Preliminary interpretation of Titan plasma interaction as observed by the Cassini Plasma Spectrometer: Comparisons with Voyager 1

The Cassini Plasma Spectrometer (CAPS) instrument observed the plasma environment at Titan during the Cassini orbiter's TA encounter on October 26, 2004. Titan was in Saturn's magnetosphere during the Voyager 1 flyby and also during the TA encounter. CAPS measurements from this encounter are compared with measurements made by the Voyager 1 Plasma Science Instrument (PLS). The comparisons focus on the composition and nature of ambient and pickup ions. They lead to: A) the major ion components of Saturn's magnetosphere in the vicinity of Titan are H+, H-2(+) and O+/CH4+ ions; B) finite gyroradius effects are apparent in ambient O+ ions as the result of their absorption by Titan's extended atmosphere; C) the principal pickup ions are composed of H+, H-2(+), N+/CH2+, CH4+, and N-2(+); D) the pickup ions are in narrow energy ranges; and E) there is clear evidence of the slowing down of background ions due to pickup ion mass loading

Insights into the Mechanism of Bovine CD38/NAD+Glycohydrolase from the X-Ray Structures of Its Michaelis Complex and Covalently-Trapped Intermediates

Bovine CD38/NAD+glycohydrolase (bCD38) catalyses the hydrolysis of NAD+ into nicotinamide and ADP-ribose and the formation of cyclic ADP-ribose (cADPR). We solved the crystal structures of the mono N-glycosylated forms of the ecto-domain of bCD38 or the catalytic residue mutant Glu218Gln in their apo state or bound to aFNAD or rFNAD, two 2′-fluorinated analogs of NAD+. Both compounds behave as mechanism-based inhibitors, allowing the trapping of a reaction intermediate covalently linked to Glu218. Compared to the non-covalent (Michaelis) complex, the ligands adopt a more folded conformation in the covalent complexes. Altogether these crystallographic snapshots along the reaction pathway reveal the drastic conformational rearrangements undergone by the ligand during catalysis with the repositioning of its adenine ring from a solvent-exposed position stacked against Trp168 to a more buried position stacked against Trp181. This adenine flipping between conserved tryptophans is a prerequisite for the proper positioning of the N1 of the adenine ring to perform the nucleophilic attack on the C1′ of the ribofuranoside ring ultimately yielding cADPR. In all structures, however, the adenine ring adopts the most thermodynamically favorable anti conformation, explaining why cyclization, which requires a syn conformation, remains a rare alternate event in the reactions catalyzed by bCD38 (cADPR represents only 1% of the reaction products). In the Michaelis complex, the substrate is bound in a constrained conformation; the enzyme uses this ground-state destabilization, in addition to a hydrophobic environment and desolvation of the nicotinamide-ribosyl bond, to destabilize the scissile bond leading to the formation of a ribooxocarbenium ion intermediate. The Glu218 side chain stabilizes this reaction intermediate and plays another important role during catalysis by polarizing the 2′-OH of the substrate NAD+. Based on our structural analysis and data on active site mutants, we propose a detailed analysis of the catalytic mechanism

Time variability and heterogeneity in the coma of 67P/Churyumov-Gerasimenko

Comets contain the best-preserved material from the beginning of our planetary system. Their nuclei and comae composition reveal clues about physical and chemical conditions during the early solar system when comets formed. ROSINA (Rosetta Orbiter Spectrometer for Ion and Neutral Analysis) onboard the Rosetta spacecraft has measured the coma composition of comet 67P/Churyumov-Gerasimenko with well-sampled time resolution per rotation. Measurements were made over many comet rotation periods and a wide range of latitudes. These measurements show large fluctuations in composition in a heterogeneous coma that has diurnal and possibly seasonal variations in the major outgassing species: water, carbon monoxide, and carbon dioxide. These results indicate a complex coma-nucleus relationship where seasonal variations may be driven by temperature differences just below the comet surface

Measurements of atmospheric electricity aloft

Measurements of the electrical characteristics of the atmosphere above the surface have been made for over 200 years, from a variety of different platforms, including kites, balloons, rockets and aircraft. From these measurements, a great deal of information about the electrical characteristics of the atmosphere has been gained, assisting our understanding of the global atmospheric electric circuit, thunderstorm electrification and lightning generation mechanisms, discovery of transient luminous events above thunderstorms, and many other electrical phenomena. This paper surveys the history of atmospheric electrical measurements aloft, from the earliest manned balloon ascents to current day observations with free balloons and aircraft. Measurements of atmospheric electrical parameters in a range of meteorological conditions are described, including clear air conditions, polluted conditions, non-thunderstorm clouds, and thunderstorm clouds, spanning a range of atmospheric conditions, from fair weather, to the most electrically active

The interstellar hydrogen shadow: Observations of interstellar pickup ions beyond Jupiter

This study analyzes the first direct, mass-resolved observations of heliospheric pickup ions beyond the orbit of Jupiter. The Cassini Plasma Spectrometer observes H+, He+, He++, and O+ pickup ions of interstellar origin between 6.4 and 8.2 AU. Cassini's trajectory carries it through the downstream direction where we observe enhancements in the pickup He consistent with gravitational focusing by the Sun. We also show the first in situ observations of an "interstellar hydrogen shadow'' where pickup H is depleted in the region behind the Sun relative to the local interstellar flow. Most H atoms cannot penetrate into this downstream shadow region both because the outward force due to radiation pressure exceeds gravitational attraction at this time and because H atoms trying to enter the shadow must pass close by the Sun where they have a high probability of being ionized and swept out with the solar wind

Lightning-induced plasma turbulence and ion heating in equatorial ionospheric depletions

International audienceA wide range of plasma instabilities exist in various regions of the terrestrial ionosphere, leading to the development of plasma turbulence, in particular close to the lower-hybrid frequency—the frequency of a longitudinal oscillation of ions and electrons in a magnetized plasma that must be near perpendicular to the magnetic field. Most observations have been carried out in the auroral regions, where intense lower-hybrid emissions are frequently observed, possibly producing solitary structures1 and ion heating2,3,4. Lower-hybrid turbulence with a smaller intensity has also been observed at mid- and low latitudes above thunderstorms5,6 and was shown to be triggered by the electromagnetic whistler wave generated by the lightning current. Here we present observations of equatorial plasma waves that demonstrate the existence of lower-hybrid solitary structures and the simultaneous occurrence of ion heating in deep, large-scale equatorial plasma depletions that form at night during disturbed geomagnetic conditions. These phenomena follow the development of lower-hybrid turbulence triggered by lightning-induced whistlers, revealing a new coupling process between the troposphere and the ionosphere. Since the energy source of the equatorial solitary structures is different from that involved in the auroral processes, our findings support the idea that the formation of lower-hybrid solitary structures may be a universal mechanism operating in inhomogeneous, magnetized plasma and possibly leading to ion heating and acceleration

Applications of electrified dust and dust devil electrodynamics to Martian atmospheric electricity

Atmospheric transport and suspension of dust frequently brings electrification, which may be substantial. Electric fields of 10 kV m−1 to 100 kV m−1 have been observed at the surface beneath suspended dust in the terrestrial atmosphere, and some electrification has been observed to persist in dust at levels to 5 km, as well as in volcanic plumes. The interaction between individual particles which causes the electrification is incompletely understood, and multiple processes are thought to be acting. A variation in particle charge with particle size, and the effect of gravitational separation explains to, some extent, the charge structures observed in terrestrial dust storms. More extensive flow-based modelling demonstrates that bulk electric fields in excess of 10 kV m−1 can be obtained rapidly (in less than 10 s) from rotating dust systems (dust devils) and that terrestrial breakdown fields can be obtained. Modelled profiles of electrical conductivity in the Martian atmosphere suggest the possibility of dust electrification, and dust devils have been suggested as a mechanism of charge separation able to maintain current flow between one region of the atmosphere and another, through a global circuit. Fundamental new understanding of Martian atmospheric electricity will result from the ExoMars mission, which carries the DREAMS (Dust characterization, Risk Assessment, and Environment Analyser on the Martian Surface)—MicroARES (Atmospheric Radiation and Electricity Sensor) instrumentation to Mars in 2016 for the first in situ electrical measurements

Applications of radar systems in planetary sciences: an overview

This chapter aims at reviewing remarkable results and sophistication of radar systems achieved over the history in several planetary explorations by dividing the treatment according to different planets and celestial bodies investigated. Both established and novel radar-based techniques for space exploration are described within an overall top-down approach being consolidated over years. As a result of the review, future perspectives of the research are highlighted and some benefits and limitations of different techniques are described. In line with this, increasingly reliable surveys are expected in the next few years, which can provide important information in the understanding of past and present natural phenomena as well as to sustain future human explorers and look for clues of habitable zones