A long-term experimental study of the reactivity of basement rock with highly alkaline cement waters: reactions over the first 15 months

A series of long-term laboratory experiments was started in 1995 to investigate longer-term dissolution/precipitation reactions that may occur in the alkaline disturbed zone surrounding a cementitious repository for radioactive waste. They consist of samples of UK basement rock reacting with either Na-K-Ca-OH water (‘young’ cement porewater) or Ca-OH water (‘evolved’ cement porewater) at 70°C. This paper summarizes results of reactions occurring over the first 15 months. Experiments of both fluid types showed many similar features, though primary mineral dissolution and secondary mineral precipitation were more extensive in the experiments involving Na-K-Ca (younger) cement porefluids compared to more evolved (Ca-rich) cement porefluids. Dissolution of dolomite, and to a lesser extent silicates (probably K-feldspar, but also possibly mica) occurred relatively rapidly at 70°C. Dolomite dissolution may have been a key factor in reducing pH values, and may be a key mineral in controlling the extent of alkaline disturbed zones. Dissolution was followed by precipitation of brucite close to dolomite grains, at least two generations of C-S-H phases (which may have contained variable amounts of K, Al and Mg); overgrowths of calcite; small crystals of hydroxyapophyllite; and elongate crystals of celestite. Though hydroxyapophyllite was observed (a phase commonly associated with zeolites), there was no evidence for the formation of zeolites in the experiments. Fluid chemical changes track the mineralogical changes, with C-S-H phases being a major control on fluid chemistry. In the ‘young’ porewater experiments there were decreases in pH, and K, Ca and Mg concentrations, together with transitory increases in SiO2 concentrations. In the ‘evolved’ porewater experiments there were decreases in pH, Mg, Ca and Sr concentrations, together with small increases in K and SiO2 concentrations. A number of experiments are still running, and will be sampled in coming years

On the production of26A1 in the early solar system by low-energy oxygen cosmic rays

Clayton & Jin have proposed that the high abundance of 26Al found in meteorites was produced by cosmic rays in the early solar system through the 12C(16O,x)26Ales reaction. We have measured the yield of 26A1 in the ground state (i.e., 26Algs) from this reaction and find that, if this mechanism produced the meteoritic 26Al, a substantial fraction of the solar system oxygen must have entered the solar system as low-energy cosmic rays. This does not seem plausible. If the proto-Sun itself was the source of the oxygen cosmic rays, they must have carried off some 5% of the power of the protosolar wind for 1 Myr. This too seems unlikely. Although we do not address the role of other cosmic-ray species in the production of26 Al, it appears that 26A1 was produced in a stellar environment, and not by cosmic rays

Neutrino-antineutrino pair production by a photon in a dense matter

The possibility of radiative effects that are due to interaction of fermions with a dense matter is investigated. Neutrino-antineutrino photo-production is studied. The rate of this process is calculated in the Furry picture. It is demonstrated that this effect does not disappear even if the medium refractive index is assumed to be equal to unity. The rate obtained strongly depends on the polarization states of the particles involved. This leads to evident spatial asymmetries, which may have certain consequences observable in astrophysical and cosmological studies.Comment: 10 pages, Late

Microbiological influences on fracture surfaces of intact mudstone and the implications for geological disposal of radioactive waste

The significance of the potential impacts of microbial activity on the transport properties of host rocks for geological repositories is an area of active research. Most recent work has focused on granitic environments. This paper describes pilot studies investigating changes in transport properties that are produced by microbial activity in sedimentary rock environments in northern Japan. For the first time, these short experiments (39 days maximum) have shown that the denitrifying bacteria, Pseudomonas denitrificans, can survive and thrive when injected into flow-through column experiments containing fractured diatomaceous mudstone and synthetic groundwater under pressurized conditions. Although there were few significant changes in the fluid chemistry, changes in the permeability of the biotic column, which can be explained by the observed biofilm formation, were quantitatively monitored. These same methodologies could also be adapted to obtain information from cores originating from a variety of geological environments including oil reservoirs, aquifers and toxic waste disposal sites to provide an understanding of the impact of microbial activity on the transport of a range of solutes, such as groundwater contaminants and gases (e.g. injected carbon dioxide)

Microbial impacts of CO2 transport in Sherwood Sandstone

Work carried out by BGS and the Japan Atomic Energy Authority (JAEA) has shown that microbial processes can have profound effects on the transport properties of host rock (i.e. the movement of fluids and contaminants through the host material) relevant to radioactive waste disposal. Recent research, performed as part of the BGS Radtran project, has examined Sherwood Sandstone samples in the context of radioactive waste disposal; this particular formation is also a potential reservoir for carbon dioxide storage in the UK. As part of the BGS opportunities fund programme, this project has, for the first time, evaluated interactions between fluids saturated with carbon dioxide/Sherwood Sandstone/microbes (Pseudomonas aeruginosa) in transport experiments, using BGS developed apparatus under pressurised subsurface conditions. This pilot study has highlighted the impacts of differences in the physical characteristics of core Sherwood Sandstone samples collected adjacent to each other in a core sample, and the ability of P. aeruginosa to survive in CO2 saturated artificial groundwater and the potential to form a biofilm in an environment suitable likely to be found at a carbon capture and storage location. These results demonstrate that in this short study, the injection of P. aeruginosa into the biotic experiment does not appear to impact on the physical transport properties of the Sherwood Sandstone, although the presence of CO2 appears to enhance the mobilisation of a number of chemical species. However, in other work which utilised the same organism and rock type but without introduction of CO2 saturated fluid, post-inoculation injection changes were observed. These included short but rapid saw-tooth like changes in the pressure profile (Wragg et al, 2012). These impacts were not observed in the current study which suggests that the CO2 saturated fluid was impacting on the ability of the microbes to alter permeability. This short study has, however, indicated the need to carry out longer term investigations to reproduce these initial findings

Analytic treatment of nuclear spin-lattice relaxation for diffusion in a cone model

We consider nuclear spin-lattice relaxation rate resulted from a diffusion equation for rotational wobbling in a cone. We show that the widespread point of view that there are no analytical expressions for correlation functions for wobbling in a cone model is invalid and prove that nuclear spin-lattice relaxation in this model is exactly tractable and amenable to full analytical description. The mechanism of relaxation is assumed to be due to dipole-dipole interaction of nuclear spins and is treated within the framework of the standard Bloemberger, Purcell, Pound - Solomon scheme. We consider the general case of arbitrary orientation of the cone axis relative the magnetic field. The BPP-Solomon scheme is shown to remain valid for systems with the distribution of the cone axes depending only on the tilt relative the magnetic field but otherwise being isotropic. We consider the case of random isotropic orientation of cone axes relative the magnetic field taking place in powders. Also we consider the cases of their predominant orientation along or opposite the magnetic field and that of their predominant orientation transverse to the magnetic field which may be relevant for, e.g., liquid crystals. Besides we treat in details the model case of the cone axis directed along the magnetic field. The latter provides direct comparison of the limiting case of our formulas with the textbook formulas for free isotropic rotational diffusion. The dependence of the spin-lattice relaxation rate on the cone half-width yields results similar to those predicted by the model-free approach.Comment: 29 p., 7 fig. arXiv admin note: substantial text overlap with arXiv:1101.249

Structure of 18Ne and the breakout from the hot CNO cycle

We used the 16O(3He,n)18Ne, 12C(12C,6He)18Ne, and 20Ne(p,t)18Ne reactions to study 18Ne states up to an excitation energy of 10 MeV, with emphasis on levels corresponding to 14O(α,p)17F and 17F(p,γ)18Ne resonances that could strongly affect these reaction rates in hot stellar environments. Excitation energies, widths, absolute cross sections, and angular distributions were measured. We found previously unidentified states at Ex=6.15±0.01 MeV, 7.12±0.02 MeV, 7.35±0.02 MeV, 7.62±0.02 MeV, 8.30±0.02 MeV, (8.45 ±0.03 MeV), 8.55±0.03 MeV, 8.94±0.02 MeV, and 9.58±0.02 MeV. We combined level width, cross section, and angular distribution data to infer Jπ values for a number of the new levels as well as for the previously known 5.1-MeV doublet. Using information from our experiments, we recalculated the 14O(α.p) 17F reaction rate, which constitutes a possible path out of the hot CNO cycle into the rp process and could play an important role in transforming nuclei involved in the hot CNO cycle into heavier nuclei with Z≥10

Excavating youth justice reform: historical mapping and speculative prospects

This article analytically excavates youth justice reform (in England and Wales) by situating it in historical context, critically reviewing the competing rationales that underpin it and exploring the overarching social, economic, and political conditions within which it is framed. It advances an argument that the foundations of a recognisably modern youth justice system had been laid by the opening decade of the 20th Century and that youth justice reform in the post‐Second World War period has broadly been structured over four key phases. The core contention is that historical mapping facilitates an understanding of the unreconciled rationales and incoherent nature of youth justice reform to date, while also providing a speculative sense of future prospects