Spectroscopic Studies of Brooker\u27s Merocyanine in Zeolite L

Zeolites are porous, crystalline substances that have very unique atomic organizations which allow for the formation of complex channels within the crystals. Each type of zeolite has a distinct shape and structure. To better understand the properties of zeolite channels, a dye molecule known as Brooker’s merocyanine was inserted into Zeolite L. Maximum dye loading into the zeolite channels was achieved by altering different experimental variables, such as heat, solution concentration, stirring, cation exchange, and light exposure. X-ray diffraction was used to verify the synthesis of zeolites, the cation exchange process, and dye loading. UV-Vis spectroscopy was used to measure the amount of dye adsorbed by the zeolite. By using the UV-Vis absorbance values and Beer’s Law, the concentration of dye in the zeolites was determined. The results showed that an increase of heat and stirring correlated to an increase of adsorption of dye by the zeolite. Due to the light sensitivity of Brooker’s merocyanine, it was found that limiting the amount of light exposure of the dye solutions also resulted in higher dye adsorption by the zeolites. An increase of the concentration of the dye solution increased the rate of adsorption in the channels. However, exchanging the potassium ions found within the synthesized Zeolite L channels with smaller hydrogen ions did not have an affect on the adsorption of dye in the channels. Characterizing how to achieve a maximum of dye adsorption in the zeolites allows for a better understanding of how dye molecules interact within the zeolite channels

Facilitating goal-oriented behaviour in the Stroop task: when executive control is influenced by automatic processing.

A portion of Stroop interference is thought to arise from a failure to maintain goal-oriented behaviour (or goal neglect). The aim of the present study was to investigate whether goal- relevant primes could enhance goal maintenance and reduce the Stroop interference effect. Here it is shown that primes related to the goal of responding quickly in the Stroop task (e.g. fast, quick, hurry) substantially reduced Stroop interference by reducing reaction times to incongruent trials but increasing reaction times to congruent and neutral trials. No effects of the primes were observed on errors. The effects on incongruent, congruent and neutral trials are explained in terms of the influence of the primes on goal maintenance. The results show that goal priming can facilitate goal-oriented behaviour and indicate that automatic processing can modulate executive control

Reconciling optical and radio observations of the binary millisecond pulsar PSR J1640+2224

Previous optical and radio observations of the binary millisecond pulsar PSR J1640+2224 have come to inconsistent conclusions about the identity of its companion, with some observations suggesting the companion is a low-mass helium-core (He-core) white dwarf (WD), while others indicate it is most likely a high-mass carbon-oxygen (CO) WD. Binary evolution models predict PSR J1640+2224 most likely formed in a low-mass X-ray binary (LMXB) based on the pulsar's short spin period and long-period, low-eccentricity orbit, in which case its companion should be a He-core WD with mass about $0.35 - 0.39 \, M_\odot$, depending on metallicity. If it is instead a CO WD, that would suggest the system has an unusual formation history. In this paper we present the first astrometric parallax measurement for this system from observations made with the Very Long Baseline Array (VLBA), from which we determine the distance to be $1520^{+170}_{-150}\,\mathrm{pc}$. We use this distance and a reanalysis of archival optical observations originally taken in 1995 with the Wide Field Planetary Camera 2 (WFPC2) on the Hubble Space Telescope (HST) in order to measure the WD's mass. We also incorporate improvements in calibration, extinction model, and WD cooling models. We find that the existing observations are not sufficient to tightly constrain the companion mass, but we conclude the WD mass is $>0.4\,M_\odot$ with $>90\%$ confidence. The limiting factor in our analysis is the low signal-to-noise ratio of the original HST observations.Comment: 6 pages, 5 figure

Running coupling and mass anomalous dimension of SU(3) gauge theory with two flavors of symmetric-representation fermions

We have measured the running coupling constant of SU(3) gauge theory coupled to Nf=2 flavors of symmetric representation fermions, using the Schrodinger functional scheme. Our lattice action is defined with hypercubic smeared links which, along with the larger lattice sizes, bring us closer to the continuum limit than in our previous study. We observe that the coupling runs more slowly than predicted by asymptotic freedom, but we are unable to observe fixed point behavior before encountering a first order transition to a strong coupling phase. This indicates that the infrared fixed point found with the thin-link action is a lattice artifact. The slow running of the gauge coupling permits an accurate determination of the mass anomalous dimension for this theory, which we observe to be small, gamma_m < 0.6, over the range of couplings we can reach. We also study the bulk and finite-temperature phase transitions in the strong coupling region.Comment: 17 pages, 16 figures. Substantial modifications to explain why the fat-link result for the beta function supersedes our thin-link result; also updated the phase diagram to reflect additional numerical work. Added references. Final versio

SU(4) lattice gauge theory with decuplet fermions: Schr\"odinger functional analysis

We complete a program of study of SU(N) gauge theories coupled to two flavors of fermions in the two-index symmetric representation by performing numerical simulations in SU(4). The beta function, defined and calculated via the Schr\"odinger functional, runs more slowly than the two-loop perturbative result. The mass anomalous dimension levels off in strong coupling at a value of about 0.45, rendering this theory unsuitable for walking technicolor. A large-N comparison of this data with results from SU(2) and SU(3) reveals striking regularities.Comment: 15 pages, 15 figure

A mouse polyomavirus-encoded microRNA targets the cellular apoptosis pathway through Smad2 inhibition

AbstractSome viruses and most eukaryotic cells have microRNAs that regulate the expression of many genes. Although many viral miRNAs have been identified, only a few have been included in in vivo functional studies. Here we show that a Py-encoded miRNA downregulates the expression of the pro-apoptotic factor Smad2, resulting in the suppression of the apoptosis pathway. To study the Py miRNA in an in vivo context, a miRNA-deficient mutant virus was created on the background of the LID virus strain which establishes a rapid and lethal infection in newborn mice. Apoptosis analysis on kidney tissues indicates that the pro-apoptotic pathway is targeted in the infected host as well. Suppression of apoptosis through targeting of Smad2 by the Py miRNA is expected to synergize with anti-apoptotic effects previously attributed to the polyoma tumor antigens in support of virus replication in the natural host