Solving surface structures from normal incidence X-ray standing wave data

A program is provided to determine structural parameters of atoms in or adsorbed on surfaces by refinement of atomistic models towards experimentally determined data generated by the normal incidence X-ray standing wave (NIXSW) technique. The method employs a combination of Differential Evolution Genetic Algorithms and Steepest Descent Line Minimisations to provide a fast, reliable and user friendly tool for experimentalists to interpret complex multidimensional NIXSW data sets

Structure of adsorbed organometallic rhodium: model single atom catalysts

We have determined the structure of a complex rhodium carbonyl chloride [Rh(CO)(2)Cl] molecule adsorbed on the TiO2 (110) surface by the normal incidence x-ray standing wave technique. The data show that the technique is applicable to reducible oxide systems and that the dominant adsorbed species is undissociated with Rh binding atop bridging oxygen and to the Cl found close to the fivefold coordinated Ti ions in the surface. A minority geminal dicarboryl species, where Rh-Cl bond scission has occurred, is found bridging the bridging oxygen ions forming a high-symmetry site

Analysis of fluorescently labeled substance P analogs: binding, imaging and receptor activation

BACKGROUND: Substance P (SP) is a peptide neurotransmitter found in central and peripheral nerves. SP is involved in the control of smooth muscle, inflammation and nociception. The amino acid sequence of SP is Arg-Pro-Lys-Pro-Gln-Gln-Phe-Phe-Gly-Leu-Met-NH(2). Five different forms of fluorescently labeled SP have recently been synthesized, in which Alexa 488, BODIPY Fl, fluorescein, Oregon Green 488 or tetramethylrhodamine has been covalently linked to SP at Lys(3). Here, these novel analogs are characterized as to their ligand binding, receptor activation and fluorescence labeling properties. RESULTS: Competition binding studies, using radiolabeled [(125)I] SP, revealed that all of the labeled forms of SP, except for Alexa 488-SP, effectively competed with radiolabeled SP for binding at the rat SP receptor. With the exception of Alexa 488-SP, all of the SP analogs produced Ca(++) elevations and fluorescence labeling of the SP receptor expressed in Chinese hamster ovary cells. In SP-responsive neurons, BODIPY Fl-SP and Oregon Green 488-SP were as effective as unlabeled SP in producing a reduction of the M-type K(+) current. Fluorescein-SP produced variable results, while tetramethylrhodamine-SP was less potent and Alexa 488-SP was less effective on intact neurons. CONCLUSIONS: The above results show that fluorescent labeling of SP altered the biological activity and the binding properties of the parent peptide. Oregon Green 488 and BODIPY FL-SP are the most useful fluorophores for labeling SP without affecting its biological activity. Given these results, these probes can now be utilized in further investigations of the mechanisms of SPR function, including receptor localization, internalization and recycling

Quantum cryptography with squeezed states

A quantum key distribution scheme based on the use of displaced squeezed vacuum states is presented. The states are squeezed in one of two field quadrature components, and the value of the squeezed component is used to encode a character from an alphabet. The uncertainty relation between quadrature components prevents an eavesdropper from determining both with enough precision to determine the character being sent. Losses degrade the performance of this scheme, but it is possible to use phase-sensitive amplifiers to boost the signal and partially compensate for their effect.Comment: 15 pages, no figure

Quantum secret sharing

Secret sharing is a procedure for splitting a message into several parts so that no subset of parts is sufficient to read the message, but the entire set is. We show how this procedure can be implemented using GHZ states. In the quantum case the presence of an eavesdropper will introduce errors so that his presence can be detected. We also show how GHZ states can be used to split quantum information into two parts so that both parts are necessary to reconstruct the original qubit.Comment: 6 pages, revtex, revised version, to appear in Phys. Rev.

Evolution of entanglement within classical light states

We investigate the evolution of quantum correlations over the lifetime of a multi-photon state. Measurements reveal time-dependent oscillations of the entanglement fidelity for photon pairs created by a single semiconductor quantum dot. The oscillations are attributed to the phase acquired in the intermediate, non-degenerate, exciton-photon state and are consistent with simulations. We conclude that emission of photon pairs by a typical quantum dot with finite polarisation splitting is in fact entangled in a time-evolving state, and not classically correlated as previously regarded

Perfect state distinguishability and computational speedups with postselected closed timelike curves

Bennett and Schumacher's postselected quantum teleportation is a model of closed timelike curves (CTCs) that leads to results physically different from Deutsch's model. We show that even a single qubit passing through a postselected CTC (P-CTC) is sufficient to do any postselected quantum measurement, and we discuss an important difference between "Deutschian" CTCs (D-CTCs) and P-CTCs in which the future existence of a P-CTC might affect the present outcome of an experiment. Then, based on a suggestion of Bennett and Smith, we explicitly show how a party assisted by P-CTCs can distinguish a set of linearly independent quantum states, and we prove that it is not possible for such a party to distinguish a set of linearly dependent states. The power of P-CTCs is thus weaker than that of D-CTCs because the Holevo bound still applies to circuits using them regardless of their ability to conspire in violating the uncertainty principle. We then discuss how different notions of a quantum mixture that are indistinguishable in linear quantum mechanics lead to dramatically differing conclusions in a nonlinear quantum mechanics involving P-CTCs. Finally, we give explicit circuit constructions that can efficiently factor integers, efficiently solve any decision problem in the intersection of NP and coNP, and probabilistically solve any decision problem in NP. These circuits accomplish these tasks with just one qubit traveling back in time, and they exploit the ability of postselected closed timelike curves to create grandfather paradoxes for invalid answers.Comment: 15 pages, 4 figures; Foundations of Physics (2011

Gamma ray measurements of the 1991 November 15 solar flare

The 1991 November 15 X1.5 flare was a well observed solar event. Comprehensive data from ground-based observatories and spacecraft provide the basis for a contextual interpretation of gamma-ray spectra from the Compton Gamma Ray Observatory (CGRO). In particular, spectral, spatial, and temporal data at several energies are necessary to understand the particle dynamics and the acceleration mechanism(s) within this flare. X-ray images, radio, Ca XIX data and magnetograms provide morphological information on the acceleration region [4,5], while gamma-ray spectral data provide information on the parent ion spectrum. Furthermore, time profiles in hard X-rays and gamma-rays provide valuable information on temporal characteristics of the energetic particles. We report the results of our analysis of the evolution of this flare as a function of energy (∼25 keV–2.5 MeV) and time. These results, together with other high energy data (e.g. from experiments on Yohkoh, Ulysses, and PVO) may assist in identifying and understanding the acceleration mechanism(s) taking place in this event

Energetic proton spectra in the 11 June 1991 solar flare

The June 11, 1991 gamma-ray flare seen by the Compton Gamma-ray Observatory (CGRO) displays several features that make it a dynamic and rich event. It is a member of a class of long duration gamma-ray events with both 2.223 MeV and greater than 8 MeV emission for hours after the impulsive phase. It also contains an inter-phase between the impulsive and extended phases that presents a challenge to the standard gamma-ray line (GRL) flare picture. This phase has strong 2.223 MeV emission and relatively weak 4.44 MeV emission indicative of a very hard parent proton spectrum. However, this would indicate emission greater than 8 MeV, which is absent from this period. We present the application of new spectroscopy techniques to this phase of the flare in order to present a reasonable explanation for this seemly inconsistent picture