Metal-Oxo Photo-oxidants, Photochemistry and Photophysics of trans-[Os^(VI)(tmc)(O)_2]^(2+)(tmc = 1,4,8,11-tetramethyl-1,4,8,11-tetra-azacyclotetradecane) and trans-[Os^(VI)(CN)_4(O)_2]^(2-)

trans-[Os^(VI)(tmc)(O)_2]^(2+)(tmc = 1,4,8,11-tetramethyl-1,4,8,11-tetra-azacyclotetradecane) and trans-[Os^(VI)(CN)_4(O)_2]^(2-) are emissive in the solid state and in fluid solutions at room temperature (τ~ 1.0–1.5 µs); the (^3)E_g state of trans-[Os^(VI)(tmc)(O)_2]^(2+) is a powerful one-electron oxidant {[Os^(VI)(O)_2]^(2+) + e^– → [Os^V (O)_2]+, E^0_f > 2.0 V vs. normal hydrogen electrode} in aqueous solution, reacting with PPh3 and ((PhCH_2)_2)S to give O=PPh_3 and ((PhCH_2)_2)S=O, respectively

Preliminary Results from the Caltech Core-Collapse Project (CCCP)

We present preliminary results from the Caltech Core-Collapse Project (CCCP), a large observational program focused on the study of core-collapse SNe. Uniform, high-quality NIR and optical photometry and multi-epoch optical spectroscopy have been obtained using the 200'' Hale and robotic 60'' telescopes at Palomar, for a sample of 50 nearby core-collapse SNe. The combination of both well-sampled optical light curves and multi-epoch spectroscopy will enable spectroscopically and photometrically based subtype definitions to be disentangled from each other. Multi-epoch spectroscopy is crucial to identify transition events that evolve among subtypes with time. The CCCP SN sample includes every core-collapse SN discovered between July 2004 and September 2005 that was visible from Palomar, found shortly (< 30 days) after explosion (based on available pre-explosion photometry), and closer than ~120 Mpc. This complete sample allows, for the first time, a study of core-collapse SNe as a population, rather than as individual events. Here, we present the full CCCP SN sample and show exemplary data collected. We analyze available data for the first ~1/3 of the sample and determine the subtypes of 13 SNe II based on both light curve shapes and spectroscopy. We discuss the relative SN II subtype fractions in the context of associating SN subtypes with specific progenitor stars.Comment: To appear in the proceedings of the meeting "The Multicoloured Landscape of Compact Objects and their Explosive Origins", Cefalu, Italy, June 2006, to be published by AIP, Eds. L. Burderi et a

Orphan GRB radio afterglows: Candidates and constraints on beaming

The number of orphan radio afterglows associated with gamma-ray bursts (GRBs) that should be detected by a flux limited radio survey, is calculated. It is shown that for jetted GRBs this number is smaller for smaller jet opening angle (theta), contrary to naive expectation. For a beaming factor f_b^{-1}=(theta^2/2)^{-1} = 500, roughly the value inferred by Frail et al. (2001) from analysis of afterglow light curves, we predict that between several hundreds to several thousands orphan radio afterglows should be detectable (over all sky) above 1 mJy at GHz frequencies at any given time. This orphan population is dominated by sources lying at distances of a few hundred Mpc, and having an age of ~1 yr. A search for point-like radio transients with flux densities greater than 6 mJy was conducted using the FIRST and NVSS surveys, yielding a list of 25 orphan candidates. We argue that most of the candidates are unlikely to be radio supernovae. However, the possibility that they are radio loud AGNs cannot be ruled out without further observations. Our analysis sets an upper limit for the all sky number of radio orphans, which corresponds to a lower limit f_b^{-1}>10 on the beaming factor. Rejection of all candidates found in our search would imply f_b^{-1}>100. This, and the fact that some candidates may indeed be radio afterglows, strongly motivate further observations of these transients.Comment: 18 pages, including 2 figure

Caltech Core-Collapse Project (CCCP) observations of type IIn supernovae: typical properties and implications for their progenitor stars

Type IIn Supernovae (SNe IIn) are rare events, constituting only a few percent of all core-collapse SNe, and the current sample of well observed SNe IIn is small. Here, we study the four SNe IIn observed by the Caltech Core-Collapse Project (CCCP). The CCCP SN sample is unbiased to the extent that object selection was not influenced by target SN properties. Therefore, these events are representative of the observed population of SNe IIn. We find that a narrow P-Cygni profile in the hydrogen Balmer lines appears to be a ubiquitous feature of SNe IIn. Our light curves show a relatively long rise time (>20 days) followed by a slow decline stage (0.01 to 0.15 mag/day), and a typical V-band peak magnitude of M_V=-18.4 +/- 1.0 mag. We measure the progenitor star wind velocities (600 - 1400 km/s) for the SNe in our sample and derive pre-explosion mass loss rates (0.026 - 0.12 solar masses per year). We compile similar data for SNe IIn from the literature, and discuss our results in the context of this larger sample. Our results indicate that typical SNe IIn arise from progenitor stars that undergo LBV-like mass-loss shortly before they explode.Comment: ApJ, submitte

SN2007ax : An Extremely Faint Type Ia Supernova

We present multi-band photometric and optical spectroscopic observations of SN2007ax, the faintest and reddest Type Ia supernova (SNIa) yet observed. With M_B = -15.9 and (B-V)max = 1.2, this SN is over half a magnitude fainter at maximum light than any other SNIa. Similar to subluminous SN2005ke, SN2007ax also appears to show excess in UV emission at late time. Traditionally, Delta-m_15(B) has been used to parameterize the decline rate for SNeIa. However, the B-band transition from fast to slow decline occurs sooner than 15 days for faint SNeIa. Therefore we suggest that a more physically motivated parameter, the time of intersection of the two slopes, be used instead. Only by explaining the faintest (and the brightest) supernovae, we can thoroughly understand the physics of thermonuclear explosions. We suggest that future surveys should carefully design their cadence, depth, pointings and follow-up to find an unbiased sample of extremely faint members of this subclass of faint SNeIa.Comment: Accepted for publication in ApJ

The Influence of Statistical versus Exemplar Appeals on Indian Adults’ Health Intentions: An Investigation of Direct Effects and Intervening Persuasion Processes

In two separate investigations, we examined the persuasive effectiveness of statistical versus exemplar appeals on Indian adults’ smoking cessation and mammography screening intentions. To more comprehensively address persuasion processes, we explored whether message response and perceived message effectiveness functioned as antecedents to persuasive effects. Results showed that statistical appeals led to higher levels of health intentions than exemplar appeals. In addition, findings from both studies indicated that statistical appeals stimulated more attention and were perceived as more effective than anecdotal accounts. Among male smokers, statistical appeals also generated greater cognitive processing than exemplar appeals. Subsequent mediation analyses revealed that message response and perceived message effectiveness fully carried the influence of appeal format on health intentions. Given these findings, future public health initiatives conducted among similar populations should design messages that include substantive factual information while ensuring that this content is perceived as credible and valuable. [ABSTRACT FROM PUBLISHER

A Very Large Array Search for 5 GHz Radio Transients and Variables at Low Galactic Latitudes

We present the results of a 5 GHz survey with the Very Large Array (VLA) and the expanded VLA, designed to search for short-lived (≾1 day) transients and to characterize the variability of radio sources at milli-Jansky levels. A total sky area of 2.66 deg^2, spread over 141 fields at low Galactic latitudes (b≅6-8 deg), was observed 16 times with a cadence that was chosen to sample timescales of days, months, and years. Most of the data were reduced, analyzed, and searched for transients in near real-time. Interesting candidates were followed up using visible light telescopes (typical delays of 1-2 hr) and the X-ray Telescope on board the Swift satellite. The final processing of the data revealed a single possible transient with a peak flux density of f_ν≅2.4 mJy. This implies a transient's sky surface density of κ(f_ν > 1.8 mJy) = 0.039^(+0.13 +0.18)_(–0.032,–0.038) deg^(–2) (1σ, 2σ confidence errors). This areal density is roughly consistent with the sky surface density of transients from the Bower et al. survey extrapolated to 1.8 mJy. Our observed transient areal density is consistent with a neutron star's origin for these events. Furthermore, we use the data to measure the source variability on timescales of days to years, and we present the variability structure function of 5 GHz sources. The mean structure function shows a fast increase on ≈1 day timescale, followed by a slower increase on timescales of up to 10 days. On timescales between 10 and 60 days, the structure function is roughly constant. We find that ≳30% of the unresolved sources brighter than 1.8 mJy are variables at the >4σ confidence level, presumably mainly due to refractive scintillation