas pesagens semanaisdas baias e pesagem individual dos leitões em dois momentos da fase (42 e 63 diasde idade) e foi medido o consumo semanal por baia. Os índices zootécnicosanalisados foram ganho de peso médio (GPM), ganho médio diário (GMD) econversão alimentar (CA). O delineamento experimental utilizado foi blocosdistribuídos ao acaso, os dados foram submetidos à análise de variância a 5% deprobabilidade. Não foram observados resultados estatisticamente significantes(p>0,05) para nenhum tratamento de AminoGut. A única diferença estatisticamentesignificante foi de CA entre os sexos (p=0,004), onde as baias que possuíamsomente machos obtiveram melhor valor (CA=1,716). Assim sendo, não se podeconcluir qual nível de inclusão de AminoGut é ideal para otimizar o desempenho deleitões em fase de creche