2,187 research outputs found

    Interpersonal emotion regulation: a review of social and developmental components

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    A staple theme in clinical psychology, emotion regulation, or the ability to manage one's emotions, is directly linked with personal wellbeing and the ability to effectively navigate the social world. Until recently, this concept has been limited to a focus on intrapersonal processes, such as suppression. Less emphasis has been placed on developmental, social, and cultural aspects of emotion regulation. We argue here that as social beings, our engagement in emotion regulation may often occur interpersonally, with trusted others helping us to regulate our emotions. This review will highlight recent research on interpersonal emotion regulation processes.Dr Hofmann receives financial support from the Alexander von Humboldt Foundation (as part of the Humboldt Prize), NIH/NCCIH (R01AT007257), NIH/NIMH (R01MH099021, U01MH108168), and the James S. McDonnell Foundation 21st Century Science Initiative in Understanding Human Cognition - Special Initiative. He receives compensation for his work as an advisor from the Palo Alto Health Sciences and for his work as a Subject Matter Expert from John Wiley & Sons, Inc. and SilverCloud Health, Inc. He also receives royalties and payments for his editorial work from various publishers. (Alexander von Humboldt Foundation; R01AT007257 - NIH/NCCIH; R01MH099021 - NIH/NIMH; U01MH108168 - NIH/NIMH; James S. McDonnell Foundation 21st Century Science Initiative in Understanding Human Cognition - Special Initiative)Accepted manuscrip

    Phase diagram of an extended quantum dimer model on the hexagonal lattice

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    We introduce a quantum dimer model on the hexagonal lattice that, in addition to the standard three-dimer kinetic and potential terms, includes a competing potential part counting dimer-free hexagons. The zero-temperature phase diagram is studied by means of quantum Monte Carlo simulations, supplemented by variational arguments. It reveals some new crystalline phases and a cascade of transitions with rapidly changing flux (tilt in the height language). We analyze perturbatively the vicinity of the Rokhsar-Kivelson point, showing that this model has the microscopic ingredients needed for the "devil's staircase" scenario [E. Fradkin et al., Phys. Rev. B 69, 224415 (2004)], and is therefore expected to produce fractal variations of the ground-state flux.Comment: Published version. 5 pages + 8 (Supplemental Material), 31 references, 10 color figure

    Realistic theory of electronic correlations in nanoscopic systems

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    Nanostructures with open shell transition metal or molecular constituents host often strong electronic correlations and are highly sensitive to atomistic material details. This tutorial review discusses method developments and applications of theoretical approaches for the realistic description of the electronic and magnetic properties of nanostructures with correlated electrons. First, the implementation of a flexible interface between density functional theory and a variant of dynamical mean field theory (DMFT) highly suitable for the simulation of complex correlated structures is explained and illustrated. On the DMFT side, this interface is largely based on recent developments of quantum Monte Carlo and exact diagonalization techniques allowing for efficient descriptions of general four fermion Coulomb interactions, reduced symmetries and spin-orbit coupling, which are explained here. With the examples of the Cr (001) surfaces, magnetic adatoms, and molecular systems it is shown how the interplay of Hubbard U and Hund's J determines charge and spin fluctuations and how these interactions drive different sorts of correlation effects in nanosystems. Non-local interactions and correlations present a particular challenge for the theory of low dimensional systems. We present our method developments addressing these two challenges, i.e., advancements of the dynamical vertex approximation and a combination of the constrained random phase approximation with continuum medium theories. We demonstrate how non-local interaction and correlation phenomena are controlled not only by dimensionality but also by coupling to the environment which is typically important for determining the physics of nanosystems.Comment: tutorial review submitted to EPJ-ST (scientific report of research unit FOR 1346); 14 figures, 26 page

    Scaling of the von Neumann entropy across a finite temperature phase transition

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    The spectrum of the reduced density matrix and the temperature dependence of the von Neumann entropy (VNE) are analytically obtained for a system of hard core bosons on a complete graph which exhibits a phase transition to a Bose-Einstein condensate at T=TcT=T_c. It is demonstrated that the VNE undergoes a crossover from purely logarithmic at T=0 to purely linear in block size nn behaviour for TTcT\geq T_{c}. For intermediate temperatures, VNE is a sum of two contributions which are identified as the classical (Gibbs) and the quantum (due to entanglement) parts of the von Neumann entropy.Comment: 4 pages, 2 figure

    Crystal lattice properties fully determine short-range interaction parameters for alkali and halide ions

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    Accurate models of alkali and halide ions in aqueous solution are necessary for computer simulations of a broad variety of systems. Previous efforts to develop ion force fields have generally focused on reproducing experimental measurements of aqueous solution properties such as hydration free energies and ion-water distribution functions. This dependency limits transferability of the resulting parameters because of the variety and known limitations of water models. We present a solvent-independent approach to calibrating ion parameters based exclusively on crystal lattice properties. Our procedure relies on minimization of lattice sums to calculate lattice energies and interionic distances instead of equilibrium ensemble simulations of dense fluids. The gain in computational efficiency enables simultaneous optimization of all parameters for Li+, Na+, K+, Rb+, Cs+, F-, Cl-, Br-, and I- subject to constraints that enforce consistency with periodic table trends. We demonstrate the method by presenting lattice-derived parameters for the primitive model and the Lennard-Jones model with Lorentz-Berthelot mixing rules. The resulting parameters successfully reproduce the lattice properties used to derive them and are free from the influence of any water model. To assess the transferability of the Lennard-Jones parameters to aqueous systems, we used them to estimate hydration free energies and found that the results were in quantitative agreement with experimentally measured values. These lattice-derived parameters are applicable in simulations where coupling of ion parameters to a particular solvent model is undesirable. The simplicity and low computational demands of the calibration procedure make it suitable for parametrization of crystallizable ions in a variety of force fields.Comment: 9 pages, 5 table

    Early Growth and Efficient Accretion of Massive Black Holes at High Redshift

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    Black-hole masses of the highest redshift quasars (4 <~ z <~ 6) are estimated using a previously presented scaling relationship, derived from reverberation mapping of nearby quasars, and compared to quasars at lower redshift. It is shown that the central black holes in luminous z >~ 4 quasars are very massive (>~ 10^9 solar masses). It is argued that the mass estimates of the high-z quasars are not subject to larger uncertainties than those for nearby quasars. Specifically, the large masses are not overestimates and the lack of similarly large black-hole masses in the nearby Universe does not rule out their existence at high-z. However, AGN host galaxies do not typically appear fully formed or evolved at these early epochs. This supports scenarios in which black holes build up mass very fast in a radiatively inefficient (or obscured) phase relative to the stars in their galaxies. Additionally, upper envelopes of black-hole mass of approximately 10^{10} solar masses and bolometric luminosity of ~ 10^{48} erg/s are observed at all redshifts.Comment: 17 pages including 7 figures (5 in color) and 1 table. To appear in ApJ, v600, January 1, 200

    On the evolutionary behaviour of BL Lac objects

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    We present a new well defined sample of BL Lac objects selected from the ROSAT All-Sky Survey (RASS). The sample consists of 39 objects with 35 forming a flux limited sample down to f_X = 8 x 10^{-13} cgs, redshifts are known for 33 objects (and 31 of the complete sample). X-ray spectral properties were determined for each object individually with the RASS data. The luminosity function of RASS selected BL Lac objects is compatible with results provided by objects selected with the Einstein observatory, but the RASS selected sample contains objects with luminosities at least tenfold higher. Our analysis confirms the negative evolution for X-ray selected BL Lac objects found in a sample by the Einstein observatory, the parameterization provides similar results. A subdivision of the sample into halves according to the X-ray to optical flux ratio yielded unexpected results. The extremely X-ray dominated objects have higher redshifts and X-ray luminosities and only this subgroup shows clear signs of strong negative evolution. The evolutionary behaviour of objects with an intermediate spectral energy distribution between X-ray and radio dominated is compatible with no evolution at all. Consequences for unified schemes of X-ray and radio selected BL Lac objects are discussed.We suggest that the intermediate BL Lac objects are the basic BL Lac population. The distinction between the two subgroups can be explained if extreme X-ray dominated BL Lac objects are observed in a state of enhanced X-ray activity.Comment: 14 pages incl. 8 figures, accepted by A&

    Many-body effects on Cr(001) surfaces: An LDA+DMFT study

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    The electronic structure of the Cr(001) surface with its sharp resonance at the Fermi level is a subject of controversial debate of many experimental and theoretical works. To date, it is unclear whether the origin of this resonance is an orbital Kondo or an electron-phonon coupling effect. We have combined ab initio density functional calculations with dynamical mean-field simulations to calculate the orbitally resolved spectral function of the Cr(001) surface. The calculated orbital character and shape of the spectrum is in agreement with data from (inverse) photoemission experiments. We find that dynamic electron correlations crucially influence the surface electronic structure and lead to a low energy resonance in the dz2d_{z^2} and dxz/yzd_{xz/yz} orbitals. Our results help to reconvene controversial experimental results from (I)PES and STM measurements.Comment: 8 pages, 5 figure
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