6,195 research outputs found
Bulk, surface and corner free energy series for the chromatic polynomial on the square and triangular lattices
We present an efficient algorithm for computing the partition function of the
q-colouring problem (chromatic polynomial) on regular two-dimensional lattice
strips. Our construction involves writing the transfer matrix as a product of
sparse matrices, each of dimension ~ 3^m, where m is the number of lattice
spacings across the strip. As a specific application, we obtain the large-q
series of the bulk, surface and corner free energies of the chromatic
polynomial. This extends the existing series for the square lattice by 32
terms, to order q^{-79}. On the triangular lattice, we verify Baxter's
analytical expression for the bulk free energy (to order q^{-40}), and we are
able to conjecture exact product formulae for the surface and corner free
energies.Comment: 17 pages. Version 2: added 4 further term to the serie
Recommended from our members
Experimental and Theoretical Evidence for Nitrogen-Fluorine Halogen Bonding in Silver-Initiated Radical Fluorinations
We
report experimental and computational evidence for nitrogen–fluorine
halogen bonding in Ag(I)-initiated radical C–H fluorinations.
Simple pyridines form [N–F–N]+ halogen bonds
with Selectfluor to facilitate single-electron reduction by catalytic
Ag(I). Pyridine electronics affect the extent of halogen bonding,
leading to significant differences in selectivity between mono- and
difluorinated products. Electronic structure calculations show that
halogen bonding to various pyridines alters the single-electron reduction
potential of Selectfluor, which is consistent with experimental electrochemical
analysis. Multinuclear correlation NMR also provides spectroscopic
evidence for pyridine halogen bonding to Selectfluor under ambient
conditions
Critical and Tricritical Hard Objects on Bicolorable Random Lattices: Exact Solutions
We address the general problem of hard objects on random lattices, and
emphasize the crucial role played by the colorability of the lattices to ensure
the existence of a crystallization transition. We first solve explicitly the
naive (colorless) random-lattice version of the hard-square model and find that
the only matter critical point is the non-unitary Lee-Yang edge singularity. We
then show how to restore the crystallization transition of the hard-square
model by considering the same model on bicolored random lattices. Solving this
model exactly, we show moreover that the crystallization transition point lies
in the universality class of the Ising model coupled to 2D quantum gravity. We
finally extend our analysis to a new two-particle exclusion model, whose
regular lattice version involves hard squares of two different sizes. The exact
solution of this model on bicolorable random lattices displays a phase diagram
with two (continuous and discontinuous) crystallization transition lines
meeting at a higher order critical point, in the universality class of the
tricritical Ising model coupled to 2D quantum gravity.Comment: 48 pages, 13 figures, tex, harvmac, eps
The application of the global isomorphism to the surface tension of the liquid-vapor interface of the Lennard-Jones fluids
In this communication we show that the surface tension of the real fluids of
the Lennard-Jones type can be obtained from the surface tension of the lattice
gas (Ising model) on the basis of the global isomorphism approach developed
earlier for the bulk properties.Comment: 8 pages, 6 figure
Study of the Potts Model on the Honeycomb and Triangular Lattices: Low-Temperature Series and Partition Function Zeros
We present and analyze low-temperature series and complex-temperature
partition function zeros for the -state Potts model with on the
honeycomb lattice and on the triangular lattice. A discussion is given
as to how the locations of the singularities obtained from the series analysis
correlate with the complex-temperature phase boundary. Extending our earlier
work, we include a similar discussion for the Potts model with on the
honeycomb lattice and with on the kagom\'e lattice.Comment: 33 pages, Latex, 9 encapsulated postscript figures, J. Phys. A, in
pres
Ground State of the Quantum Symmetric Finite Size XXZ Spin Chain with Anisotropy Parameter
We find an analytic solution of the Bethe Ansatz equations (BAE) for the
special case of a finite XXZ spin chain with free boundary conditions and with
a complex surface field which provides for symmetry of the
Hamiltonian. More precisely, we find one nontrivial solution, corresponding to
the ground state of the system with anisotropy parameter
corresponding to .Comment: 6 page
Statistical mechanical aspects of joint source-channel coding
An MN-Gallager Code over Galois fields, , based on the Dynamical Block
Posterior probabilities (DBP) for messages with a given set of autocorrelations
is presented with the following main results: (a) for a binary symmetric
channel the threshold, , is extrapolated for infinite messages using the
scaling relation for the median convergence time, ;
(b) a degradation in the threshold is observed as the correlations are
enhanced; (c) for a given set of autocorrelations the performance is enhanced
as is increased; (d) the efficiency of the DBP joint source-channel coding
is slightly better than the standard gzip compression method; (e) for a given
entropy, the performance of the DBP algorithm is a function of the decay of the
correlation function over large distances.Comment: 6 page
Absence of Phase Transition for Antiferromagnetic Potts Models via the Dobrushin Uniqueness Theorem
We prove that the -state Potts antiferromagnet on a lattice of maximum
coordination number exhibits exponential decay of correlations uniformly at
all temperatures (including zero temperature) whenever . We also prove
slightly better bounds for several two-dimensional lattices: square lattice
(exponential decay for ), triangular lattice (), hexagonal
lattice (), and Kagom\'e lattice (). The proofs are based on
the Dobrushin uniqueness theorem.Comment: 32 pages including 3 figures. Self-unpacking file containing the tex
file, the needed macros (epsf.sty, indent.sty, subeqnarray.sty, and
eqsection.sty) and the 3 ps file
Design of a high efficiency cyclone for collection of rare and low concentration airborne pathogens
Recent serious outbreaks of pathogens such as Chalara Fraxinea, (Ash Dieback) demonstrate the vulnerability of UK’s forests, woods, and trees. Early detection of threats is critical in the fight against such tree pests and pathogens. This requires a process for collecting and analysing the spores which is robust, flexible and can be deployed rapidly, but which also has sufficient sensitivity to detect the earliest precursors. The work presented here describes a newly-developed high-efficiency detection apparatus and is part of an ongoing BBRSC project to improve the UK’s biosecurity. Our automatic spore system is capable of collecting and analysing Chalara Fraxinea using a novel cyclonic pathogen collector. Cyclones are an effective way to separate small particles (spores) from large quantities of surrounding air and store them for analysis. Our system incorporates a purpose-designed high efficiency cyclone directly integrated with a low power custom impeller to maximise volumetric air sampling while minimising the power requirement. 3D printing was used extensively to validate theoretical models and the particle collection and retention capability of this series of prototypes was evaluated experimentally within our Aerosol test chamber. We found that we could collect greater than 90% of particulate in the target size range, thus providing a front-end to a detection platform. Our system is capable of operating autonomously and at low power, with a high sensitivity to ambient particles. The final system design incorporates the use of multiple cyclone storage vessels ensuring complete isolation of each sample, eradicating cross-contamination, and facilitating automated handling of the sample inside the same apparatus. COTS – commercial off the shelf components were incorporated into the cyclone to make a series of cost effective collection vessels. Early collection and detection of pathogens in-situ represents a considerable advance in surveillance and monitoring of pathogens strengthening UK biosecurity for the future
Development of an automated smart trap for wheat pathogens
National surveys show fungicide use on wheat continues to increase despite fluctuations in disease pressure, reaching a 30 year high in 2012 (Defra). Septoria tritici is the most significant foliar disease in UK wheat causing between £43M to £53M in yield losses annually; Yellow and brown rust are more sporadic but have caused significant losses during high disease years. In all cases control is by fungicide application costing £82M annually (GFK Kynetec 2013). Effective disease management relies on either prophylactic pesticide use or significant manual intervention and time consuming assessment of crop disease indicators by farmers and agronomists. Furthermore indications are that current levels of pesticide use could lead to increased risk of pesticide resistance, if this should occur it is estimated that wheat yields could reduce by up to 20%. To address this we have developed a prototype integrated and automated spore detection system, designed for unattended field application, to monitor and identify the presence of Septoria, brown and yellow rust. The prototype system incorporates novel cyclonic pathogen collection, on-board sample processing and isothermal DNA amplification chemistry (LAMP). We present the engineering design, optimisation and evaluation of our prototype system reporting on successfully completed laboratory testing and initial field trial results. This prototype will be the basis for the development of a commercially available system which, in addition to inoculum detection, will be capable of providing growers/agronomists with real-time information on inoculum moving into a crop enabling more effective timing and selection of fungicide application, and thus better control, increased yield, and improved environmental stewardship
- …