FACILE FUNCTIONALIZATION OF sp2 CARBON ALLOTROPES WITH A BIOBASED JANUS MOLECULE

A simple, versatile, sustainable, not expensive method for the functionalization of sp2 carbon allotropes, both nanosized and nano-structured, without altering their bulk crystalline organization, is presented. Carbon materials available at the commercial scale were used: furnace carbon black (CB), nano-sized graphite with high surface area, and multiwalled carbon nanotubes. A bio-sourced molecule, 2-(2,5-dimethyl-1H-pyrrol-1-yl)-1,3-propanediol (serinol pyrrole), was used for the functionalization. Serinol pyrrole (SP) was obtained from serinol through a reaction with atomic efficiency of about 82%, performed in the absence of solvents or catalysts. Synthesis of serinol pyrrole was performed as well on carbon allotropes as the solid support. Adducts of serinol pyrrole with a carbon allotrope were prepared with the help of either thermal or mechanical energy. Functionalization yield was in all cases larger than 90%. With such adducts, stable dispersions in water and inNRlatex were prepared.Afew layers of graphene were isolated from the water dispersions, and NR-based composites precipitated from the latex revealed very even distribution of fine graphitic particles. Composites were prepared, based on NR, IR, andBRas the rubbers andCBand silica as the fillers, with different amounts of CB–SPadduct, and were cross-linked with a sulfur-based system without observing appreciable effect of functionalization on vulcanization kinetics. The CB–SP adduct led to appreciable reduction of the Payne effect

SAPIENT-Simulator Modelling and Architecture

Future aeronautical communications will be based on the TCP/IP protocol stack, and will occur through a number of different data-link channels (e.g., satellite, terrestrial), with multipath capabilities – the so-called multilink. Seamless vertical handover between different data-links is a requirement and it will improve the safety and reliability of AEROCOM systems, possibly enabling remote-piloted aircrafts (RPAs) for civil operations. This paper describes the modelling, design and implementation of an AEROCOM system simulator based on OMNeT++, developed in the framework of the SAPIENT EU project. The simulator includes models of the aircrafts, including their mobility, terrestrial and satellite data links and core network. Moreover, it includes a solution to simulate the effect of multilink capabilities, which enables one to test multilink decision policies

Valori Etici e Principio di Maggioranza

Una versione, in parte diversa, di questo scritto è stata anticipata sulla Rivista “Atlantide, n.3 del 2005

Valori etici e principio di maggioranza

Raramente i temi eticamente sensibili (quali la vita, la morte, l'eutanasia, testamento biologico) trovano spazio nei classici recinti del diritto costituzionale e solo da qualche anno appaiono qua e là introdotti da dichiarazioni internazionali o da caute decisioni della Corte europea dei diritti e di altre Corti internazionali. Non infrequente è l’assunzione di questi temi nell’ambito del diritto costituzionale attraverso un’attività interpretativa evolutiva delle vigenti norme costituzional

Open Science - Challenges and best practices: a view from research institutes in Italy

Talk given by Stefano Bianco at MINERVA Study Visit 2021.05. organised online by Universita' Marconi Roma

Open Science for Fair and Sustainable Access to Knowledge

Talk given at SISSA Trieste

Plan S - FAQ's

A report on Plan S and the cOAlition S collaboration, with particular focus on the role of repositories and green OA

Master curves for the sulphur assisted crosslinking reaction of natural rubber in the presence of nano- and nano-structured sp2 carbon allotropes

In this paper, master curves are reported for the crosslinking of a diene rubber with a sulphur based system in the presence of either nano- or nano-structured carbon allotropes, such as carbon nanotubes (CNT), a nanosized graphite with high surface area (HSAG) and carbon black (CB). Poly(1,4-cis-isoprene) from Hevea Brasiliensis was the diene rubber and crosslinking was performed in temperatures ranging from 151 to 180°C, with carbon allotropes below and above their percolation threshold. Such carbon allotropes were characterized by different aspect ratio, surface area and pH. However, in the crosslinking reaction, they revealed common behaviour. In fact, the specific interfacial area could be used to correlate crosslinking parameters, such as induction time (ts1) and activation energy (Ea) calculated by applying the autocatalytic model. Monotonous decrease of ts1 and increase of Ea were observed, with points lying on master curves, regardless of the nature of the carbon allotropes. Remarkable differences were however observed in the structure of the crosslinking network: when the carbon allotrope was above the percolation threshold much larger crosslinking density was obtained in the presence of CNT whereas composites based on HSAG became soluble in hydrocarbon solvent, after the reaction with a thiol. Proposed explanation of these results is based on the reactivity of carbon allotropes with sulphur and sulphur based compounds, demonstrated through the reaction of 1-dodecanethiol and sulphur with CNT and HSAG and with a model substrate such as anthracene

Fact-Checking at Scale with Crowdsourcing: Experiments and Lessons Learned

In this paper, we present our journey in exploring the use of crowdsourcing for fact-checking. We discuss our early experiments aimed towards the identification of the best possible setting for misinformation assessment using crowdsourcing. Our results indicate that the crowd can effectively address misinformation at scale, showing some degree of correlation with experts. We also highlight the influence of worker background on the quality of truthfulness assessments