Solid rocket technology advancements for space tug and IUS applications

In order for the shuttle tug or interim upper stage (IUS) to capture all the missions in the current mission model for the tug and the IUS, an auxiliary or kick stage, using a solid propellant rocket motor, is required. Two solid propellant rocket motor technology concepts are described. One concept, called the 'advanced propulsion module' motor, is an 1800-kg, high-mass-fraction motor, which is single-burn and contains Class 2 propellent. The other concept, called the high energy upper stage restartable solid, is a two-burn (stop-restartable on command) motor which at present contains 1400 kg of Class 7 propellant. The details and status of the motor design and component and motor test results to date are presented, along with the schedule for future work

The Effect of Clamping Pressure and Orthotropic Wood Structure on Strength of Glued Bonds

Reference values for compression strength perpendicular to the grain were determined for radial and tangential sections of samples of sugar maple and ponderosa pine. Samples to be glued were matched according to specific gravity and orthotropic structure and bonded along the grain in tangential or radial sections. Magnitude of clamp pressure was controlled throughout a range of pressures commonly applied in industry, up to about 80% of the compression strength of the wood sample. Tests were conducted on the bonded samples to determine glueline shear strength and percent of wood failure at the bonded surfaces. Results were subjected to regression analysis to ascertain relationships. It was determined that clamping pressure had a different effect on both shear strength and percent of wood failure depending on species and orthotropic section. It is possible to maximize joint strength by applying proper clamping pressure. Results similar in direction but differing in magnitude were obtained with both PVAc and U-F adhesives. A generalized measure of clamping pressure was defined as the ratio of applied clamping pressure to the compression strength (CP/CS) of the wood section to be glued. Using this concept, the optimum clamping pressure for sugar maple was found to be 0.3 times compression strength using U-F glue and 0.5 times using PVAc glue. This approach to determining reliable clamping pressure data can lead to improved gluing practice and more precise testing procedures

Interactions between alkali metals and oxygen on a reconstructed surface: An STM study of oxygen adsorption on the alkali-metal-covered Cu(110) surface

Room-temperature adsorption of oxygen on potassium- and cesium-precovered Cu(110) surfaces was studied by scanning tunneling microscopy. Depending on the alkali-metal precoverage, two different scenarios exist for the structural evolution of the surfaces. For alkali-metal coverages θalk≤0.13 ML [θalk=0.13 corresponds to the (1×3) missing-row reconstructed Cu(110) surface], oxygen adsorption leads first to a transient contraction of the missing rows into islands of a (1×2) structure. After longer exposures it causes the local removal of the alkali-metal-induced reconstruction, and the (2×1) Cu-O ‘‘added-row’’ structure with θO=0.5 is formed. In this structure the alkali-metal atoms are incorporated in the Cu-O chains. For higher alkali-metal precoverages, in the range of the (1×2) reconstruction (θalk≊0.2), more than one-half a monolayer of oxygen can be incorporated into the (1×2) phase with only a minor structural effect before, at higher oxygen coverages, complex oxygen–alkali-metal–Cu structures with oxygen coverages well above 0.5 ML are formed. The saturation oxygen coverage is drastically enhanced beyond θO=0.5, the quasisaturation value of the clean surface. Based on mass-transport arguments the substrate is reconstructed for all ratios of oxygen and alkali metal investigated here. Hence, adsorbate-substrate interactions are essential for these structures; they are not dominated by interactions between alkali metals and oxygen, i.e., by adsorbate-adsorbate interactions

Ionic Liquid Electrolytes for Metal-Air Batteries: Interactions between O2, Zn2+ and H2O Impurities

Motivated by the potential of ionic liquids (ILs) to replace traditional aqueous electrolytes in Zn-air batteries, we investigated the effects arising from mutual interactions between O₂ and Zn(TFSI)₂ as well as the influence of H₂O impurities in the oxygen reduction/oxygen evolution reaction (ORR/OER) and in Zn deposition/dissolution on a glassy carbon (GC) electrode in the ionic liquid N-butyl-N-methylpyrrolidinium bis(trifluoromethanesulfonyl)-imide (BMP-TFSI) by differential electrochemical mass spectrometry. This allowed us to determine the number of electrons transferred per reduced/evolved O₂ molecule. In O₂ saturated neat BMP-TFSI the ORR and OER were found to be reversible, in Zn²⁺containing IL Zn deposition/stripping proceeds reversibly as well. Simultaneous addition of O₂ and Zn²⁺ suppresses Zn metal deposition, instead ZnO₂ is formed in the ORR, which is reversible only after excursions to very negative potentials (−1.4 V). The addition of water leads to an enhancement of all processes described above, which is at least partly explained by a higher mobility of O₂ and Zn²⁺ in the water containing electrolytes. Consequences for the operation of Zn-air batteries in these electrolytes are discussed

Influence of Additives on the Reversible Oxygen Reduction Reaction/Oxygen Evolution Reaction in the Mg²⁺‐Containing Ionic Liquid N ‐Butyl‐N ‐Methylpyrrolidinium Bis(Trifluoromethanesulfonyl)imide

The influence of different additives on the oxygen reduction reaction/oxygen evolution reaction (ORR/OER) in magnesium‐containing N ‐butyl‐N ‐methylpyrrolidinium bis(trifluoromethanesulfonyl)imide ([BMP][TFSI]) on a glassy carbon electrode was investigated to gain a better understanding of the electrochemical processes in Mg–air batteries. 18‐Crown‐6 was used as a complexing agent for Mg ions to hinder the passivation caused by their reaction with ORR products such as superoxide and peroxide anions. Furthermore, borane dimethylamine complex (NBH) was used as a potential water‐removing agent to inhibit electrode passivation by reacting with trace impurities of water. The electrochemical processes were characterized by differential electrochemical mass spectrometry to monitor the consumed and evolved O2 in the ORR/OER and determine the number of transferred electrons. Crown ether and NBH efficiently masked Mg$^{2+}$. A stochiometric excess of crown ether resulted in reduced formation of a passivation layer, whereas at too high concentrations the reversibility of the ORR/OER was diminished

Atomic structure of Cu adlayers on Au(100) and Au(111) electrodes observed by in situ scanning tunneling microscopy

The atomic structure of ordered Cu adsorbate layers on Au(111) and Au(100) electrode surfaces and of the clean substrates was resolved in scanning tunneling microscopy images taken in situ. For submonolayer coverages deposited from sulfuric acid solutions under potential control, various ordered structures were observed. The quasihexagonal arrangement of Cu atoms in these structures reflects increasingly repulsive interactions between closely spaced Cu adatoms. These structures differ from the pseudomorphic Cu adlayer formed under vacuum conditions, which demonstrates the structure-determining role of the coadsorbed anions

Interaction of oxygen with Al(111) at elevated temperatures

The interaction of oxygen with Al(111) was investigated by STM at temperatures between 350 and 530 K, by annealing an oxygen precovered surface and by adsorption of oxygen on the hot surface. For exposures up to 10 L and temperatures up to 470 K a considerable part of the oxygen exists still in the chemisorbed state, another part transforms into Al oxide. In contrast to 300 K chemisorbed Oad atoms are mobile at elevated temperatures, and compact, hexagonal (1×1)Oad islands develop by an ordinary nucleation and growth scheme. This evidences attractive interactions between the oxygen atoms on (1×1) sites. From the lateral distribution of Oad islands a diffusion barrier of 1.0–1.1 eV is derived. The imaging of the islands of the (1×1) phase by STM depends on their size, which is understood by a different imaging of the Oad/Al adsorbate complexes at the island borders. Defects in the islands and bright features at the edges are interpreted as nuclei of aluminum oxide. Additional features which appear as topographic holes may be attributed to nonconducting Al oxide grains

A Combined XPS and Computational Study of the Chemical Reduction of BMP‐TFSI by Lithium

Employing density functional theory (DFT) calculations and X-ray photoelectron spectroscopy (XPS), we identify products of the reaction of the ionic liquid N,N-butylmethylpyrrolidinum bis(trifluoromethylsulfonyl)imide (BMP-TFSI) with lithium in order to model the initial chemical processes contributing to the formation of the solid electrolyte interphase in batteries. Besides lithium oxide, sulfide, carbide and fluoride, we find lithium cyanide or cyanamide as possible, thermodynamically stable product in the Li-poor regime, whilst Li$_{3}$N is the stable product in the Li-rich regime. The thermodynamically controlled reaction products as well as larger fragments of TFSI persisting due to kinetic barriers could be identified by a comparison of experimentally and computationally determined core level binding energies