Biosolids-based catalyst for oxidative desulphurization of drop-in fuels derived from waste fats

In this work, the catalytic performance of a biosolids-based catalyst was tested in the oxidative desulphurization process of a model fuel solution containing benzothiophene ([S] of 500 ppm), as well as sulphur-rich products from a two-step thermal conversion process of brown grease to renewable hydrocarbons using biosolids as a water replacement during the hydrolysis step. The catalytic results of the biosolids-based material were compared with a classical Fenton-like reagent and a non-catalytic system. Biosolids-based catalyst outperformed the other systems at low temperature with a full desulphurization of benzothiophene solution achieved at 60 °C after 3 h and a good recyclability after four catalytic runs at 80 °C for 3 h. The desulphurization was less effective for hydrolysed fatty acids and crude pyrolysis oil derived from the conversion of brown grease to renewable hydrocarbons, which was due to the composition of the sulphur containing compounds, but still reached 87.7 ± 3.0 % and 74.7 ± 9.5 %, respectively

Gauge Fixing in Higher Derivative Gravity

Linearized four-derivative gravity with a general gauge fixing term is considered. By a Legendre transform and a suitable diagonalization procedure it is cast into a second-order equivalent form where the nature of the physical degrees of freedom, the gauge ghosts, the Weyl ghosts, and the intriguing "third ghosts", characteristic to higher-derivative theories, is made explicit. The symmetries of the theory and the structure of the compensating Faddeev-Popov ghost sector exhibit non-trivial peculiarities.Comment: 21 pages, LaTe

Field-Dependent Tilt and Birefringence of Electroclinic Liquid Crystals: Theory and Experiment

An unresolved issue in the theory of liquid crystals is the molecular basis of the electroclinic effect in the smectic-A phase. Recent x-ray scattering experiments suggest that, in a class of siloxane-containing liquid crystals, an electric field changes a state of disordered molecular tilt in random directions into a state of ordered tilt in one direction. To investigate this issue, we measure the optical tilt and birefringence of these liquid crystals as functions of field and temperature, and we develop a theory for the distribution of molecular orientations under a field. Comparison of theory and experiment confirms that these materials have a disordered distribution of molecular tilt directions that is aligned by an electric field, giving a large electroclinic effect. It also shows that the net dipole moment of a correlated volume of molecules, a key parameter in the theory, scales as a power law near the smectic-A--smectic-C transition.Comment: 18 pages, including 9 postscript figures, uses REVTeX 3.0 and epsf.st

Higher-Derivative Boson Field Theories and Constrained Second-Order Theories

As an alternative to the covariant Ostrogradski method, we show that higher-derivative relativistic Lagrangian field theories can be reduced to second differential-order by writing them directly as covariant two-derivative theories involving Lagrange multipliers and new fields. Despite the intrinsic non-covariance of the Dirac's procedure used to deal with the constraints, the explicit Lorentz invariance is recovered at the end. We develop this new setting on the grounds of a simple scalar model and then its applications to generalized electrodynamics and higher-derivative gravity are worked out. For a wide class of field theories this method is better suited than Ostrogradski's for a generalization to 2n-derivative theoriesComment: 31 pages, Plain Te

Non-destructive characterisation of a Villanovan sword using time-of-flight neutron diffraction

In the present work we report an example application of time-of-flight neutron diffraction for the non-destructive characterisation of ancient bronzes. A Villanovan sword tightly joined to its scabbard by corrosion has been investigated. Data on alloy composition of the different parts and information about the manufacturing techniques have been successfully achieved. The present study is part of an extensive non-destructive investigation program concerning bronze productions of Central Italy during the Iron Age

Energy dissipation via acoustic emission in ductile crack initiation

This article presents a modeling approach to estimate the energy release due to ductile crack initiation in conjunction to the energy dissipation associated with the formation and propagation of transient stress waves typically referred to as acoustic emission. To achieve this goal, a ductile fracture problem is investigated computationally using the finite element method based on a compact tension geometry under Mode I loading conditions. To quantify the energy dissipation associated with acoustic emission, a crack increment is produced given a pre-determined notch size in a 3D cohesive-based extended finite element model. The computational modeling methodology consists of defining a damage initiation state from static simulations and linking such state to a dynamic formulation used to evaluate wave propagation and related energy redistribution effects. The model relies on a custom traction separation law constructed using full field deformation measurements obtained experimentally using the digital image correlation method. The amount of energy release due to the investigated first crack increment is evaluated through three different approaches both for verification purposes and to produce an estimate of the portion of the energy that radiates away from the crack source in the form of transient waves. The results presented herein propose an upper bound for the energy dissipation associated to acoustic emission, which could assist the interpretation and implementation of relevant nondestructive evaluation methods and the further enrichment of the understanding of effects associated with fracture

Highly efficient methods for the one-pot synthesis of b-substituted enones

A mild and practically-convenient one-pot procedure for the direct b-substitution of enones has been developed using a conjugate addition–oxidation strategy with a full range of copper-based reagents and N-tert-butylphenylsulfinimidoyl chloride; alkyl- and aryl-substituted enones are delivered in good to excellent yields