Measurements of I/SVOCs in biomass-burning smoke using solid-phase extraction disks and two-dimensional gas chromatography

Biomass-burning organic-aerosol (OA) emissions are known to exhibit semi-volatile behavior that impacts OA loading during plume transport. Because such semi-volatile behavior depends in part on OA composition, improved speciation of intermediate and semi-volatile organic compounds (I/SVOCs) emitted during fires is needed to assess the competing effects of primary OA volatilization and secondary OA production. In this study, 18 laboratory fires were sampled in which a range of fuel types were burned. Emitted I/SVOCs were collected onto Teflon filters and solid-phase extraction (SPE) disks to qualitatively characterize particulate and gaseous I/SVOCs, respectively. Derivatized filter extracts were analyzed using comprehensive two-dimensional gas chromatography with time-of-flight mass spectrometry (GC×GC-TOFMS). Quality control tests were performed using biomass-burning relevant standards and demonstrate the utility of SPE disks for untargeted analysis of air samples. The observed chromatographic profiles of I/SVOCs in coniferous fuel-derived smoke samples were well correlated with each other, but poorly correlated with other fuel types (e.g., herbaceous and chaparral fuels). Emissions of benzenediol isomers were also shown to be fuel dependent. The combined Teflon and SPE filter data captured differences in gas-particle partitioning of the benzenediol isomers, with hydroquinone having a significantly higher particle-phase fraction than catechol due to its lower volatility. Additionally, the speciated volatility distribution of I/SVOCs in smoke from a rotten-log fire was estimated to evaluate the composition of potentially volatilized primary OA, which was entirely attributed to oxygenated (or other heteroatomic) compounds. The isomer-dependent partitioning and the speciated volatility distributions both suggest the need for better understanding of gas-phase and heterogenous reaction pathways of biomass-burning-derived I/SVOCs in order to represent the atmospheric chemistry of smoke in models

Interaction-range effects and universality in the BCS-BEC crossover of spin-orbit-coupled Fermi gases

We explore the evolution of an ultracold quantum gas of interacting fermions crossing from a Bardeen-Cooper-Schrieffer (BCS) superfluidity to a Bose-Einstein condensation (BEC) of molecular bosons in the presence of a tunable-range interaction among the fermions and of an artificial magnetic field, which can be used to simulate a pseudo-spin-orbit coupling (SOC) and to produce topological states. We find that the crossover is affected by a competition between the finite range of the interaction and the SOC and that the threshold λB for the topological transition is affected by the interactions only in the small pair size, BEC-like, regime. Below λB, we find persistence of universal behavior in the critical temperature, chemical potential, and condensate fraction, provided that the pair correlation length is used as a driving parameter. Above threshold, universality is lost in the regime of large pair sizes. Here, the limiting ground state departs from a weakly interacting BCS-like one so that a different description is required. Our results can be relevant in view of current experiments with cold atoms in optical cavities, where tunable-range effective atomic interactions can be engineered

Random error propagation and uncertainty analysis in the dynamic characterization of Tilting Pad Journal Bearings

In this work a new statistical method for the determination of the dynamic coefficients of Tilting Pad Journal Bearings is described. The method is applied to the results obtained testing a 5 pads tilting pad journal bearing with 280 mm diameter. Tests were performed on an advanced experimental apparatus specifically realized for investigations on large size high performance bearings for turbomachinery. The linear coefficient identification procedure is based on the dynamic measurement of forces, accelerations and relative displacements of rotor and bearing, as function of excitation frequency for different operating conditions. The post-processing of the dynamic data is performed in the frequency domain using the Fast Fourier Transform. Along with a description of the experimental test and identification procedure, this paper presents a least-square minimization technique for determining the dynamic coefficients and a bootstrap statistical technique for estimating their confidence intervals

3D Reality-Based Survey and Retopology for Structural Analysis of Cultural Heritage

Cultural heritage’s structural changes and damages can influence the mechanical behaviour of artefacts and buildings. The use of finite element methods (FEM) for mechanical analysis is largely used in modelling stress behaviour. The workflow involves the use of CAD 3D models and the use of non-uniform rational B-spline (NURBS) surfaces. For cultural heritage objects, altered by the time elapsed since their creation, the representation created with the CAD model may introduce an extreme level of approximation, leading to wrong simulation results. The focus of this work is to present an alternative method intending to generate the most accurate 3D representation of a real artefact from highly accurate 3D reality-based models, simplifying the original models to make them suitable for finite element analysis (FEA) software. The approach proposed, and tested on three different case studies, was based on the intelligent use of retopology procedures to create a simplified model to be converted to a mathematical one made by NURBS surfaces, which is also suitable for being processed by volumetric meshes typically embedded in standard FEM packages. This allowed us to obtain FEA results that were closer to the actual mechanical behaviour of the analysed heritage asset

The stochastic quantization method and its application to the numerical simulation of volcanic conduit dynamics under random conditions

Stochastic Quantization (SQ) is a method for the approximation of a continuous probability distribution with a discrete one. The proposal made in this paper is to apply this technique to reduce the number of numerical simulations for systems with uncertain inputs, when estimates of the output distribution are needed. This question is relevant in volcanology, where realistic simulations are very expensive and uncertainty is always present. We show the results of a benchmark test based on a one-dimensional steady model of magma flow in a volcanic conduit

Seasonal rainfall trends of a key Mediterranean area in relation to large-scale atmospheric circulation: How does current global change affect the rainfall regime?

Current global warming causes a change in atmospheric dynamics, with consequent variations in the rainfall regimes. Understanding the relationship between global climate patterns, global warming, and rainfall regimes is crucial for the creation of future scenarios and for the relative modification of water management. The aim of this study is to improve knowledge of the relationship between North Atlantic Oscillation (NAO), East Atlantic (EA), and Western Mediterranean Oscillation (WeMO) with the seasonal rainfalls in Tuscany, Italy. The study area occupies a strategic position since it lies in a transition zone between the wet area of northern Europe and the dry area of the northern coast of Africa. This research, based on a statistical correlation method and on linear models, is designed to understand the relationship between seasonal rainfalls and climate patterns. The results of this study demonstrate that the use of linear models can yield more information than traditional statistical corre-lations. The results show a decrease in rainfall in the warm period of the year, namely in the summer, when its expression is most visible. This phenomenon is ascribable to current global warming, which causes an increase in sea-surface temperatures. An increase in the Northern Atlantic Sea Surface Temperature and in the Mediterra-nean Sea Surface Temperature causes a reduction of the Iceland Low, with an extension of the Azores High. Moreover, an increase in the Genoa Gulf SST induces a weakening of the Genoa Gulf Low, one of the main cyclogenetic systems of the Mediterranean

error analysis in the determination of the dynamic coefficients of tilting pad journal bearings

n/

Integral method coefficients for the ring-core technique to evaluate non-uniform residual stresses

The ring-core technique allows for the determination of non-uniform residual stresses from the surface up to relatively higher depths as compared to the hole-drilling technique. The integral method, which is usually applied to hole-drilling, can also be used for elaborating the results of the ring-core test since these two experimental techniques share the axisymmetric geometry and the 0°–45°–90° layout of the strain gage rosette. The aim of this article is to provide accurate coefficients which can be used for evaluating the residual stress distribution by the ring-core integral method. The coefficients have been obtained by elaborating the results of a very refined plane harmonic axisymmetric finite element model and verified with an independent three-dimensional model. The coefficients for small depth steps were initially provided, and then the values for multiple integer step depths were also derived by manipulating the high-resolution coefficient matrices, thus showing how the present results can be practically used for obtaining the residual stresses according to different depth sequences, even non-uniform. This analysis also allowed the evaluation of the eccentricity effect which turned out to be negligible due to the symmetry of the problem. An applicative example was reported in which the input of the experimentally measured relaxed strains was elaborated with different depth resolutions, and the obtained residual stress distributions were compared

experimental study of hydrogen embrittlement in maraging steels

Abstract This research activity aims at investigating the hydrogen embrittlement of Maraging steels in connection to real sudden failures of some of the suspension blades of the Virgo Project experimental apparatus. Some of them failed after 15 years of service in working conditions. Typically, in the Virgo detector, blades are loaded up to 50-60% of the material yield strength. For a deeper understanding of the failure, the relationship between hydrogen concentration and mechanical properties of the material, have been investigated with specimens prepared in order to simulate blade working conditions. A mechanical characterization of the material has been carried out by standard tensile testing in order to establish the effect of hydrogen content on the material strength. Further experimental activity was executed in order to characterize the fracture surface and to measure the hydrogen content. Finally, some of the failed blades have been analyzed in DICI-UNIPI laboratory. The experimental results show that the blades failure can be related with the hydrogen embrittlement phenomenon