12,773 research outputs found
Spectroscopic Studies of Brooker\u27s Merocyanine in Zeolite L
Zeolites are porous, crystalline substances that have very unique atomic organizations which allow for the formation of complex channels within the crystals. Each type of zeolite has a distinct shape and structure. To better understand the properties of zeolite channels, a dye molecule known as Brooker’s merocyanine was inserted into Zeolite L. Maximum dye loading into the zeolite channels was achieved by altering different experimental variables, such as heat, solution concentration, stirring, cation exchange, and light exposure. X-ray diffraction was used to verify the synthesis of zeolites, the cation exchange process, and dye loading. UV-Vis spectroscopy was used to measure the amount of dye adsorbed by the zeolite. By using the UV-Vis absorbance values and Beer’s Law, the concentration of dye in the zeolites was determined. The results showed that an increase of heat and stirring correlated to an increase of adsorption of dye by the zeolite. Due to the light sensitivity of Brooker’s merocyanine, it was found that limiting the amount of light exposure of the dye solutions also resulted in higher dye adsorption by the zeolites. An increase of the concentration of the dye solution increased the rate of adsorption in the channels. However, exchanging the potassium ions found within the synthesized Zeolite L channels with smaller hydrogen ions did not have an affect on the adsorption of dye in the channels. Characterizing how to achieve a maximum of dye adsorption in the zeolites allows for a better understanding of how dye molecules interact within the zeolite channels
Facilitating goal-oriented behaviour in the Stroop task: when executive control is influenced by automatic processing.
A portion of Stroop interference is thought to arise from a failure to maintain goal-oriented behaviour (or goal neglect). The aim of the present study was to investigate whether goal- relevant primes could enhance goal maintenance and reduce the Stroop interference effect. Here it is shown that primes related to the goal of responding quickly in the Stroop task (e.g. fast, quick, hurry) substantially reduced Stroop interference by reducing reaction times to incongruent trials but increasing reaction times to congruent and neutral trials. No effects of the primes were observed on errors. The effects on incongruent, congruent and neutral trials are explained in terms of the influence of the primes on goal maintenance. The results show that goal priming can facilitate goal-oriented behaviour and indicate that automatic processing can modulate executive control
Reconciling optical and radio observations of the binary millisecond pulsar PSR J1640+2224
Previous optical and radio observations of the binary millisecond pulsar PSR
J1640+2224 have come to inconsistent conclusions about the identity of its
companion, with some observations suggesting the companion is a low-mass
helium-core (He-core) white dwarf (WD), while others indicate it is most likely
a high-mass carbon-oxygen (CO) WD. Binary evolution models predict PSR
J1640+2224 most likely formed in a low-mass X-ray binary (LMXB) based on the
pulsar's short spin period and long-period, low-eccentricity orbit, in which
case its companion should be a He-core WD with mass about , depending on metallicity. If it is instead a CO WD, that would
suggest the system has an unusual formation history. In this paper we present
the first astrometric parallax measurement for this system from observations
made with the Very Long Baseline Array (VLBA), from which we determine the
distance to be . We use this distance and a
reanalysis of archival optical observations originally taken in 1995 with the
Wide Field Planetary Camera 2 (WFPC2) on the Hubble Space Telescope (HST) in
order to measure the WD's mass. We also incorporate improvements in
calibration, extinction model, and WD cooling models. We find that the existing
observations are not sufficient to tightly constrain the companion mass, but we
conclude the WD mass is with confidence. The limiting
factor in our analysis is the low signal-to-noise ratio of the original HST
observations.Comment: 6 pages, 5 figure
Running coupling and mass anomalous dimension of SU(3) gauge theory with two flavors of symmetric-representation fermions
We have measured the running coupling constant of SU(3) gauge theory coupled
to Nf=2 flavors of symmetric representation fermions, using the Schrodinger
functional scheme. Our lattice action is defined with hypercubic smeared links
which, along with the larger lattice sizes, bring us closer to the continuum
limit than in our previous study. We observe that the coupling runs more slowly
than predicted by asymptotic freedom, but we are unable to observe fixed point
behavior before encountering a first order transition to a strong coupling
phase. This indicates that the infrared fixed point found with the thin-link
action is a lattice artifact. The slow running of the gauge coupling permits an
accurate determination of the mass anomalous dimension for this theory, which
we observe to be small, gamma_m < 0.6, over the range of couplings we can
reach. We also study the bulk and finite-temperature phase transitions in the
strong coupling region.Comment: 17 pages, 16 figures. Substantial modifications to explain why the
fat-link result for the beta function supersedes our thin-link result; also
updated the phase diagram to reflect additional numerical work. Added
references. Final versio
SU(4) lattice gauge theory with decuplet fermions: Schr\"odinger functional analysis
We complete a program of study of SU(N) gauge theories coupled to two flavors
of fermions in the two-index symmetric representation by performing numerical
simulations in SU(4). The beta function, defined and calculated via the
Schr\"odinger functional, runs more slowly than the two-loop perturbative
result. The mass anomalous dimension levels off in strong coupling at a value
of about 0.45, rendering this theory unsuitable for walking technicolor. A
large-N comparison of this data with results from SU(2) and SU(3) reveals
striking regularities.Comment: 15 pages, 15 figure
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