Data management study. Appendix Q - Contractor data requirements advanced missions /AM/ Final report

Contractor data requirements relating to advanced missions and potential follow-up programs of Voyager projec

Data management study. Appendix M - Contractor data requirements safety /SA/ FINAL report

Contractor data requirements to insure safety of personnel, facilities, and equipment of Voyager operation

How A Refocused CRP Could Be Administered In Minnesota

Reinvest In Minnesota (RIM) Reserve and Permanent Wetland Preserves (PWP) are state conservation easement programs designed to keep certain marginal agricultural land, including drained restorable wetlands, and existing types 1, 2, 3, or 6 wetlands out of crop production to protect soil and water quality and enhance fish and wildlife habitat. The Minnesota Board of Water and Soil Resources (BWSR) suggests an alternative approach to administering a refocused Conservation Reserve (CRP) and the new Wetland Reserve Programs (WRP), in Minnesota. BWSR could enter into a delegation agreement with the U. S. Department of Agriculture to transfer easement acquisition, practice establishment, and necessary administrative funding through BWSR to local soil and water conservation districts (SWCDs). This presentation will outline how this arrangement could successfully administer a federally delegated program through the state and local SWCDs to participating landowners. Benefits of this arrangement will also be discussed

The Effect of Clamping Pressure and Orthotropic Wood Structure on Strength of Glued Bonds

Reference values for compression strength perpendicular to the grain were determined for radial and tangential sections of samples of sugar maple and ponderosa pine. Samples to be glued were matched according to specific gravity and orthotropic structure and bonded along the grain in tangential or radial sections. Magnitude of clamp pressure was controlled throughout a range of pressures commonly applied in industry, up to about 80% of the compression strength of the wood sample. Tests were conducted on the bonded samples to determine glueline shear strength and percent of wood failure at the bonded surfaces. Results were subjected to regression analysis to ascertain relationships. It was determined that clamping pressure had a different effect on both shear strength and percent of wood failure depending on species and orthotropic section. It is possible to maximize joint strength by applying proper clamping pressure. Results similar in direction but differing in magnitude were obtained with both PVAc and U-F adhesives. A generalized measure of clamping pressure was defined as the ratio of applied clamping pressure to the compression strength (CP/CS) of the wood section to be glued. Using this concept, the optimum clamping pressure for sugar maple was found to be 0.3 times compression strength using U-F glue and 0.5 times using PVAc glue. This approach to determining reliable clamping pressure data can lead to improved gluing practice and more precise testing procedures

Data management study. Appendix O - Contractor data requirements science integration /SI/ Final report

Contractor data requirements for integration of scientific experiments aboard Voyager spacecraf

The role of reactive reaction intermediates in two-step heterogeneous electro-catalytic reactions: a model study

Experimental investigations of heterogeneous electrocatalytic reactions have been performed in flow cells which provide an environment with controlled parameters. Measurements of the oxygen reduction reaction in a flow cell with an electrode consisting of an array of Pt nanodisks on a glassy carbon substrate exhibited a decreasing fraction of the intermediate $H_2O_2$ in the overall reaction products with increasing density of the nanodiscs. A similar result is true for the dependence on the catalyst loading in the case of a supported Pt/C catalyst thin-film electrode, where the fraction of the intermediate decreases with increasing catalyst loading. Similar effects have been detected for the methanol oxidation. We present a model of multistep heterogeneous electrocatalytic oxidation and reduction reactions based on an adsorption-reaction-desorption scheme using the Langmuir assumption and macroscopic transport equations. A continuum based model problem in a vertical cross section of a rectangular flow cell is proposed in order to explain basic principles of the experimental situation. It includes three model species A, B, C, which undergo adsorption and desorption at a catalyst surface, as well as adsorbate reactions from A to B to C. These surface reactions are coupled with diffusion and advection in the Hagen Poiseuille flow in the flow chamber of the cell. Both high velocity asymptotic theory and a finite volume numerical are used to obtain approximate solutions to the model. Both approaches show a behaviour similar to the experimentally observed. Working in more general situations, the finite volume scheme was applied to a catalyst layer consisting of a number of small catalytically active areas corresponding to nanodisks. Good qualitative agreement with the experimental findings was established for this case as well

Interaction of oxygen with Al(111) at elevated temperatures

The interaction of oxygen with Al(111) was investigated by STM at temperatures between 350 and 530 K, by annealing an oxygen precovered surface and by adsorption of oxygen on the hot surface. For exposures up to 10 L and temperatures up to 470 K a considerable part of the oxygen exists still in the chemisorbed state, another part transforms into Al oxide. In contrast to 300 K chemisorbed Oad atoms are mobile at elevated temperatures, and compact, hexagonal (1×1)Oad islands develop by an ordinary nucleation and growth scheme. This evidences attractive interactions between the oxygen atoms on (1×1) sites. From the lateral distribution of Oad islands a diffusion barrier of 1.0–1.1 eV is derived. The imaging of the islands of the (1×1) phase by STM depends on their size, which is understood by a different imaging of the Oad/Al adsorbate complexes at the island borders. Defects in the islands and bright features at the edges are interpreted as nuclei of aluminum oxide. Additional features which appear as topographic holes may be attributed to nonconducting Al oxide grains

Interaction of ionic liquids with noble metal surfaces: Structure formation and stability of [OMIM][TFSA] and [EMIM][TFSA] on Au(111) and Ag(111)

Principles of structure formation and adsorbate–adsorbate interactions in ionic liquid adlayers on metal surfaces were investigated in a comparative STM study on Ag(111) and Au(111) surfaces.</p

Metal–organic framework derived Fe7S8 nanoparticles embedded in heteroatom-doped carbon with Lithium and Sodium storage capability

Iron sulfides are promising materials for lithium- and sodium-ion batteries owing to their high theoretical capacity and widespread abundance. Herein, the performance of an iron sulfide-carbon composite, synthesized from a Fe-based metal–organic framework (Fe-MIL-88NH2) is reported. The material is composed of ultrafine Fe7S8 nanoparticles (&lt;10&nbsp;nm in diameter) embedded in a heteroatom (N,&nbsp;S, and O)-doped carbonaceous framework (Fe7S8@HD-C), and is obtained via a simple and efficient one-step sulfidation process. The Fe7S8@HD-C composite, investigated in diethylene glycol dimethyl ether-based electrolytes as anode material for lithium and sodium batteries, shows high reversible capacities (930&nbsp;mAh&nbsp;g−1 for lithium and 675&nbsp;mAh&nbsp;g−1 for sodium at 0.1&nbsp;A&nbsp;g−1). In situ X-ray diffraction reveals an insertion reaction to occur in the first lithiation and sodiation steps, followed by conversion reactions. The composite electrodes show rather promising long-term cycling stability and rate capability for sodium storage in glyme electrolyte, while an improved rate capacity and long-term cycling stability (800&nbsp;mAh&nbsp;g−1 after 300 cycles at 1&nbsp;A&nbsp;g−1) for lithium can be achieved using conventional carbonates

Atomistic modeling of the directed-assembly of bimetallic Pt-Ru nanoclusters on Ru(0001)-supported monolayer graphene

The formation of Pt-Ru nanoclusters (NCs) by sequential deposition of Pt and Ru on a periodically rumpled graphene sheet supported on Ru(0001) is analyzed by atomistic-level modeling and kinetic Monte Carlo simulations. The “coarse-scale” periodic variation of the adsorption energy of metal adatoms across the graphene sheet directs the assembly of NCs to a periodic array of thermodynamically preferred locations. The modeling describes not only just the NC densities and size distributions, but also the composition distribution for mixed NCs. A strong dependence of these quantities on the deposition order is primarily related to different effective mobilities of Pt and Ru on the supported graphene