Estudio de las propiedades mecánicas, tribológicas y electroquímicas de aleaciones CoCrMoC con adiciones de boro

El ser humano con su admirable capacidad de ingenio, se ha distinguido por la característica de innovación en diferentes áreas del conocimiento a través del tiempo, tal ha sido el caso de la bio-ingeniería en donde se han desarrollado una gran cantidad de aplicaciones biomédicas con el objeto de acrecentar la calidad de vida de muchos pacientes. Una de las aplicaciones biomédicas catalogadas como uno de los avances médicos más importantes del siglo XX, fue el éxito del implante total de la cadera. Actualmente los materiales de contacto utilizados para este sistema protésico no cuentan con la suficiente resistencia al desgaste para pacientes activos (jóvenes), las partículas de desgaste acumuladas en los alrededores del implante promueven respuestas inflamatorias de rechazo al implante teniendo que re-intervenir hasta tres veces durante la vida del paciente. El presente trabajo está enfocado en un estudio tribológico en diferentes microestructuras de la aleación Co-Cr la cual ha sido ampliamente utilizada y aceptada en la manufactura de implantes quirúrgicos articulares. Este trabajo, además de contribuir con la formación de un tecnólogo, sin duda deja huella en las líneas de investigación y desarrollo tecnológico de biomateriales y biotribología para la humanidad dado a que con los resultados de este estudio, se podrán plantear nuevas alternativas de contacto y nuevos estudios biotribológicos en simuladores de cadera a fin de incrementar la durabilidad de implantes quirúrgicos articulares para una creciente y cada vez más longeva población

X-ray determination of compressive residual Stresses in spring steel generated by high-speed water Quenching

Automotive components manufacturers use the 5160 steel in leaf and coil springs. The industrial heat treatment process consists in austenitizing followed by the oil quenching and tempering process. Typically, compressive residual stresses are induced by shot peening on the surface of automotive springs to bestow compressive residual stresses that improve the fatigue resistance and increase the service life of the parts after heat treatment. In this work, a high-speed quenching was used to achieve compressive residual stresses on the surface of AISI/SAE 5160 steel samples by producing high thermal gradients and interrupting the cooling in order to generate a case-core microstructure. A special laboratory equipment was designed and built, which uses water as the quenching media in a high-speed water chamber. The severity of the cooling was characterized with embedded thermocouples to obtain the cooling curves at different depths from the surface. Samples were cooled for various times to produce different hardened case depths. The microstructure of specimens was observed with a scanning electron microscope (SEM). X-ray diffraction (XRD) was used to estimate the magnitude of residual stresses on the surface of the specimens. Compressive residual stresses at the surface and sub-surface of about -700 MPa were obtained.Peer ReviewedPostprint (published version

Continuous Estimation of the Crack Growth Rate during Rotating‒Bending Fatigue Testing

A method for estimating the crack growth rate in steel during rotating‒bending fatigue testing is presented. Constant deflection tests were conducted in which the initial load remained constant prior to crack nucleation, when it decreased as the crack grew. In the proposed approach, steel samples were sharp-notched to produce a characteristic circular fracture upon loading and the final fracture area was correlated with a ratio of the load prior to fracture and the initial load. In this method, the deflection imposed is a function of a material’s elastic modulus rather than its yield strength and the correlation obtained to estimate the average crack length as a function of the instantaneous load is independent of the applied stress or steel grade

X-ray Determination of Compressive Residual Stresses in Spring Steel Generated by High-Speed Water Quenching

Automotive components manufacturers use the 5160 steel in leaf and coil springs. The industrial heat treatment process consists in austenitizing followed by the oil quenching and tempering process. Typically, compressive residual stresses are induced by shot peening on the surface of automotive springs to bestow compressive residual stresses that improve the fatigue resistance and increase the service life of the parts after heat treatment. In this work, a high-speed quenching was used to achieve compressive residual stresses on the surface of AISI/SAE 5160 steel samples by producing high thermal gradients and interrupting the cooling in order to generate a case-core microstructure. A special laboratory equipment was designed and built, which uses water as the quenching media in a high-speed water chamber. The severity of the cooling was characterized with embedded thermocouples to obtain the cooling curves at different depths from the surface. Samples were cooled for various times to produce different hardened case depths. The microstructure of specimens was observed with a scanning electron microscope (SEM). X-ray diffraction (XRD) was used to estimate the magnitude of residual stresses on the surface of the specimens. Compressive residual stresses at the surface and sub-surface of about --700 MPa were obtained

Tribological Performance of CoCrMo Alloys with Boron Additions in As-Cast and Heat-Treated Conditions

The present study evaluates the effect of boron additions on the tribological performance of CoCrMo alloys. The alloys were prepared with boron ranging from 0.06 to 1 wt%. The materials were characterized using metallographic techniques, scanning electronic microscopy, and roughness and hardness tests. Tribological evaluation was made by means of ball-on-disc tests for sliding distances of 4, 8 and 12 km. The samples were in the as-cast condition and after a heat treatment at 1200 °C for 1 h, finished by water quenching. The results showed that wear resistance was influenced by the microstructure and the number of secondary phases. The volume loss decreased as the boron content increased. Due to hard phases, abrasion wear was observed. Delamination fatigue was also detected after long sliding distances. Both wear mechanisms diminished in higher boron content alloys

Influence of Boron Addition on the Microstructure and the Corrosion Resistance of CoCrMo Alloy

Cobalt-based alloys are extensively used in orthopedic applications for joint replacements due to their wear and corrosion resistance. Corrosion, however, is often associated with fatigue failure in these orthopedic devices. In this study, the effect of boron addition on the corrosion behavior of CoCrMo alloys was studied using linear polarization resistance, potentiodynamic polarization curves, electrochemical impedance spectroscopy, and cyclic voltammetry. The samples were analyzed under as-cast and heat treatment conditions after 21 days of immersion in phosphate-buffered saline (PBS) solution at 37 °C. The boron addition increased the particle content, while the heat treatment promoted enlargement and even distribution of the precipitates throughout the structure. The corrosion resistance was improved by both boron and heat treatments. The best performance was observed for a heat-treated alloy having a very small amount of boron, which had an increased resistance to corrosive attack. Such behavior was attributed to the homogenized microstructure achieved by boron and heat treatment that helped to form a stable passive layer of chromium oxide which endured the 21 days of immersion

Influence of Boron Additions and Heat Treatments on the Fatigue Resistance of CoCrMo Alloys

Cobalt-based alloys are widely used in the manufacture of joint prostheses. In this study, the effect of boron additions and heat treatment on the ASTM F75 was evaluated by rotating bending fatigue. The boron ranged from 0.06–1 wt %. The alloys were tested in as-cast and heat-treated conditions. In the as-cast condition, the infinite life was observed at 380 MPa, improving to 433–615 MPa according to the amount of boron added. In the heat treatment condition, the fatigue resistance was improved only in the base alloy. The addition of 0.06 wt % boron and heat treatment led to the same resistance as in the as-cast condition. Adding large amounts of boron combined with heat treatment diminished the fatigue limit. The fracture analysis revealed primarily brittle behaviour with some ductile features even on the same sample; only the heat-treated alloy with 0.06 wt % boron was clearly ductile. This alloy also exhibited notably better toughness to crack propagation

X-ray determination of compressive residual Stresses in spring steel generated by high-speed water Quenching

Automotive components manufacturers use the 5160 steel in leaf and coil springs. The industrial heat treatment process consists in austenitizing followed by the oil quenching and tempering process. Typically, compressive residual stresses are induced by shot peening on the surface of automotive springs to bestow compressive residual stresses that improve the fatigue resistance and increase the service life of the parts after heat treatment. In this work, a high-speed quenching was used to achieve compressive residual stresses on the surface of AISI/SAE 5160 steel samples by producing high thermal gradients and interrupting the cooling in order to generate a case-core microstructure. A special laboratory equipment was designed and built, which uses water as the quenching media in a high-speed water chamber. The severity of the cooling was characterized with embedded thermocouples to obtain the cooling curves at different depths from the surface. Samples were cooled for various times to produce different hardened case depths. The microstructure of specimens was observed with a scanning electron microscope (SEM). X-ray diffraction (XRD) was used to estimate the magnitude of residual stresses on the surface of the specimens. Compressive residual stresses at the surface and sub-surface of about -700 MPa were obtained.Peer Reviewe