Automatization of TDS data evaluation

Tato práce se zabývá automatizací vyhodnocování dat termální desorpční spektroskopie (TDS). Teoretická část pojednává o procesích adsorpce a desorpce atomů a molekul a teplotní závislosti desorpce. Součástí práce je také kvantitativní analýza signálu měřícího přístroje. Hlavním cílem praktické části bylo vytvoření počítačového programu na automatizaci vyhodnocování dat TDS. Popis programu a uživatelská příručka jsou také součástí práce. Proběhlo testování programu na předchozích měření a kinetické parametry desorpce byly zjištěny u několika vzorků.This bachelor thesis is focused on automatization of post-processing and evaluation of thermal desorption spectroscopy (TDS) data. The theoretical part discusses the processes of adsorption and desorption of atoms and molecules on surfaces and the thermal dependence of the latter. This work also provides a quantitative analysis of the measured signal from the instrument. The main objective of the practical part is to create a computer tool for automatization of TDS data evaluation. Description of the program, as well as a user guide, is included in the work. Comprehensive tests of the created program were concluded on previously measured TDS spectra and the kinetic parameters of several samples were determined.

Hydrodynamic Nambu Brackets derived by Geometric Constraints

A geometric approach to derive the Nambu brackets for ideal two-dimensional (2D) hydrodynamics is suggested. The derivation is based on two-forms with vanishing integrals in a periodic domain, and with resulting dynamics constrained by an orthogonality condition. As a result, 2D hydrodynamics with vorticity as dynamic variable emerges as a generic model, with conservation laws which can be interpreted as enstrophy and energy functionals. Generalized forms like surface quasi-geostrophy and fractional Poisson equations for the stream-function are also included as results from the derivation. The formalism is extended to a hydrodynamic system coupled to a second degree of freedom, with the Rayleigh-B\'{e}nard convection as an example. This system is reformulated in terms of constitutive conservation laws with two additive brackets which represent individual processes: a first representing inviscid 2D hydrodynamics, and a second representing the coupling between hydrodynamics and thermodynamics. The results can be used for the formulation of conservative numerical algorithms that can be employed, for example, for the study of fronts and singularities.Comment: 12 page

Construction of Hamiltonian and Nambu forms for the shallow water equations

A systematic method to derive the Hamiltonian and Nambu form for the shallow water equations, using the conservation for energy and potential enstrophy, is presented. Different mechanisms, such as vortical flows and emission of gravity waves, emerge from different conservation laws (CLs) for total energy and potential enstrophy. The equations are constructed using exterior differential forms and self-adjoint operators and result in the sum of two Nambu brackets, one for the vortical flow and one for the wave-mean flow interaction, and a Poisson bracket representing the interaction between divergence and geostrophic imbalance. The advantage of this approach is that the Hamiltonian and Nambu forms can be here written in a coordinate independent form

Hyperbolic Covariant Coherent Structures in two dimensional flows

A new method to describe hyperbolic patterns in two dimensional flows is proposed. The method is based on the Covariant Lyapunov Vectors (CLVs), which have the properties to be covariant with the dynamics, and thus being mapped by the tangent linear operator into another CLVs basis, they are norm independent, invariant under time reversal and can be not orthonormal. CLVs can thus give a more detailed information on the expansion and contraction directions of the flow than the Lyapunov Vector bases, that are instead always orthogonal. We suggest a definition of Hyperbolic Covariant Coherent Structures (HCCSs), that can be defined on the scalar field representing the angle between the CLVs. HCCSs can be defined for every time instant and could be useful to understand the long term behaviour of particle tracers. We consider three examples: a simple autonomous Hamiltonian system, as well as the non-autonomous "double gyre" and Bickley jet, to see how well the angle is able to describe particular patterns and barriers. We compare the results from the HCCSs with other coherent patterns defined on finite time by the Finite Time Lyapunov Exponents (FTLEs), to see how the behaviour of these structures change asymptotically

Nonlinear stratospheric variability: multifractal detrended fluctuation analysis and singularity spectra

Characterising the stratosphere as a turbulent system, temporal fluctuations often show different correlations for different time scales as well as intermittent behaviour that cannot be captured by a single scaling exponent. In this study, the different scaling laws in the long term stratospheric variability are studied using Multifractal de-trended Fluctuation Analysis. The analysis is performed comparing four re-analysis products and different realisations of an idealised numerical model, isolating the role of topographic forcing and seasonal variability, as well as the absence of climate teleconnections and small-scale forcing. The Northern Hemisphere (NH) shows a transition of scaling exponents for time scales shorter than about one year, for which the variability is multifractal and scales in time with a power law corresponding to a red spectrum, to longer time scales, for which the variability is monofractal and scales in time with a power law corresponding to white noise. Southern Hemisphere (SH) variability also shows a transition at annual scales. The SH also shows a narrower dynamical range in multifractality than the NH, as seen in the generalised Hurst exponent and in the singularity spectra. The numerical integrations show that the models are able to reproduce the low-frequency variability but are not able to fully capture the shorter term variability of the stratosphere