Preparation and optical properties of novel bioactive photonic crystals obtained from core-shell poly(styrene/α-tert-butoxy-ω-vinylbenzyl-polyglycidol) microspheres

Optical properties of polymer microspheres with polystyrene cores and polyglycidol-enriched shells poly(styrene/α-tert-butoxy-ω-vinylbenzyl-polyglycidol) (P(S/PGL) particles with number average diameters Dn determined by scanning electron microscopy equal 237 and 271 nm), were studied before and after immobilization of ovalbumin. The particles were synthesized by emulsifier-free emulsion copolymerization of styrene and polyglycidol macromonomer (poly(styrene/α-tert-butoxy-ω-vinylbenzyl-polyglycidol)) initiated with potassium persulfate. Molar fraction of polyglycidol units in the interfacial layer of the microspheres determined by XPS was equal 42.6 and 34.0%, for the particles with Dn equal 137 and 271 nm, respectively. Colloidal crystals from the aforementioned particles were prepared by deposition of particle suspensions on the glass slides and subsequent evaporation of water. It was found that optical properties of colloidal crystals from the P(S/PGL) microspheres strongly depend on modification of their interfacial layer by covalent immobilization of ovalbumin. The coating of particles with ovalbumin resulted in decreasing their refractive index from 1.58 to 1.52

X-ray Spectroscopy of MXB 1728-34 with XMM-Newton

We have analysed an XMM-Newton observation of the low mass X-ray binary and atoll source MXB 1728-34. The source was in a low luminosity state during the XMM-Newton observation, corresponding to a bolometric X-ray luminosity of 5*10E36 d^2 erg/s, where d is the distance in units of 5.1 kpc. The 1-11 keV X-ray spectrum of the source, obtained combining data from all the five instruments on-board XMM-Newton, is well fitted by a Comptonized continuum. Evident residuals are present at 6-7 keV which are ascribed to the presence of a broad iron emission line. This feature can be equally well fitted by a relativistically smeared line or by a self-consistent, relativistically smeared, reflection model. Under the hypothesis that the iron line is produced by reflection from the inner accretion disk, we can infer important information on the physical parameters of the system, such as the inner disk radius, Rin = 25-100 km, and the inclination of the system, 44{\deg} < i < 60{\deg}.Comment: 7 pages, 3 figures, Accepted by A&A on 29.03.201

Binary systems and their nuclear explosions

Peer ReviewedPreprin

Role of inter-district cooperation in the development of balanced tourism in rural areas – case study

With the transformation of the polish Civil Service in the 80/90. the local government obtained new regulations and possibilities in the social-economy development. Such of them is building different types of regional partnerships e.g. inter-district unions. The article discusses the essence and significance of inter-district cooperation in the development of balanced tourism in rural areas. Sustainable tourism can be important impact factor of agricultural areas development. The origin and characteristics of partnerships of subjects active in the region were presented, which gave rise to the discussion of the example of the ”Wielkopolska Gościnna” Tourism Inter-district Union (Międzygminny Związek Turystyczny „Wielkopolska Gościnna“). This made it possible to answer the question whether and, if yes, to what extent special unions may contribute to the development of balanced tourism in the rural areas