6 research outputs found

    Assessing exposure in epidemiologic studies to disinfection by-products in drinking water: report from an international workshop.

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    The inability to accurately assess exposure has been one of the major shortcomings of epidemiologic studies of disinfection by-products (DBPs) in drinking water. A number of contributing factors include a) limited information on the identity, occurrence, toxicity, and pharmacokinetics of the many DBPs that can be formed from chlorine, chloramine, ozone, and chlorine dioxide disinfection; b) the complex chemical interrelationships between DBPs and other parameters within a municipal water distribution system; and c) difficulties obtaining accurate and reliable information on personal activity and water consumption patterns. In May 2000, an international workshop was held to bring together various disciplines to develop better approaches for measuring DBP exposure for epidemiologic studies. The workshop reached consensus about the clear need to involve relevant disciplines (e.g., chemists, engineers, toxicologists, biostatisticians and epidemiologists) as partners in developing epidemiologic studies of DBPs in drinking water. The workshop concluded that greater collaboration of epidemiologists with water utilities and regulators should be encouraged in order to make regulatory monitoring data more useful for epidemiologic studies. Similarly, exposure classification categories in epidemiologic studies should be chosen to make results useful for regulatory or policy decision making

    Implications of Using On-Farm Flood Flow Capture To Recharge Groundwater and Mitigate Flood Risks Along the Kings River, CA

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    The agriculturally productive San Joaquin Valley faces two severe hydrologic issues: persistent groundwater overdraft and flooding risks. Capturing flood flows for groundwater recharge could help address both of these issues, yet flood flow frequency, duration, and magnitude vary greatly as upstream reservoir releases are affected by snowpack, precipitation type, reservoir volume, and flood risks. This variability makes dedicated, engineered recharge approaches expensive. Our work evaluates leveraging private farmlands in the Kings River Basin to capture flood flows for direct and <i>in lieu</i> recharge, calculates on-farm infiltration rates, assesses logistics, and considers potential water quality issues. The Natural Resources Conservation Service (NRCS) soil series suggested that a cementing layer would hinder recharge. The standard practice of deep ripping fractured the layer, resulting in infiltration rates averaging 2.5 in d<sup>–1</sup> (6 cm d<sup>–1</sup>) throughout the farm. Based on these rates 10 acres are needed to infiltrate 1 cfs (100 m<sup>3</sup> h<sup>–1</sup>) of flood flows. Our conceptual model predicts that salinity and nitrate pulses flush initially to the groundwater but that groundwater quality improves in the long term due to pristine flood flows low in salts or nitrate. Flood flow capture, when integrated with irrigation, is more cost-effective than groundwater pumping

    Experimental Dosing of Wetlands with Coagulants Removes Mercury from Surface Water and Decreases Mercury Bioaccumulation in Fish

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    Mercury pollution is widespread globally, and strategies for managing mercury contamination in aquatic environments are necessary. We tested whether coagulation with metal-based salts could remove mercury from wetland surface waters and decrease mercury bioaccumulation in fish. In a complete randomized block design, we constructed nine experimental wetlands in California’s Sacramento–San Joaquin Delta, stocked them with mosquitofish (Gambusia affinis), and then continuously applied agricultural drainage water that was either untreated (control), or treated with polyaluminum chloride or ferric sulfate coagulants. Total mercury and methylmercury concentrations in surface waters were decreased by 62% and 63% in polyaluminum chloride treated wetlands and 50% and 76% in ferric sulfate treated wetlands compared to control wetlands. Specifically, following coagulation, mercury was transferred from the filtered fraction of water into the particulate fraction of water which then settled within the wetland. Mosquitofish mercury concentrations were decreased by 35% in ferric sulfate treated wetlands compared to control wetlands. There was no reduction in mosquitofish mercury concentrations within the polyaluminum chloride treated wetlands, which may have been caused by production of bioavailable methylmercury within those wetlands. Coagulation may be an effective management strategy for reducing mercury contamination within wetlands, but further studies should explore potential effects on wetland ecosystems
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