Structural controls on basin- and crustal-scale fluid flow and resulting mineral reactions

This preface summarizes the main contents of the special issue Structural Controls on Basin- and Crustal-Scale Fluid Flow and Resulting Mineral Reactions, organized by topic. The description of contributions starts with those addressing crustal-scale processes, followed by studies of relatively shallower fluid flow mechanisms and their consequences. The final subsection summarizes contributions on structural controls on mineral reactions, as well as those evaluating how they impact geothermal reservoir properties

The contact uranium prospect, Kiggavik project, Nunavut (CVanada): Tectonic history, structural constrains and timing of mineralization

Uranium mineralization in the Kiggavik area, on the eastern border of the Thelon basin (Nunavut, Canada), hosts significant uranium resources within the basement and its understanding is critical to comprehending the genesis of unconformity-related deposits' structural controls and therefore exploration of these types of deposits in this prospective district. This article deciphers the complex multiphase fracture network associated with uranium mineralization of the most recently discovered, basement-hosted prospect in the Kiggavik area, named Contact. The Contact prospect is located along the Andrew Lake Fault (ALF), a major NE-SW fault corridor in the area. This study combines field work, drillcore logging, sampling, and macro- to micro- petro-structural analyses. Key results from this study highlight that the NE-trending ALF, along with the ENE-trending Thelon (TF) and Judge Sissons (JSF) faults, formed early during intracratonic rifting and deposition of the Baker Lake and Wharton groups (ca. 1850-1750 Ma) in response to the Thelon and Trans-Hudsonian orogeny. The ALF was affected by a strong silicification-brecciation event that likely developed at ca. 1750 Ma, and partitioned later deformation and fluid circulation. In the Contact prospect, the ALF was reactivated multiple times and mineralized in three stages with distinctive secondary fracture patterns, alteration, and mineralization types. Ten fracture stages have been identified at the Contact prospect, f1-f10. The first stage of mineralization, coeval with f5, is related to fluids of unconstrained origin that circulated through E-W faults in the area that locally re-activated quartz veins of the brecciation event at the intersection with the ALF. Mineralization at this stage is polymetallic and associated with weak clay alteration. The second stage of uranium mineralization occurred coeval with transtensional reactivation of the NE-SW trending ALF (f6c) and in relation to circulation of oxidizing basinal brines within the fault zone. Mineralization at this stage is monometallic and associated with illite and sudoite alteration. Later reactivation of the inherited fracture network (f8) led to strong illitization and bleaching of the host rock, with local reworking of the ore body. Finally, reactivation of the fracture network during f9 and 10 lead to circulation of meteoric fluids that remobilized mineralization in a third stage of uranium re-concentration along redox fronts, with strong illitization and bleaching of the host rock. Unlike the classic unconformity-related uranium deposits in the Athabasca Basin where clay alteration halos occur around the ore bodies related to mineralizing processes, in the Contact prospect the strongest clay alteration event (f8) postdates both main stages of mineralization. Along with uranium remobilization, the basement-hosted Contact prospect is likely a relict of what was once a larger deposit

Fluid Dynamics in a Thrust Fault Inferred from Petrology and Geochemistry of Calcite Veins: An Example from the Southern Pyrenees

Petrographic and geochemical analyses (δ18O, δ13C, 87Sr/86Sr, clumped isotopes, and elemental composition) coupled with field structural data of synkinematic calcite veins, fault rocks, and host rocks are used to reconstruct the episodic evolution of an outstanding exposed thrust zone in the Southern Pyrenees and to evaluate the fault behavior as a conduit or barrier to fluid migration. The selected thrust displaces the steeply dipping southern limb of the Sant Corneli-Bóixols anticline, juxtaposing a Cenomanian-Turonian carbonate unit against a Coniacian carbonate sequence. Successive deformation events are recorded by distinct fracture systems and related calcite veins, highlighting (i) an episodic evolution of the thrust zone, resulting from an upward migration of the fault tip (process zone development) before growth of the fault (thrust slip plane propagation), and (ii) compartmentalization of the thrust fault zone, leading to different structural and fluid flow histories in the footwall and hanging wall. Fractures within the footwall comprise three systematically oriented fracture sets (F1, F2, and F3), each sealed by a separate generation calcite cement, and a randomly oriented fracture system (mosaic to chaotic breccia), cemented by the same cements as fracture sets F1 and F2. The formation of fractures F1 and F2 and the mosaic to chaotic breccia is consistent with dilatant fracturing within the process zone (around the fault tip) during initial fault growth, whereas the formation of the latest fracture system points to hybrid shear-dilational failure during propagation of the fault. The continuous formation of different fracture systems and related calcite cementation phases evidences that the structural permeability in the footwall was transient and that the fluid pathways and regime evolved due to successive events of fracture opening and calcite cementation. Clumped isotopes evidence a progressive increase in precipitation temperatures from around 50°C to 117°C approximately, interpreted as burial increase linked to thrust sheet emplacement. During this period, the source of fluid changed from meteoric fluids to evolved meteoric fluids due to the water-rock interaction at increasing depths and temperatures. Contrary to the footwall, within the hanging wall, only randomly oriented fractures are recognized and the resulting crackle proto-breccia is sealed by a later and different calcite cement, which is also observed in the main fault plane and in the fault core. This cement precipitated from formation fluids, at around 95°C, that circulated along the fault core and in the hanging wall block, again supporting the interpretation of compartmentalization of the thrust structure. The integration of these data reveals that the studied thrust fault acted as a transverse barrier, dividing the thrust zone into two separate fluid compartments, and a longitudinal drain for migration of fluids. This study also highlights the similarity in deformation processes and mechanisms linked to the evolution of fault zones in compressional and extensional regimes involving carbonate rocks

Deciphering the complex evolution of a polyphase fault/fracture network and its control on fluid circulation and ore deposition through macro- to micro-scale observations

In the Kiggavik area (Nunavut, Canada), uranium mineralization is hosted in outcropping metamorphosed Archean to Paleoproterozoic basement rocks that were likely covered by the nearby Paleoproterozoic sandstones of the Thelon basin infill (1667-1540 Ma). The uranium mineralization is controlled by faults and fractures which developed during a long-lasting polyphase brittle tectonic history spanning from ca. 1850 Ma (after the Thelon and Trans-Hudsonian orogenies) to ca. 1270 Ma (before emplacement of MacKenzie dikes) for the main fracturing events

Fault Zone Evolution and Development of a Structural and Hydrological Barrier: The Quartz Breccia in the Kiggavik Area (Nunavut, Canada) and Its Control on Uranium Mineralization

In the Kiggavik area (Nunavut, Canada), major fault zones along, or close to, where uranium deposits are found are often associated with occurrence of thick quartz breccia (QB) bodies. These bodies formed in an early stage (~1750 Ma) of the long-lasting tectonic history of the Archean basement, and of the Proterozoic Thelon basin. The main characteristics of the QB are addressed in this study; through field work, macro and microscopic observations, cathodoluminescence microscopy, trace elements, and oxygen isotopic signatures of the quartz forming the QB. Faults formed earlier during syn- to post-orogenic rifting (1850-1750 Ma) were subsequently reactivated, and underwent cycles of cataclasis, pervasive silicification, hydraulic brecciation, and quartz recrystallization. This was synchronous with the circulation of meteoric fluids mixing with Si-rich magmatic-derived fluids at depth, and were coeval with the emplacement of the Kivalliq igneous suite at 1750 Ma. These processes led to the emplacement of up to 30 m thick QB, which behaved as a mechanically strong, transverse hydraulic barrier that localized later fracturing, and compartmentalized/channelized vertical flow of uranium-bearing fluids after the deposition of the Thelon Basin (post 1750 Ma). The development and locations of QB control the location of uranium mineralization in the Kiggavik area

Quantifying deformation processes in the SE Pyrenees using U-Pb dating of fracture-filling calcites

It is difficult to quantify the timing of the deformation processes in brittle fold-thrust belts because minerals suitable for dating and well-preserved growth strata sediments are scarce or absent. Here, we quantify the duration of thrust sheet emplacement and shortening rates in the SE Pyrenean thrust sequence using U-Pb dating of fracture-filling calcites. The obtained U-Pb dates reveal a minimum duration for the emplacement of each thrust unit (18.7 Ma for the Bóixols-Upper Pedraforca, 11.6 Ma for the Lower Pedraforca and 14.3 Ma for the Cadí thrust sheets) and show that piggy-back thrusting was accompanied by post-emplacement deformation of the upper thrust sheets above the lower sheets during their south-directed tectonic transport. We calculated shortening rates of 0.6, 3.1 and 1.1 mm a−1 from the older to younger emplaced thrust sheets. Our results also reveal the formation of local normal faults during the late Oligocene as a result of the late stages of compression and exhumation in the SE Pyrenees. We observed that temperatures >110 °C could be a limiting factor when applying the U-Pb dating method

Multiple fluid flow events from salt-related rifting to basin inversion (Upper Pedraforca thrust sheet, SE Pyrenees)

Fault-related dolomitisation is responsible for the development of numerous hydrocarbon reservoirs hosted in diagenetically-altered carbonates and is therefore critical to hydrocarbon exploration, subsurface storage (i.e. CO2), the formation of associated mineralisation (i.e. MVT-deposits) and for understanding the key controls on subsurface fluid flow. Multiple dolomitised outcrop analogues have been characterised in recent years, but uncertainty still remains as to the controls on dolomitisation in terms of dolostone geobody size and geometries, their distribution and how they impact reservoir quality. Late Tithonian shallow-marine carbonates at Serra Esparreguera in the Maestrat Basin (E. Spain) were partially dolomitised on the seismic scale, resulting in a spectrum of geobodies with varying degrees of spatial connectivity. Dolostone predominantly replaces Polpís Fm wackestones and packstones, and bioclastic grainstones of the Bovalar Fm. Dolostone geobodies transition through vertical stratigraphy from being massive and spatially extensive to localised stratabound bodies as textural heterogeneity increases. Irregular dolostone geometries occur in the Polpís Fm, which is texturally homogenous relative to the overlying Bovalar Fm, cross-cutting bedding in areas with high abundance of faults. Faults occur adjacent to dolostone and constrain its lateral extent across the outcrop. Dolomitisation fronts are typically sharp with morphologies affected by small-scale faults and bedding-parallel stylolites. Dolomitisation occurred under burial conditions and dolostones were later overprinted by phases of calcite and saddle dolomite cementation. The spatial distribution of dolostone is strongly influenced by the depositional heterogeneity and faults, while smaller structures (i.e. metre-scale fractures and stylolites) and bedding surfaces controlled the dolomitisation front geometry. Dolostone geobodies at Serra Esparreguera provide new insights into the structural, depositional and diagenetic controls on dolomitisation at a seismic scale, which can be used as a predictive guide to improve the understanding of carbonate reservoirs with complex paragenetic histories

From Early Contraction to Post-Folding Fluid Evolution in the Frontal Part of the Bóixols Thrust Sheet (Southern Pyrenees) as Revealed by the Texture and Geochemistry of Calcite Cements

Structural, petrological and geochemical (δ13C, δ18O, clumped isotopes, 87Sr/86Sr and ICP-MS) analyses of fracture-related calcite cements and host rocks are used to establish a fluid-flow evolution model for the frontal part of the Bóixols thrust sheet (Southern Pyrenees). Five fracture events associated with the growth of the thrust-related Bóixols anticline and Coll de Nargó syncline during the Alpine orogeny are distinguished. These fractures were cemented with four generations of calcite cements, revealing that such structures allowed the migration of different marine and meteoric fluids through time. During the early contraction stage, Lower Cretaceous seawater circulated and precipitated calcite cement Cc1, whereas during the main folding stage, the system opened to meteoric waters, which mixed with the connate seawater and precipitated calcite cement Cc2. Afterwards, during the post-folding stages, connate evaporated marine fluids circulated through newly formed NW-SE and NE-SW conjugate fractures and later through strike-slip faults and precipitated calcite cements Cc3 and Cc4. The overall paragenetic sequence reveals the progressive dewatering of Cretaceous marine host sediments during progressive burial, deformation and fold tightening and the input of meteoric waters only during the main folding stage. This study illustrates the changes of fracture systems and the associated fluid-flow regimes during the evolution of fault-associated folds during orogenic growth

U-Pb dating and geochemical dataset of fracture-filling calcite veins from the Bóixols-Sant Corneli anticline (Southern Pyrenees)

U-Pb dating and geochemical analyzes (δ18O, δ13C, Δ47, 87Sr/86Sr and elemental composition) have been applied to fracture-filling calcite veins and host carbonates from the Bóixols-Sant Corneli anticline, which developed along the front of the Bóixols thrust sheet in the Southern Pyrenees. This robust dataset is used to determine: (i) the absolute timing of fracturing and mineralization from fluid flow; (ii) the age and duration of fold evolution; and (iii) the variations and implications of fluid behavior across the anticline, as has been described in the article “Spatio-temporal variation of fluid flow behavior along a fold: The Bóixols-Sant Corneli anticline (Southern Pyrenees) from U–Pb dating and structural, petrographic, and geochemical constraints – Marine and Petroleum Geology (2022) (Muñoz-López et al., 2022). In this new contribution, we present the raw data that have been analyzed and discussed in the related research article and, also, the whole elemental and REE composition of calcite veins and host carbonates that has not been published yet. These data may be used to unravel the age and origin of veins, to understand their sequential evolution in orogenic belts and to compare our results with those obtained in similar settings worldwide.</p

Examining the immune signatures of SARS-CoV-2 infection in pregnancy and the impact on neurodevelopment: Protocol of the SIGNATURE longitudinal study

The COVID-19 pandemic represents a valuable opportunity to carry out cohort studies that allow us to advance our knowledge on pathophysiological mechanisms of neuropsychiatric diseases. One of these opportunities is the study of the relationships between inflammation, brain development and an increased risk of suffering neuropsychiatric disorders. Based on the hypothesis that neuroinflammation during early stages of life is associated with neurodevelopmental disorders and confers a greater risk of developing neuropsychiatric disorders, we propose a cohort study of SARS-CoV-2-infected pregnant women and their newborns. The main objective of SIGNATURE project is to explore how the presence of prenatal SARS-CoV-2 infection and other non-infectious stressors generates an abnormal inflammatory activity in the newborn. The cohort of women during the COVID-19 pandemic will be psychological and biological monitored during their pregnancy, delivery, childbirth and postpartum. The biological information of the umbilical cord (foetus blood) and peripheral blood from the mother will be obtained after childbirth. These samples and the clinical characterisation of the cohort of mothers and newborns, are tremendously valuable at this time. This is a protocol report and no analyses have been conducted yet, being currently at, our study is in the recruitment process step. At the time of this publication, we have identified 1,060 SARS-CoV-2 infected mothers and all have already given birth. From the total of identified mothers, we have recruited 537 SARS-COV-2 infected women and all of them have completed the mental health assessment during pregnancy. We have collected biological samples from 119 mothers and babies. Additionally, we have recruited 390 non-infected pregnant women.This work has received support from the Fundación Alicia Koplowitz to realize the epigenetic wide association study and to the clinical assessment to the children. This work has also received public support from the Consejería de Salud y Familias para la financiación de la investigación, desarrollo e innovación (i + d + i) biomédica y en ciencias de la salud en Andalucía (CSyF 2021 - FEDER). Grant Grant number PECOVID- 0195-2020. Convocatoria financiada con Fondo Europeo de Desarrollo Regional (FEDER) al 80% dentro del Programa Operativo de Andalucía FEDER 2014-2020. Andalucía se mueve con Europa. NG-T received payment under Rio Hortega contract CM20-00015 with the Carlos III Health Institute.Peer reviewe