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A dramatic isotope effect in the reaction of ClSiH with trimethylsilane-1-d: experimental evidence for intermediate complexes in silylene Si-H(D) insertion reactions
A kinetic isotope effect (kD/kH) of 7.4 has been found for the reaction of chlorosilylene with trimethysilane (Me3SiD vs Me3SiH). Such a value can be accounted for by theoretical modelling, but only if an internal rearrangement of the initially form complex is included in the mechanism. This provides the first concrete evidence for such complexes
Reverse Shock Emission Revealed in Early Photometry in the Candidate Short GRB 180418A
We present observations of the possible short GRB 180418A in -rays,
X-rays, and in the optical. Early optical photometry with the TAROT and RATIR
instruments show a bright peak ( 14.2 AB mag) between and
seconds that we interpret as the signature of a reversal shock. Later
observations can be modeled by a standard forward shock model and show no
evidence of jet break, allowing us to constrain the jet collimation to
. Using deep late-time optical observations we place an
upper limit of AB mag on any underlying host galaxy. The detection of
the afterglow in the \textit{Swift} UV filters constrains the GRB redshift to
and places an upper bound on the -ray isotropic equivalent
energy erg.
The properties of this GRB (e.g. duration, hardness ratio, energetic, and
environment) lie at the intersection between short and long bursts, and we can
not conclusively identify its type. We estimate that the probability that it is
drawn from the population of short GRBs is 10\%-30\%.Comment: Accepted por publication in Ap
Modeling Gamma-ray burst Afterglow observations with an Off-axis Jet emission
Gamma-ray bursts (GRBs) are fascinating extragalactic objects. They represent
a fantastic opportunity to investigate unique properties not exhibited in other
sources. Multi-wavelength afterglow observations from some short- and
long-duration GRBs reveal an atypical long-lasting emission that evolves
differently from the canonical afterglow light curves favoring the off-axis
emission. We present an analytical synchrotron afterglow scenario, and the
hydrodynamical evolution of an off-axis top-hat jet decelerated in a stratified
surrounding environment. The analytical synchrotron afterglow model is shown
during the coasting, deceleration (off- and on-axis emission), and the
post-jet-break decay phases, and the hydrodynamical evolution is computed by
numerical simulations showing the time evolution of the Doppler factor, the
half-opening angle, the bulk Lorentz factor, and the deceleration radius. We
show that numerical simulations are in good agreement with those derived with
our analytical approach. We apply the current synchrotron model and describe
successfully the delayed non-thermal emission observed in a sample of long and
short GRBs with evidence of off-axis emission. Furthermore, we provide
constraints on the possible afterglow emission by requiring the
multi-wavelength upper limits derived for the closest Swift-detected GRBs and
promising gravitational-wave events.Comment: 36 pages, 16 figures, accepted for publication in Ap
New GTC spectroscopic data and a statistical study to better constrain the redshift of the BL Lac RGB J2243 + 203
We present new spectroscopic data of the BL Lac RGB 2243 + 203, and its surroundings, obtained with the OSIRIS Multi Object Spectrograph (MOS) mounted in the Gran Telescopio Canarias (GTC). The spectra of neither the BL Lac nor its host galaxy show any spectral feature, thus hindering direct determination of its redshift. The spectroscopic redshift distribution of objects in the MOS field of view shows four galaxies with redshift between 0.5258 and 0.5288. We make use of a statistical analysis to test the possibility that the targeted BL Lac may be a member of that group. By using the spectroscopic redshifts obtained with our GTC observations, we found that this probability is between 86 and 93 per cent.Fil: Rosa González, D. Instituto Nacional de Astrofísica, Optica y Electrónica; MéxicoFil: Muriel, Hernan. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Astronomía Teórica y Experimental. Universidad Nacional de Córdoba. Observatorio Astronómico de Córdoba. Instituto de Astronomía Teórica y Experimental; ArgentinaFil: Mayya, Y. D.. Instituto Nacional de Astrofísica, Optica y Electrónica; MéxicoFil: Aretxaga, I.. Instituto Nacional de Astrofísica, Optica y Electrónica; MéxicoFil: Becerra González, J.. Instituto de Astrofisica de Canarias; EspañaFil: Carramiñana, Alberto. Instituto Nacional de Astrofísica, Optica y Electrónica; MéxicoFil: Méndez-Abreu, J.. Instituto Nacional de Astrofísica, Optica y Electrónica; MéxicoFil: Vega, O. Instituto Nacional de Astrofísica, Optica y Electrónica; MéxicoFil: Terlevich, E-. Instituto Nacional de Astrofísica, Optica y Electrónica; MéxicoFil: Coutiño de León, S.. Instituto Nacional de Astrofísica, Optica y Electrónica; MéxicoFil: Furniss, A.. Instituto Nacional de Astrofísica, Optica y Electrónica; MéxicoFil: Longinotti, A. L.. Instituto Nacional de Astrofísica, Optica y Electrónica; MéxicoFil: Terlevich, R. J.. Instituto Nacional de Astrofísica, Optica y Electrónica; MéxicoFil: Pichel, Ana Carolina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Astronomía y Física del Espacio. - Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Astronomía y Física del Espacio; ArgentinaFil: Rovero, Adrian Carlos. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Astronomía y Física del Espacio. - Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Astronomía y Física del Espacio; ArgentinaFil: Donzelli, Carlos Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Astronomía Teórica y Experimental. Universidad Nacional de Córdoba. Observatorio Astronómico de Córdoba. Instituto de Astronomía Teórica y Experimental; Argentin
VAMOS: a Pathfinder for the HAWC Gamma-Ray Observatory
VAMOS was a prototype detector built in 2011 at an altitude of 4100m a.s.l.
in the state of Puebla, Mexico. The aim of VAMOS was to finalize the design,
construction techniques and data acquisition system of the HAWC observatory.
HAWC is an air-shower array currently under construction at the same site of
VAMOS with the purpose to study the TeV sky. The VAMOS setup included six water
Cherenkov detectors and two different data acquisition systems. It was in
operation between October 2011 and May 2012 with an average live time of 30%.
Besides the scientific verification purposes, the eight months of data were
used to obtain the results presented in this paper: the detector response to
the Forbush decrease of March 2012, and the analysis of possible emission, at
energies above 30 GeV, for long gamma-ray bursts GRB111016B and GRB120328B.Comment: Accepted for pubblication in Astroparticle Physics Journal (20 pages,
10 figures). Corresponding authors: A.Marinelli and D.Zaboro
The Sensitivity of HAWC to High-Mass Dark Matter Annihilations
The High Altitude Water Cherenkov (HAWC) observatory is a wide field-of-view
detector sensitive to gamma rays of 100 GeV to a few hundred TeV. Located in
central Mexico at 19 degrees North latitude and 4100 m above sea level, HAWC
will observe gamma rays and cosmic rays with an array of water Cherenkov
detectors. The full HAWC array is scheduled to be operational in Spring 2015.
In this paper, we study the HAWC sensitivity to the gamma-ray signatures of
high-mass (multi- TeV) dark matter annihilation. The HAWC observatory will be
sensitive to diverse searches for dark matter annihilation, including
annihilation from extended dark matter sources, the diffuse gamma-ray emission
from dark matter annihilation, and gamma-ray emission from non-luminous dark
matter subhalos. Here we consider the HAWC sensitivity to a subset of these
sources, including dwarf galaxies, the M31 galaxy, the Virgo cluster, and the
Galactic center. We simulate the HAWC response to gamma rays from these sources
in several well-motivated dark matter annihilation channels. If no gamma-ray
excess is observed, we show the limits HAWC can place on the dark matter
cross-section from these sources. In particular, in the case of dark matter
annihilation into gauge bosons, HAWC will be able to detect a narrow range of
dark matter masses to cross-sections below thermal. HAWC should also be
sensitive to non-thermal cross-sections for masses up to nearly 1000 TeV. The
constraints placed by HAWC on the dark matter cross-section from known sources
should be competitive with current limits in the mass range where HAWC has
similar sensitivity. HAWC can additionally explore higher dark matter masses
than are currently constrained.Comment: 15 pages, 4 figures, version to be published in PR
Machine-Learning Enhanced Photometric Analysis of the Extremely Bright GRB 210822A
We present analytical and numerical models of the bright long GRB 210822A at
. The intrinsic extreme brightness exhibited in the optical, which is
very similar to other bright GRBs (e.g., GRBs 080319B, 130427A, 160625A
190114C, and 221009A), makes GRB 210822A an ideal case for studying the
evolution of this particular kind of GRB. We use optical data from the RATIR
instrument starting at s, with publicly available optical data from
other ground-based observatories, as well as X-ray data from the Swift/X-ray
Telescope (XRT) and data from the Swift/Ultraviolet/Optical Telescope (UVOT).
The temporal profiles and spectral properties during the late stages align
consistently with the conventional forward shock model, complemented by a
reverse shock element that dominates optical emissions during the initial
phases ( s). Furthermore, we observe a break at s that we
interpreted as evidence of a jet break, which constrains the opening angle to
be about degrees. Finally, we apply a
machine-learning technique to model the multi-wavelength light curve of GRB
210822A using the AFTERGLOWPY library. We estimate the angle of sight
degrees, the energy ergs, the electron index , the thermal
energy fraction in electrons and in
the magnetic field , the efficiency
, and the density of the surrounding medium .Comment: Submitted to MNRAS, 11 pages, 6 figures. Fixed typo
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